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Characterization of gas adsorption thin film prepared by physical vapor deposition methods and application for gas sensors

Research Project

Project/Area Number 21560744
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/treatments
Research InstitutionTokai University (2010-2011)
Kanazawa University (2009)

Principal Investigator

IWAMORI Satoru  東海大学, 工学部, 教授 (90345603)

Co-Investigator(Kenkyū-buntansha) NODA Kazutoshi  産業技術総合研究所, 主任研究員 (60357746)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2009: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords物理気相蒸着法 / 有機薄膜 / ガス吸着 / QCM / 高周波スパッタリング / ガス吸着速度 / センサ感度
Research Abstract

Highly sensitive detection methods for volatile organic compounds(VOCs) are needed in working environment handling the VOCs. The use of a quartz crystal microbalance(QCM) is one such method, and we report on adsorption properties of organic thin films deposited onto the QCM electrode by physical vapor depositions, e. g., vacuum evaporation, plasma-assisted vacuum evaporation and r. f. sputtering, for low molecular weight VOCs. The adsorption phenomenon is considered to be a physical adsorption. Polarization and density of these organic thin films affect adsorption mass of these VOC molecules. In the fluorocarbon thin films sputtered with a Poly(tetrafluoroethylene)(PTFE) target, sensitivities for these aliphatic alcohols were almost the same level, however the sensitivities for acetone were higher than those for these aliphatic alcohols. It is considered that these organic thin films can be used for a sensor of detection of these VOCs.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (30 results)

All 2012 2011 2010 2009 Other

All Journal Article (13 results) (of which Peer Reviewed: 12 results) Presentation (15 results) Remarks (2 results)

  • [Journal Article] Fundamental adsorption properties for low molecular weight alcohols in fluorocarbon thin films deposited onto quartz crystal microbalance electrode by an r. f. sputtering and spin coating2012

    • Author(s)
      S. Iwamori, T. Miyamoto, Y. Ikeda, Y. Ohnishi, K. Noda
    • Journal Title

      IEEJ, Sec. E

      Volume: Vol.132, No.6 Pages: 149-153

    • NAID

      10030607189

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Gas adsorption properties of fluorocarbon thin films prepared by three different types of r.f.magnetron sputtering systems2012

    • Author(s)
      Satoru IWAMORI, Takaaki MIYAMOTO, Yuki IKEDA, Yasutaka OHNISHI, Kazutoshi NODA
    • Journal Title

      電気学会誌E部門

      Volume: Vol.132,No.6 Pages: 149-153

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption and desorption properties of alcohols in fluorocarbon thin films deposited onto quartz crystal microbalance (QCM) electrode by an r.f.sputtering and spin coating2011

    • Author(s)
      Satoru IWAMORI, Takaaki MIYAMOTO, Yuki IKEDA, Yasutaka OHNISHI, Kazutoshi NODA
    • Journal Title

      ISSP2011、Proceedings

      Pages: 432-435

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Gas adsorption performance of organic thin films prepared by plasma-assisted vacuum evaporation with polyimide precursors2010

    • Author(s)
      S. Iwamori, R. Sugimoto, K. Osada, M. Kurata, H. Matsumoto, K. Noda
    • Journal Title

      Sensors & Materials

      Volume: Vol.22, No.7 Pages: 347-356

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption properties of fluorocarbon thin films prepared by physical vapor deposition methods2010

    • Author(s)
      S. Iwamori, T. Tanabe, S. Yano, K. Noda
    • Journal Title

      Surface & Coatings Technology

      Volume: Vol.204 Pages: 2803-2807

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption properties of thin films prepared by r. f. sputtering with a BPDA-PDA polyimide target2010

    • Author(s)
      S. Iwamori, S. Yano, R. Sugimoto, A. Uemura, H. Matsumoto, K. Noda
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: Vol.49, 04

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Gas adsorption properties of fluorocarbon thin films prepared by three different types of r. f. magnetron sputtering systems2010

