Elucidation of the mechanism of low-temperature type solid state diffusion induced by hydrogen atoms in electrodeposited films
| Project/Area Number |
21560692
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Physical properties of metals
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| Research Institution | University of Hyogo |
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Principal Investigator |
MATSUDA Hitoshi 兵庫県立大学, 大学院・工学研究科, 教授 (60118015)
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| Co-Investigator(Kenkyū-buntansha) |
YAE Shinji 兵庫県立大学, 大学院・工学研究科, 准教授 (00239716)
FUKUMURO Naoki 兵庫県立大学, 大学院・工学研究科, 助教 (10347528)
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| Co-Investigator(Renkei-kenkyūsha) |
FUKAI Yuh 中央大学, 名誉教授 (80055136)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2009: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | 拡散 / 相変態 / 状態図 / 電析めっき / 水素 / 固体拡散 / 空孔 / 再結晶 / ナノ構造 / 薄膜 / 電気化学 / 析出膜 / 固相反応 |
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| Research Abstract |
The mechanism of recrystallisation observed at room temperature in electrodeposited films has been examined in light of the enhancement of metal atom diffusion by hydrogen induced superabundant vacancies. Thermal desorption spectroscopy revealed that the films electrodeposited showed a pronounced peak, which was ascribed to the break-up of vacancy. hydrogen clusters. The grain size of the films increased as hydrogen desorption proceeded. These results indicate that the room temperature recrystallisation of electrodeposited films is caused by hydrogen induced superabundant vacancies.
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Report
(4 results)
Research Products
(60 results)
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[Presentation]2012
Author(s)
福室直樹, 安達貴良, 八重真治, 松田均, 深井有
Organizer
日本金属学会第150回講演大会
Related Report
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[Presentation] Au電析膜中の水素2011
Author(s)
仲大輔
Organizer
第13回関西表面技術フォーラム
Place of Presentation
キャンパスプラザ京都(京都府)
Year and Date
2011-11-29
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