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Reaction mechanism of nano-scale silicon-insulator thin films by real-time observation

Research Project

Project/Area Number 21560321
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionHirosaki University

Principal Investigator

ENTA Yoshiharu  弘前大学, 大学院・理工学研究科, 准教授 (20232986)

Co-Investigator(Kenkyū-buntansha) SAKISAKA Yasuo  弘前大学, 大学院・理工学研究科, 教授 (80108977)
加藤 博雄  弘前大学, 大学院・理工学研究科, 教授 (20152738)
手塚 泰久  弘前大学, 大学院・理工学研究科, 教授 (20236970)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2009: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Keywordsシリコン酸化膜 / 光電子分光 / 酸化速度 / リアルタイム測定 / ゲート酸化膜 / 熱脱離 / 放射光 / ドライ酸化 / ウェット酸化
Research Abstract

For further technological development of semiconductor integrated circuits, we have developed ambient pressure x-ray photoelectron spectroscopy, and carried out real-time observation of nanoscale surface reaction on silicon insulator films with this method. We found two regimes for oxidation rate in initial stage by measuring the growth rate of thermal silicon oxide films accurately. In addition, we found many silicon nanoscale structures on the surface when the silicon oxide films were heated in vacuum.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (49 results)

All 2012 2011 2010 2009 Other

All Journal Article (17 results) (of which Peer Reviewed: 14 results) Presentation (32 results)

  • [Journal Article] Characteristics of Silicon/Nitrogen-Incorporated Diamond-Like Carbon Films Prepared by Plasma-Enhanced Chemical Vapor Deposition2012

    • Author(s)
      H. Nakazawa, S. Miura, R. Kamata, S. Okuno, Y. Enta, M. Suemitsu, T. Abe
    • Journal Title

      apanese Journal of Applied Physics

      Volume: 51 Pages: 15603-15603

    • NAID

      40019137978

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characteristics of Silicon/Nitrogen-Incorporated Diamond-Like Carbon Films Prepared by Plasma-Enhanced Chemical Vapor Deposition2012

    • Author(s)
      H.Nakazawa
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 51 Issue: 1R Pages: 15603-15603

    • DOI

      10.1143/jjap.51.015603

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Controls over Structural and Electronic Properties of Epitaxial Graphene on Silicon Using Surface Termination of 3C-SiC(111)/Si2011

    • Author(s)
      H. Fukidome, S. Abe, R. Takahashi, K. Imaizumi, S. Inomata, H. Handa, E. Saito, Y. Enta, A. Yoshigoe, Y. Teraoka, M. Kotsugi, T. Ohkouchi, T. Kinoshita, S. Ito, M. Suemitsu
    • Journal Title

      Applied Physics Express

      Volume: 4 Pages: 115104-115104

    • NAID

      10030153776

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Control of Epitaxy of Graphene by Crystallographic Orientation of Si Substrate toward Device Applications2011

    • Author(s)
      H. Fukidome, R. Takahashi, S. Abe, K. Imaizumi, H. Handa, H.-C. Kang, H. Karasawa, T. Suemitsu, T. Otsuji, Y. Enta, M. Suemitsu, A. Yoshigoe, Y. Teraoka, M. Kotsugi, T. Ohkouchi, T. Kinoshita
    • Journal Title

      Journal of Materials Chemistry

      Volume: 21 Pages: 17242-17248

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Oxygen-Induced Reduction of the Graphitization Temperature of SiC Surface2011

    • Author(s)
      K. Imaizumi, H. Hanada, R. Takahashi, E. Saito, H. Fukidome, Y. Enta, Y. Teraoka, A. Yoshigoe, M. Suemitsu
    • Journal Title

      apanese Journal of Applied Physics

      Volume: 50 Pages: 70105-70105

    • NAID

      210000070788

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] シリコン酸化膜の不均一な熱分解2011

    • Author(s)
      遠田義晴, 小川可乃, 永井孝幸
    • Journal Title

      電子情報通信学会技術研究報告書

      Volume: 111巻 Pages: 61-64

    • NAID

      110008801099

    • Related Report
      2011 Final Research Report
  • [Journal Article] Oxygen-Induced Reduction of the Graphitization Temperature of SiC Surface2011

    • Author(s)
      K.Imaizumi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 50 Issue: 7R Pages: 70105-70105