    • Author(s)
      S. Iwamori, N. Hasegawa, S. Yano, K. Noda
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: Vol.49, 04

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Gas adsorption properties of fluorocarbon thin films prepared by three different types of r.f. magnetron sputtering systems2010

    • Author(s)
      S.Iwamori, N.Hasegawa, S.Yano, K.Noda
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 49

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption properties of thin films prepared by r.f. sputtering with a BPDA-PDA polyimide target2010

    • Author(s)
      S.Iwamori, S.Yano, R.Sugimoto, A.Uemura, H.Matsumoto, K.Noda
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 49

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption properties of fluorocarbon thin films prepared by physical vapor deposition methods2010

    • Author(s)
      S.Iwamori, T.Tanabe, S.Yano
    • Journal Title

      Surface & Coatings Technology

      Volume: 204 Pages: 2803-2807

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Gas adsorption performance of organic thin films prepared by plasma-assisted vacuum evaporation with polyimide precursors2010

    • Author(s)
      S.Iwamori, R.Sugimoto,K.Osada, M.Kurata, H.Matsumoto, K.Noda
    • Journal Title

      Sensors & Materials

      Volume: 22 Pages: 347-356

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Monitoring of Surface Treatment Effects on Sputter-Coated Organic Film under Atomic Oxygen and Ultraviolet Irradiation2010

    • Author(s)
      H.Matsumoto, M.Matsuoka, K.Yoshino, T.Iwasaki, S.Kinoshita, K.Noda, S.Iwamori
    • Journal Title

      Chemistry Letters 39

      Pages: 102-103

    • NAID

      10027177023

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Active Oxygen Minitor Using Quartz Crystal Microbalance Method with Polymer Detection Layers2009

    • Author(s)
      H.Matsumoto, M.Matsuoka, T.Iwasaki, S.Kinoshita, S.Iwamori, K.Noda
    • Journal Title

      Journal of Photopolymer Science & Technology 22

      Pages: 279-284

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 水晶振動子上に形成したフッ化炭素薄膜の低分子量揮発性有機溶剤の吸着特性2012

    • Author(s)
      岩森暁、大西康貴、池田佑旭、野田和俊
    • Organizer
      電子情報通信学会年次大会
    • Place of Presentation
      岡山大学
    • Year and Date
      2012-03-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] 水晶振動子の金属電極上に形成したフッ化炭素薄膜の接着性2012

    • Author(s)
      岩森暁
    • Organizer
      第2回超微細切削による材料評価研究会
    • Place of Presentation
      東京大学
    • Year and Date
      2012-02-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] 水晶振動子上に形成したフッ化炭素薄膜の低分子量揮発性有機溶剤の吸着特性2012

    • Author(s)
      岩森暁、大西康貴、池田佑旭、野田和俊
    • Organizer
      電子情報通信学会年次大会シンポジウム(DVD-ROM)
    • Place of Presentation
      岡山
    • Related Report
      2011 Final Research Report
  • [Presentation] 高周波スパッタリングにより形成した有機薄膜のVOC(アセトン)の吸着特性2011

    • Author(s)
      大西康貴、池田佑旭、岩森暁、野田和俊
    • Organizer
      第52回真空に関する連合講演会
    • Place of Presentation
      学習院大学
    • Year and Date
      2011-11-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金属基板上に形成したフッ化炭素薄膜の表面特性とセンサへの応用2011

    • Author(s)
      岩森暁
    • Organizer
      高分子学会接着と塗装研究会
    • Place of Presentation
      すみだ産業会館(東京都)
    • Year and Date
      2011-06-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] 高周波スパッタリングにより形成した有機薄膜のVOC(アセトン)の吸着特性2011

    • Author(s)
      大西康貴、池田佑旭、岩森暁、野田和俊
    • Organizer
      第52回真空に関する連合講演会
    • Place of Presentation
      東京
    • Related Report
      2011 Final Research Report
  • [Presentation] Adsorption and desorption properties of alcohols in fluorocarbon thin films deposited onto quartz crystal microbalance(QCM) electrode by an r. f. sputtering and spin coating2011

