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Synthesis and Properties of Novel Solid Catalysts With Hierarchical Pore Structures

Research Project

Project/Area Number 21560700
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionEhime University

Principal Investigator

TAKAHASHI Ryoji  愛媛大学, 大学院・理工学研究科, 教授 (80292663)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords表面・界面物性 / 多孔体 / 触媒・化学プロセス / 無機工業化学 / 反応・分離工学 / 環境材料
Research Abstract

Bimodal porous solid catalysts, such as titania-supported and alumina-supported nickel and organic-inorganic composite catalysts, were prepared by the combination of sol-gel and phase separation methods. We proved the effectiveness of macropores in the catalysts in steam-reforming of methane and in selective dehydration of butanediol in reaction-distillation.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (51 results)

All 2011 2010 2009

All Journal Article (22 results) (of which Peer Reviewed: 22 results) Presentation (29 results)

  • [Journal Article] Giant Negative Thermal Expansion in the Iron Perovskite SrCu3Fe4O122011

    • Author(s)
      Ikuya Yamada, Kazuki Tsuchida, Kenya Ohgushi, Naoaki Hayashi, Jungeun Kim, Naruki Tsuji, Ryoji Takahashi, Masafumi Matsushita, Norimasa Nishiyama, Toru Inoue, Tetsuo Irifune, Kenichi Kato, Masaki Takata, and Mikio Takano
    • Journal Title

      Angew. Chem., Int. Ed

      Volume: 50 Pages: 6579-6582

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Suppression of geometric frustration by magnetoelastic coupling in AuCrS22011

    • Author(s)
      S. J. E. Carlsson, G. Rousse, I. Yamada, H. Kuriki, R. Takahashi, F. Levy-Bertrand, G. Giriat, A. Gauzzi
    • Journal Title

      Phys. Rev. B

      Volume: 84

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Giant Negative Thermal Expansion in the Iron Perovskite SrCu3Fe4O122011

    • Author(s)
      Ikuya Yamada
    • Journal Title

      Angew.Chem., Int.Ed.

      Volume: 50 Pages: 6579-6582

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Suppression of geometric frustration by magnetoelastic coupling in AuCrS22011

    • Author(s)
      S.J.E.Carlsson
    • Journal Title

      Phys.Rev.B

      Volume: 84

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phase separation in the system with sodium silicate and sodium dodecyl sulfate under acidic conditions2010

    • Author(s)
      Ryoji Takahashi, Satoshi Sato, Yasuhide Kojima, Toshiaki Sodesawa, Ikuya Yamada, Daisuke Nishi, Katsuhiro Muramatsu, Hidenori Yahiro, Hiroyuki Yamaura, and Naoki Mikami
    • Journal Title

      J. Ceram. Soc. Japan

      Volume: 118 Pages: 295-299

    • NAID

      130000304732

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sol-Gel Preparation of Ni/TiO2 Catalysts with Bimodal Pore Structures2010

    • Author(s)
      Masayuki Numata, Ryoji Takahashi, Ikuya Yamada, Kazuki Nakanishi, and Satoshi Sato
    • Journal Title

      Appl. Catal. A.: Gen

      Volume: 383 Pages: 66-72

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of 3-butene-1-ol from 1, 4-butanediol over indium oxide2010

    • Author(s)
      Ryoji Takahashi, Ikuya Yamada, Aiko Iwata, Naoya Kurahashi, Satoshi Yoshida, Satoshi Sato
    • Journal Title

      Appl. Catal. A.: Gen

      Volume: 383 Pages: 134-140

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] CaCu3Pt4O12 : The First Perovskite with the B Site Fully Occupied by Pt4+2010

    • Author(s)
      Ikuya Yamada, Yuka Takahashi, Kenya Ohgushi, Norimasa Nishiyama, Ryoji Takahashi, Kohei Wada, Takehiro Kunimoto, Hiroaki Ohfuji, Yohei Kojima, Toru Inoue, Tetsuo Irifune
    • Journal Title

