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Thermoelectric properties of the hole-electron coexisting-type transition-metal multiple oxides

Research Project

Project/Area Number 21560694
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionTohoku University

Principal Investigator

TAKAHASHI Junichi  東北大学, 多元物質科学研究所, 助教 (20261472)

Co-Investigator(Renkei-kenkyūsha) YAMANE Hisanori  東北大学, 多元物質科学研究所, 教授 (20191364)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords機能性セラミックス / セラミックス / 廃熱利用 / 半導体物性 / エネルギー効率化 / 熱電変換材料 / 熱電変換材
Research Abstract

The single crystal/polycrystal sample of the transition metal oxides in which the crystal structure consisted of several crystallographically different coordination polyhedrons were produced, and the career characteristic was evaluated. Some characteristics such as the Seebeck coefficient, electrical conductivity, and electronic state calculation showed that the 2H-perovskite type calcium cobaltite and spinel-type ruthenium cobaltite were in the coexistence state of the hole and electron by the electron exchange reaction and disproportionation reaction between each site resulting from two or more mixed ionic states.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (22 results)

All 2011 2010 2009 Other

All Journal Article (9 results) (of which Peer Reviewed: 8 results) Presentation (9 results) Remarks (4 results)

  • [Journal Article] Na-Si融液とFe圧粉成型体の反応によるss-FeSi2多結晶バルク体の低温合成2011

    • Author(s)
      山田高広、苅谷英里、森戸春彦、高橋純一、山根久典
    • Journal Title

      粉体および粉末冶金

      Volume: 58 Pages: 110-115

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Na-Si融液とFe圧粉成型体の反応によるβ-FeSi_2多結晶バルク体の低温合成2011

    • Author(s)
      山田高広, 高橋純一, ら
    • Journal Title

      粉体および粉末冶金

      Volume: 58 Pages: 110-115

    • NAID

      10027916252

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] スピン-電荷不均化反応によるコバルト系導電性酸化物の熱電特性制御2010

    • Author(s)
      高橋純一、山根久典
    • Journal Title

      Annual Report of the Murata Science Foundation

      Volume: 24 Pages: 169-177

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Journal Article] Simulation of the estimation of the maximum inclusion size from 2-dimensional observation data on the basis of the extreme value of statistics2009

    • Author(s)
      Junichi Takahashi
    • Journal Title

      ISIJ International

      Volume: 49 Pages: 1030-1035

    • NAID

      10027035574

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Oxidation of Rare Earth Silicon Oxynitride J-Phases2009

    • Author(s)
      Junichi Takahashi, Takayuki Suehiro
    • Journal Title

      Key Engineering Materials

      Volume: 403 Pages: 57-59

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, crystal structures and high-temperature thermoelectric properties of spinel-type cobalt ruthenium oxides2009

    • Author(s)
      Tetsuya Kawano, Junichi Takahashi, Takeshi Okutani, Takahiro Yamanda, Hisanori Yamane
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 468 Pages: 447-451

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, crystal structures and high-temperature thermoelectric properties of spinel-type cobalt ruthenium oxides2009

    • Author(s)
      T.Kawano, J.Takahashi, ら
    • Journal Title

      Journal of Alloys and Compounds 468

      Pages: 447-451

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxidation of Rare Earth Silicon Oxynitride J-Phases2009

    • Author(s)
      J.Takahashi, T.Suehiro
    • Journal Title

      Key Engineering Materials 403

      Pages: 57-59

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Simulation of the estimation of the maximum inclusion size from 2-dimensional observation data on the basis of the extreme value of statistics2009

    • Author(s)
      J.Takahashi
    • Journal Title

      ISIJ International 49

      Pages: 1030-1035

    • NAID

      10027035574

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] High-temperature thermoelectric properties of Ca3(Cu, Rh)2O6 single crystals with pseudo one-dimensional structure2011