    • DOI

      10.1143/jjap.50.070105

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Controls over Structural and Electronic Properties of Epitaxial Graphene on Silicon Using Surface Termination of 3C-SiC(111)/Si2011

    • Author(s)
      H.Fukidome
    • Journal Title

      Applied Physics Express

      Volume: 4 Issue: 11 Pages: 115104-115104

    • DOI

      10.1143/apex.4.115104

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] シリコン酸化膜の不均一な熱分解2011

    • Author(s)
      遠田義晴
    • Journal Title

      電子情報通信学会技術研究報告書

      Volume: 111 Pages: 61-64

    • NAID

      110008801099

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Initial thermal oxidation of Si(100) investigated by Si 2p core-level photoemission2011

    • Author(s)
      Y.Enta
    • Journal Title

      Photon Factory Activity Report 2010

      Volume: 28B Pages: 57-57

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Changes in chemical bonding of diamond-like carbon films by atomic-hydrogen exposure2010

    • Author(s)
      H. Nakazawa, R. Osozawa, Y. Enta, M. Suemitsu
    • Journal Title

      Diamond and Related Materials

      Volume: 19 Pages: 1387-1392

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Silicon thermal oxidation and its thermal desorption investigated by Si 2p core-level photoemission2010

    • Author(s)
      Y. Enta, H. Nakazawa, S. Sato, H. Kato, Y. Sakisaka
    • Journal Title

      Journal of Physics : Conference Series

      Volume: 235 Pages: 12008-12008

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Silicon thermal oxidation and its thermal desorption investigated by Si 2p core-level photoemission2010

    • Author(s)
      Y.Enta
    • Journal Title

      Journal of Physics : Conference Series

      Volume: 235 Pages: 12008-12008

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Silicon Source Gas and Substrate Bias on the Film Properties of Si-Incorporated Diamond-Like Carbon by Radio-Frequency Plasma-Enhanced Chemical Vapor Deposition2009

    • Author(s)
      H. Nakazawa, T. Kinoshita, Y. Kaimori, Y. Asai, M. Suemitsu, T. Abe, K. Yasui, T. Endoh, T. Itoh, Y. Narita, Y. Enta, M. Mashita
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 48 Pages: 116002-116002

    • NAID

      40016844227

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photoemission from the valence bands of Ce(111)on W(110)2009

    • Author(s)
      O.Morimoto
    • Journal Title

      Surface Science 603

      Pages: 2145-2151

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Silicon Source Gas and Substrate Bias on the Film Properties of Si-Incorporated Diamond-Like Carbon by Radio-Frequency Plasma-Enhanced Chemical Vapor Deposition2009

    • Author(s)
      H.Nakazawa
    • Journal Title

      Japanese Journal of Applied Physics 48

      Pages: 116002-116002

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Epitaxial of Graphene on 3C-SiC(111) Thin Films on Microfabricated Si(111) Substrates

    • Author(s)
      T.Ide, Y. Kawai, H. Handa, H. Fukidome, M. Kotsugi, T. Ohkochi, Y. Enta, T. Kinoshita, A.Yoshigoe, Y. Teraoka, M. Suemitsu
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: (印刷中)

    • NAID

      210000140718

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Presentation] Control of electronic and structural properties of epitaxial graphene on 3C-SiC/Si and its device applications2012

    • Author(s)
      H.Fukidome
    • Organizer
      MRS/JSAP Joint meeting
    • Place of Presentation
      San Francisco
    • Year and Date
      2012-04-10
    • Related Report
      2011 Final Research Report
  • [Presentation] 微細構造Si(111)基板上3C-SiC(111)薄膜へのエピタキシャルグラフェン形成2012

    • Author(s)
      井出隆之
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学早稲田キャンパス
    • Year and Date
      2012-03-15
    • Related Report
      2011 Final Research Report
  • [Presentation] 微細構造Si(111)基板上3C-SiC(111)薄膜へのエピタキシャルグラフェン形成2012

    • Author(s)
      井出隆之
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京都)
    • Year and Date
      2012-03-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 微細加工SiC基板上のエピタキシャルグラフェンの電子状態2011

    • Author(s)
      吹留博一
    • Organizer
      第7回放射光表面科学部会顕微ナノ材料科学研究会合同シンポジウム
    • Place of Presentation
      大阪電気通信大学(大阪府)
    • Year and Date
      2011-11-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Tuning of Electronic Properties of Epitaxial Graphene on Microfabrication2011