      Inorg. Chem

      Volume: 49 Pages: 6778-6780

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Sol-Gel Preparation of Ni/TiO_2 Catalysts with Bimodal Pore Structures2010

    • Author(s)
      Masayuki Numata
    • Journal Title

      Appl.Catal.A

      Volume: 383 Pages: 66-74

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of 3-butene-1-ol from 1,4-butanediol over indium oxide2010

    • Author(s)
      Ryoji Takahashi
    • Journal Title

      Appl.Catal.A

      Volume: 383 Pages: 134-140

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] CaCu_3Pt_4O_<12> : The First Perovskite with the B Site Fully Occupied by Pt^<4+>2010

    • Author(s)
      Ikuya Yamada
    • Journal Title

      Inorg.Chem

      Volume: 49 Pages: 6778-6780

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phase separation in the system with sodium silicate and sodium dodecyl sulfate under acidic conditions2010

    • Author(s)
      Ryoji Takahashi
    • Journal Title

      J.Ceram.Soc.Japan 118

      Pages: 295-299

    • NAID

      130000304732

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dehydration-hydrogenation of glycerol into 1, 2-propanediol at ambient hydrogen pressure2009

    • Author(s)
      Masaki Akiyama, Satoshi Sato, Ryoji Takahashi, Kanichiro Inui, Masahiro Yokota
    • Journal Title

      Appl. Catal. A : General

      Volume: 371 Pages: 60-66

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dehydration of 1, 4-butanediol over rare earth oxides2009

    • Author(s)
      Satoshi Sato, Ryoji Takahashi, Mika Kobune, Hirotomo Inoue, Yusuke Izawa, Hironobu Ohno, Kazunari Takahashi
    • Journal Title

      Appl. Catal. A : General

      Volume: 356 Pages: 64-71

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Basic properties of rare earth oxides2009

    • Author(s)
      Satoshi Sato, Ryoji Takahashi, Mika Kobune, Hiroshi Gotoh
    • Journal Title

      Appl. Catal. A : General

      Volume: 356 Pages: 57-63

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dehydration of 1, 4-butanediol over supported rare earth oxide catalysts2009

    • Author(s)
      Hirotomo Inoue, Satoshi Sato, Ryoji Takahashi, Yusuke Izawa, Hironobu Ohno, Kazunari Takahashi
    • Journal Title

      Appl. Catal. A : General

      Volume: 352 Pages: 66-73

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Vapor-phase dehydration of 1, 3-butanediol over CeO2-ZrO2 catalysts2009

    • Author(s)
      Takashi Nozawa, Satoshi Sato, Ryoji Takahashi
    • Journal Title

      Topics in Catalysis

      Volume: 52 Pages: 609-617

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Vapor-phase dehydration of 1,3-butanediol over CeO2-ZrO2 catalysts2009

    • Author(s)
      Takashi Nozawa
    • Journal Title

      Topics in Catalysis 52

      Pages: 609-617

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dehydration of 1,4-butanediol over supported rare earth oxide catalysts2009

    • Author(s)
      Hirotomo Inoue
    • Journal Title

      Appl.Catal.A 352

      Pages: 66-73

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Basic properties of rare earth oxides2009

    • Author(s)
      Satoshi Sato
    • Journal Title

      Appl.Catal.A 356

      Pages: 57-63

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dehydration of 1,4-butanediol over rare earth oxides2009

    • Author(s)
      Satoshi Sato
    • Journal Title

      Appl.Catal.A 356

      Pages: 64-71

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dehydration-hydrogenation of glycerol into 1,2-propanediol at ambient hydrogen pressure2009

    • Author(s)
      Masaki Akiyama
    • Journal Title

      Appl.Catal.A 371

      Pages: 57-63

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Precise Design of Nanocoraposites of Metal/Metal Oxides for solid Catalysis2011