    • Author(s)
      Junichi Takahashi, Hisanori Yamane
    • Organizer
      International Conference on Materials for Advanced Technologies
    • Place of Presentation
      Singapore
    • Year and Date
      2011-06-27
    • Related Report
      2011 Final Research Report
  • [Presentation] High-temperature thermoelectric properties of Ca_3(Cu, Rh)_2O_6 single crystals with pseudo one-dimensional structure2011

    • Author(s)
      J.Takahashi, ら
    • Organizer
      International Conference on Materials for Advanced Technologies
    • Place of Presentation
      シンガポール,サンテックシンガポール国際会議場
    • Year and Date
      2011-06-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] Preparation of ss-FeSi2 and MnSi1. 7+ ≦ Bulks from Metal Compact Bodies Using a Na-Si Melt and Their Thermoelectric Properties2010

    • Author(s)
      Takahiro Yamada, Eri Kariya, Haruhiko Morito, Yuzuru Miyazaki, Junichi Takahashi, Hisanori Yamane
    • Organizer
      3rd International Congress on Ceramics
    • Place of Presentation
      日本, 大阪
    • Year and Date
      2010-11-17
    • Related Report
      2011 Final Research Report
  • [Presentation] Preparation of β-FeSi_2 and MnSi_<1.7+δ> Bulks from Metal Compact Bodies Using a Na-Si Melt and Their Thermoelectric Properties2010

    • Author(s)
      J.Takahashi, ら
    • Organizer
      3^<rd> International Congress on Ceramics (ICC3)
    • Place of Presentation
      大阪
    • Year and Date
      2010-11-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Maximum Size of the Dispersed Particles Estimated from 2-Dimensional Observation Data on the Basis of the Extreme Value of Statistics2010

    • Author(s)
      Junichi Takahashi
    • Organizer
      The 2nd International Symposium on Cutting Edge of Computer Simulation of Solidification and Casting
    • Place of Presentation
      日本, 北海道
    • Year and Date
      2010-02-03
    • Related Report
      2011 Final Research Report
  • [Presentation] Maximum Size of the Dispersed Particles Estimated from 2-Dimensional Observation Data on the Basis of the Extreme Value of Statistics2010

    • Author(s)
      J.Takahashi
    • Organizer
      The 2nd International Symposium on Cutting Edge of Computer Simulation of Solidification and Casting(CSSC2010)
    • Place of Presentation
      札幌
    • Year and Date
      2010-02-03
    • Related Report
      2009 Annual Research Report
  • [Presentation] 極値統計法を用いた2次元断面粒径分布からの3次元最大粒径分布の推定2009

    • Author(s)
      高橋純一
    • Organizer
      第9回東北大学多元物質科学研究所研究発表会
    • Place of Presentation
      日本, 宮城
    • Year and Date
      2009-12-10
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis, Crystal Structures and High-Temperature Thermoelectric Properties of Multicomponent Cobalt-Ruthenium Oxides2009

    • Author(s)
      Junichi Takahashi, Tetsuya Kawano, Takahiro Yamada, Takeshi Okutani, Hisanori Yamane
    • Organizer
      International Conference on Materials for Advanced Technologies 2009 & International Union of Materials Research Societies International Conference in Asia 2009
    • Place of Presentation
      Singapore(Suntec Singapore)
    • Year and Date
      2009-07-02
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis, Crystal Structures and High-Temperature Thermoelectric Properties of Multicomponent Cobalt-Ruthenium Oxides2009

    • Author(s)
      J.Takahashi, ら
    • Organizer
      International Conference on Materials for Advanced Technologies 2009
    • Place of Presentation
      シンガポール,サンテックシンガポール国際会議場
    • Year and Date
      2009-07-02
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.tagen.tohoku.ac.jp/

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://www.tagen.tohoku.ac.jp/

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.tagen.tohoku.ac.jp/

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.tagen.tohoku.ac.jp/

    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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