    • Author(s)
      H. Fukidome
    • Organizer
      第24回マイクロプロセス・ナノテクノロジー国際会議
    • Place of Presentation
      京都市ANAホテル
    • Year and Date
      2011-10-25
    • Related Report
      2011 Final Research Report
  • [Presentation] Tuning of Electronic Properties of Epitaxial Graphene on Microfabrication2011

    • Author(s)
      H.Fukidome
    • Organizer
      第24回マイクロプロセス・ナノテクノロジー国際会議
    • Place of Presentation
      ANAホテル(京都府)
    • Year and Date
      2011-10-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Tuning of Structural and Electronic properties of Epitazial Graphene by Substrate Microfabrication2011

    • Author(s)
      H.Fukidome
    • Organizer
      2011 International Conference on Solid State Devices and Materials
    • Place of Presentation
      愛知県産業労働センター(愛知県)
    • Year and Date
      2011-09-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] SiC微細メサ構造上に形成したエピタキシャルグラフェンの電子状態の観察2011

    • Author(s)
      井出隆之
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学(山形県)
    • Year and Date
      2011-09-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] シリコン基板上SiO2膜の熱分解によるボイド形成2011

    • Author(s)
      遠田義晴
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学
    • Year and Date
      2011-08-30
    • Related Report
      2011 Final Research Report
  • [Presentation] シリコン基板上SiO2膜の熱分解によるボイド形成2011

    • Author(s)
      遠田義晴
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学(山形県)
    • Year and Date
      2011-08-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] シリコン酸化膜の不均一な熱分解2011

    • Author(s)
      遠田義晴
    • Organizer
      電子情報通信学会電子部品・材料研究会
    • Place of Presentation
      弘前大学
    • Year and Date
      2011-08-11
    • Related Report
      2011 Final Research Report
  • [Presentation] シリコン酸化膜の不均一な熱分解2011

    • Author(s)
      遠田義晴
    • Organizer
      電子情報通信学会電子部品・材料研究会
    • Place of Presentation
      弘前大学(青森県)
    • Year and Date
      2011-08-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] ダイヤモンドライクカーボンの化学結合状態2011

    • Author(s)
      中澤日出樹
    • Organizer
      第28回PFシンポジウム
    • Place of Presentation
      つくば国際会議場(茨城県)
    • Year and Date
      2011-07-12
    • Related Report
      2011 Annual Research Report
  • [Presentation] Mechanical and tribological properties of silicon-and nitrogen-incorporated diamond-like carbon films by plasma-enhanced chemical vapor deposition2011

    • Author(s)
      H. Nakazawa
    • Organizer
      International Conference on New Diamond and Nano Carbons2011
    • Place of Presentation
      松江市Kunibiki Messe
    • Year and Date
      2011-05-18
    • Related Report
      2011 Final Research Report
  • [Presentation] Mechanical and tribological properties of silicon- and nitrogen-incorporated diamond-like carbon films by plasma-enhanced chemical vapor deposition2011

    • Author(s)
      H.Nakazawa
    • Organizer
      International Conference on New Diamond and Nano Carbons 2011
    • Place of Presentation
      くにびきメッセ(島根県)
    • Year and Date
      2011-05-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] シリコン酸化膜のSi 2p光イオン化断面積2011

    • Author(s)
      遠田義晴
    • Organizer
      第24回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2011-01-10
    • Related Report
      2011 Final Research Report
  • [Presentation] シリコン酸化膜のSi 2p光イオン化断面積2011

    • Author(s)
      遠田義晴
    • Organizer
      第24回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      つくば国際会議場(茨城県)
    • Year and Date
      2011-01-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] Formation of epitaxial graphene on mesa-patterned SiC substrate2010

    • Author(s)
      H.Fukidome
    • Organizer
      第23回マイクロプロセス・ナノテクノロジー国際会議
    • Place of Presentation
      リーガロイヤルホテル小倉(福岡県)
    • Year and Date
      2010-11-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] 表面微細加工によるグラフェンのエピタキシャル成長の制御2010

    • Author(s)
      吹留博一
    • Organizer
      第30回表面科学学術講演会
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      2010-11-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] 3C-Sic(111)極薄膜上エピタキシャルグラフェン形成過程のLEED/PEs解析2010