    • Author(s)
      Ryoji Takahashi
    • Organizer
      BIT's 1st Annual World Congress of Nano-S & T
    • Place of Presentation
      Dalian, China(Invited)
    • Year and Date
      2011-10-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Precise Design of Nanocomposites of Metal/Metal Oxides for solid Catalysis(Invited)2011

    • Author(s)
      Ryoji Takahashi
    • Organizer
      BIT's 1st Annual World Congress of Nano-S & T(Dalian, China) October 23-26, 2011 Track 3-16 : Oxide Nanocomposites and Multilayes
    • Related Report
      2011 Final Research Report
  • [Presentation] ポリスチレン-シリカ複合体の構造制御と触媒活性2011

    • Author(s)
      高橋亮治・山田幾也・小谷優美
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] シリカ複合体触媒による反応蒸留を用いたテトラヒドロフラン選択合成2011

    • Author(s)
      好井潤弥・高橋亮治・山田幾也・小谷優美
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 光学半導体用透明封止剤のための球状無機酸化物フィラーの合成2011

    • Author(s)
      大野右貴・高橋亮治・山田幾也・内藤俊雄
    • Organizer
      ゾルゲル学会第9回討論会
    • Place of Presentation
      京都
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] ゾル-ゲル法による二元細孔AlPO4多孔体の作製と細孔構造制御2011

    • Author(s)
      平山徹・高橋亮治・山田幾也
    • Organizer
      ゾルゲル学会第9回討論会
    • Place of Presentation
      京都
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] ゾルゲル法固体酸触媒によるテトラヒドロフランの選択合成2011

    • Author(s)
      好井潤弥・高橋亮治・山田幾也・小谷優美
    • Organizer
      ゾルゲル学会第9回討論会
    • Place of Presentation
      京都
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 階層細孔構造を有するNi/Al2O3触媒の作製2010

    • Author(s)
      入澤計太
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      甲府山梨大
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 二元細孔Ni/TiO_2触媒の構造制御と選択的水素化活性2010

    • Author(s)
      沼田昌之
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      甲府山梨大
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of 3-butene-1-ol from 1,4-butanediol over indium oxide2010

    • Author(s)
      Takahashi Ryoji
    • Organizer
      TOCAT6/APCAT5
    • Place of Presentation
      Sapporo
    • Year and Date
      2010-04-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Preparation of Ni/TiO2 Catalyst with Bimodal Pore structures for hydrogenation reaction2010

    • Author(s)
      Numata Masayuki
    • Organizer
      TOCAT6/APCAT5
    • Place of Presentation
      Sapporo
    • Year and Date
      2010-04-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis and morphology control of novel organic-inorganic composites by polymerization in pores of bimodal porous silica2010

    • Author(s)
      Kodani Yumi
    • Organizer
      TOCAT6/APCAT5
    • Place of Presentation
      Sapporo
    • Year and Date
      2010-04-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] シリカ細孔内重合による新規有機無機複合体の合成とモルフォロジー制御2010

    • Author(s)
      小谷優美, 高橋亮治, 山田幾也, 川本大祐, 清水祐貴
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-28
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] イオン交換能を有する新規有機無機複合体の合成2010

    • Author(s)
      川本大祐, 高橋亮治, 山田幾也, 小谷優美, 清水祐貴
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-28
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 二元細孔Ni/TiO<SUB> 2</SUB>触媒の作製と水素化活性2010

    • Author(s)
      沼田昌之, 高橋亮治, 山田幾也
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-28
    • Related Report
      2011 Final Research Report
  • [Presentation] 二元細孔Ni/TiO2触媒の作製と水素化活性2010

    • Author(s)
      沼田昌之
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 二元細孔Ni/TiO2触媒の構造制御と選択的水素化活性2010

    • Author(s)
      沼田昌之, 高橋亮治, 山田幾也
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      甲府
    • Related Report
      2011 Final Research Report
  • [Presentation] 階層細孔構造を有するNi/Al2O3触媒の作製2010