    • Author(s)
      S. Iwamori, T. Miyamoto, Y. Ikeda, Y. Ohnishi and K. Noda
    • Organizer
      ISSP2011
    • Place of Presentation
      Kyoto
    • Related Report
      2011 Final Research Report
  • [Presentation] 金属基板上に形成したフッ化炭素薄膜の表面特性とセンサへの応用2011

    • Author(s)
      岩森暁
    • Organizer
      高分子学会接着と塗装研究会
    • Place of Presentation
      東京
    • Related Report
      2011 Final Research Report
  • [Presentation] Monitoring of Active Oxygen Generated under Ultraviolet Irradiation Used a Quartz Crystal Microbalance(QCM) with Sputter-coated and Spin-coated Poly(tetrafluoroethylene) Thin Films2011

    • Author(s)
      S. Iwamori, K. Yoshino, H. Matsumoto, K. Noda
    • Organizer
      8th International symposium on Polymer Surface Modification
    • Place of Presentation
      Abstract
    • Related Report
      2011 Final Research Report
  • [Presentation] プラズマ支援真空蒸着法で成膜したポリイミド系薄膜の表面特性2010

    • Author(s)
      岩森暁, ほか4名
    • Organizer
      電気学会 誘電・絶縁材料研究会
    • Place of Presentation
      帝人(株)先端技術開発センター
    • Year and Date
      2010-07-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] プラズマ支援蒸着法で成膜したポリイミド系薄膜の表面特性2010

    • Author(s)
      岩森暁、杉本亮祐、長田幸輔、松本裕之、野田和俊
    • Organizer
      電気学会誘電・絶縁材料研究会
    • Place of Presentation
      山口
    • Related Report
      2011 Final Research Report
  • [Presentation] Adsorption properties of polymer thin films prepared by r.f.sputtering with a BPDA-PDA polyimide target2009

    • Author(s)
      S.Yano, A.Uemura, S.Iwamori, K.Noda
    • Organizer
      2009 International Conference on Solid State Devices and Materials
    • Place of Presentation
      仙台国際ホテル(宮城県)
    • Year and Date
      2009-10-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] Gas adsorption properties of fluorocarbon polymer thin films prepared by three different types of r.f.magnetron sputtering systems2009

    • Author(s)
      N.Hasegawa, S.Yano, S.Iwamori, K.Noda
    • Organizer
      2009 International Conference on Solid State Devices and Materials
    • Place of Presentation
      仙台国際ホテル(宮城県)
    • Year and Date
      2009-10-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] Gas adsorption properties of fluorocarbon polymer thin films prepared by three different types of r. f. magnetron sputtering systems2009

    • Author(s)
      N. Hasegawa, S. Yano, S. Iwamori, K. Noda
    • Organizer
      International Conference on Solid State Devices and Materials
    • Place of Presentation
      Sendai
    • Related Report
      2011 Final Research Report
  • [Presentation] Adsorption properties of polymer thin films prepared by r. f. sputtering with a BPDA-PDA polyimide target2009

    • Author(s)
      S. Yano, A. Uemura, S. Iwamori, K. Noda
    • Organizer
      International Conference on Solid State Devices and Materials
    • Place of Presentation
      Sendai
    • Related Report
      2011 Final Research Report
  • [Remarks] VACUUM2009第31回真空展『物理気相蒸着法により作製したガス吸着膜の特性解明とガス検知センサへの応用』(岩森暁)(in CD-ROM) 2009年9月16日(水)~18日(金)東京ビッグサイト(主催:日本真空工業会・日本真空協会)

    • Related Report
      2011 Final Research Report
  • [Remarks] VACUUM2010第32回真空展『機能性有機薄膜を応用したガス検知センサ・活性酸素種検知センサの開発』(岩森暁)(in CD-ROM) 2010年9月1日(水)~3日(金)東京ビッグサイト(主催:日本真空工業会・日本真空協会)

    • Related Report
      2011 Final Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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