    • Author(s)
      高橋良太
    • Organizer
      第30回表面科学学術講演会
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      2010-11-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] A modular approach to high pressure photoelectron spectroscopy2010

    • Author(s)
      Burkhard Kromker
    • Organizer
      The 6th International Workshop on Nano-scale Spectroscopy and Nanotechnology
    • Place of Presentation
      神戸大学(兵庫県)
    • Year and Date
      2010-10-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Spectromicroscopic Distinction of SiGe nanocompounds on Si(100) using Photoemission Electron Microscopy2010

    • Author(s)
      H.Fukidome
    • Organizer
      The 6th International Workshop on Nano-scale Spectroscopy and Nanotechnology
    • Place of Presentation
      神戸大学(兵庫県)
    • Year and Date
      2010-10-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] 6H-SiC基板上微細メサ構造へのエピタキシャルグラフェン形成2010

    • Author(s)
      半田浩之
    • Organizer
      第71回応用物理学会学術講演会
    • Place of Presentation
      長崎大学(長崎県)
    • Year and Date
      2010-09-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] 酸化膜厚2nmまでのシリコン急速初期酸化2010

    • Author(s)
      遠田義晴
    • Organizer
      第57回応用物理学関係連合講演会
    • Place of Presentation
      東海大学
    • Year and Date
      2010-03-20
    • Related Report
      2011 Final Research Report
  • [Presentation] 酸化膜厚2nmまでのシリコン急速初期酸化2010

    • Author(s)
      遠田義晴
    • Organizer
      第57回応用物理学関係連合講演会
    • Place of Presentation
      東海大学(神奈川県)
    • Year and Date
      2010-03-20
    • Related Report
      2009 Annual Research Report
  • [Presentation] 原子状水素を照射したダイヤモンドライクカーボン膜の化学結合状態2010

    • Author(s)
      遲澤遼一
    • Organizer
      第57回応用物理学関係連合講演会
    • Place of Presentation
      東海大学(神奈川県)
    • Year and Date
      2010-03-19
    • Related Report
      2009 Annual Research Report
  • [Presentation] SiGeナノ化合物の元素吸収端近傍における軟X線光電子顕微鏡観察2010

    • Author(s)
      吹留博一
    • Organizer
      第57回応用物理学関係連合講演会
    • Place of Presentation
      東海大学(神奈川県)
    • Year and Date
      2010-03-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] Silicon thermal oxidation and its thermal desorption investigated by Si 2p core-level photoemission2009

    • Author(s)
      Y. Enta
    • Organizer
      International Workshop on Electronic Spectroscopy for Gas-phase Molecules and Solid Surfaces
    • Place of Presentation
      宮城県松島町ホテル大観荘
    • Year and Date
      2009-10-13
    • Related Report
      2011 Final Research Report
  • [Presentation] Chemical composition of Ge(Si)islands on Si(100)substrate capped with Si2009

    • Author(s)
      H.Fukidome
    • Organizer
      International Workshop on Electronic Spectroscopy for Gas-phase Molecules and Solid Surfaces
    • Place of Presentation
      Hotel Taikansou (宮城県)
    • Year and Date
      2009-10-13
    • Related Report
      2009 Annual Research Report
  • [Presentation] Silicon thermal oxidation and its thermal desorption investigated by Si2p core-level photoemission2009

    • Author(s)
      Y.Enta
    • Organizer
      International Workshop on Electronic Spectroscopy for Gas-phase Molecules and Solid Surfaces
    • Place of Presentation
      Hotel Taikansou (宮城県)
    • Year and Date
      2009-10-13
    • Related Report
      2009 Annual Research Report
  • [Presentation] Epitaxy of Graphene on Si substrates toward 3-D Graphene Devices2009

    • Author(s)
      H.Fukidome
    • Organizer
      2009 International Conference on Solid State Devices and Materials
    • Place of Presentation
      Sendai Kokusai Hotel (宮城県)
    • Year and Date
      2009-10-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] 原子状水素照射によるダイヤモンドライクカーボン膜の化学結合状態の変化2009

    • Author(s)
      遲澤遼一
    • Organizer
      電子情報通信学会 電子部品・材料研究会
    • Place of Presentation
      弘前大学(青森県)
    • Year and Date
      2009-08-10
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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