    • Author(s)
      入澤計太, 高橋亮治, 山田幾也
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      甲府
    • Related Report
      2011 Final Research Report
  • [Presentation] Preparation of Ni/TiO2 Catalyst with Bimodal Pore structures for hydrogenation reaction2010

    • Author(s)
      Masayuki Numata, Ryoji Takahashi, Ikuya Yamada
    • Organizer
      The Sixth Tokyo Conference on Advanced Catalytic Science and Technology(TOCAT6) and The Fifth Asia Pacific Congress
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis and morphology control of novel organic-inorganic composites by polymerization in pores of bimodal porous silica2010

    • Author(s)
      Yumi Kodani, Ryoji Takahashi, Ikuya Yamada, Daisuke Kawamoto, Yuki Shimizu
    • Organizer
      The Sixth Tokyo Conference on Advanced Catalytic Science and Technology(TOCAT6) and The Fifth Asia Pacific Congress on Catalysis(APCAT5) SAPPORO
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis of 3-butene-1-ol from 1, 4-butanediol over indium oxide2010

    • Author(s)
      Ryoji Takahashi, Ikuya Yamada, Aiko Iwata, Naoya Kurahashi, Satoshi Sato
    • Organizer
      The Sixth Tokyo Conference on Advanced Catalytic Science and Technology(TOCAT6) and The Fifth Asia Pacific Congress on Catalysis(APCAT5) SAPPORO
    • Related Report
      2011 Final Research Report
  • [Presentation] Sol-gel preparation of silica-titania nanocomposites with macropores2009

    • Author(s)
      Olim Ruzimuradov, Ryoji Takahashi, and Ikuya Yamada
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      愛媛
    • Year and Date
      2009-11-08
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 有機無機ハイブリッドのモルフォロジー制御2009

    • Author(s)
      高橋亮治
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      愛媛
    • Year and Date
      2009-11-08
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] Structure Control in Silica-Titania with Macro-Meso Pore System2009

    • Author(s)
      Olim Ruzimuradov, Ryoji Takahashi, Ikuya Yamada, and Yumi Kodani
    • Organizer
      日本セラミックス協会第22回秋季シンポジウム
    • Place of Presentation
      愛媛
    • Year and Date
      2009-09-17
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 二元細孔チタニアの構造制御と固体触媒としての応用2009

    • Author(s)
      沼田昌之, 高橋亮治, 山田幾也
    • Organizer
      日本セラミックス協会第22回秋季シンポジウム
    • Place of Presentation
      愛媛
    • Year and Date
      2009-09-17
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] ゾル-ゲル法による固体触媒調製とその活性2009

    • Author(s)
      高橋亮治
    • Organizer
      ゾルゲル学会第7回討論会
    • Place of Presentation
      京都
    • Year and Date
      2009-07-31
    • Related Report
      2011 Final Research Report
  • [Presentation] ゾル・ゲル法による固体触媒調製とその活性2009

    • Author(s)
      高橋亮治
    • Organizer
      ゾルゲル学会第7回討論会
    • Place of Presentation
      京都
    • Year and Date
      2009-07-31
    • Related Report
      2009 Annual Research Report
  • [Presentation] マクロ孔を有する複合酸化物の合成2009

    • Author(s)
      小谷優美, 高橋亮治, 山田幾也, 村松克洋
    • Organizer
      ゾルゲル学会第7回討論会
    • Place of Presentation
      京都
    • Year and Date
      2009-07-30
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 二元細孔チタニアの作製と固体触媒としての応用2009

    • Author(s)
      沼田昌之, 高橋亮治, 山田幾也
    • Organizer
      ゾルゲル学会第7回討論会
    • Place of Presentation
      京都
    • Year and Date
      2009-07-30
    • Related Report
      2011 Final Research Report 2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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