• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Fundamental Study for New Crystal Capsule Formed by Using Nucleation of mutual anti-solvent crystallization

Research Project

Project/Area Number 21560782
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionUniversity of Hyogo

Principal Investigator

MAEDA Kouji  兵庫県立大学, 大学院・工学研究科, 教授 (00264838)

Co-Investigator(Renkei-kenkyūsha) FUKUI Keisuke  兵庫県立大学, 大学院・工学研究科, 教授 (50047635)
Project Period (FY) 2009 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords晶析操作 / Crystal Capsule / Co-Crystals / Anti-Solvent / Co-Solvent / Molecular Dynamics / Nuclei / Spray Dry / Crystal capsule / Co-crystals / Anti-solvent / Co-solvent / Molecular dynamics / Cluster / Spray dry / cluster / Splay dry
Research Abstract

Mixed crystals of crystal capsule structure have been formed by mutual anti-solvent crystallization. One solution is sprayed onto the bulk solution. The mixed crystals were made of aqueous solute (ammonium chloride or glycine) and fatty acid. The structure of the crystals was analyzed by XRD, and it was found that the mixed crystals have two individual crystal patterns of the composed substances. Macroscopic structure was the capsule of aqueous solute crystal surrounded by fatty acid crystals. The long-range structure was also analyzed by SAX of Spring-8, and it was found that the crystal structure of fatty acid was slightly shifted to large structure with ammonium chloride inclusions. The deformation of those capsules was effectively performed by the addition of solvent.

Report

(5 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (35 results)

All 2013 2012 2011 2010 2009 Other

All Journal Article (19 results) (of which Peer Reviewed: 8 results) Presentation (10 results) (of which Invited: 1 results) Book (2 results) Remarks (4 results)

  • [Journal Article] Electrical Conductivity of Aqueous Ethanol Solutions Containing Ammonium Salts under High Pressure at 298 K2013

    • Author(s)
      K. Maeda, K. Maeno, K. Fukui, M. Moritoki, H. Kuramochi
    • Journal Title

      J. Chem. Eng. Data

      Volume: 58 Pages: 264-270

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Journal Article] 水溶性各種リン酸塩の溶解特性とその応用2012

    • Author(s)
      前田光治, 飯村健次, 倉持秀敏, 福井啓介
    • Journal Title

      Bull. Soc. Sea Water Sci. Jpn.

      Volume: 66 Pages: 314-318

    • NAID

      10031126294

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
  • [Journal Article] Liquid Equilibria in Fatty Acid/Triglycerol Systems2012

    • Author(s)
      K. Nishimura, K. Maeda, H. Kuramochi, K. Nakagawa, Y. Asakuma, K. Fukui, M. Osako and S. Sakai
    • Journal Title

      J. Chem. Eng. Data

      Volume: 56(2) Issue: 4 Pages: 1613-1616

    • DOI

      10.1021/je101092j

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Monitoring Nonisothermal Crystallization of Thermoplastic Polymers Using a Quartz Crystal Resonator2011

    • Author(s)
      B-C. Kim, K. Maeda, Y-H. Kim
    • Journal Title

      J. Appl. Polymer Sci.

      Volume: 120 Pages: 3370-3380

    • Related Report
      2012 Final Research Report
  • [Journal Article] De-emulsification of mixtures containing glycerin and fatty acid methyl ester promoted by dimethyl ether co-solvent2011

    • Author(s)
      K. Maeda, H. Kuramochi, K. Fukui, T. Tsuji, M. Osako, S. Sakai
    • Journal Title

      Chem. Eng. J.

      Volume: 169 Pages: 226-230

    • Related Report
      2012 Final Research Report
  • [Journal Article] Solid-Liquid Equilibria in Fatty Acid/Triglycerol Systems2011

    • Author(s)
      K. Nishimura, K. Maeda, H. Kuramochi, K. Nakagawa, K. Fukui, M. Osako, S. Sakai
    • Journal Title

      J. Chem. Eng. Data

      Volume: 56 Pages: 1613-1616

    • Related Report
      2012 Final Research Report
  • [Journal Article] Monitoring Nonisothermal Crystallization of Thermoplastic Polymers Using a Quartz Crystal Resonator2011

    • Author(s)
      B-C.Kim, K.Maeda, Y-H.Kim
    • Journal Title

      J.Appl.Polymer Sci.

      Volume: 120 Issue: 6 Pages: 3370-3380

    • DOI

      10.1002/app.33552

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] De-emulsification of mixtures containing glycerin and fatty acid methyl ester promoted by dimethyl ether co-solvent2011

    • Author(s)
      K.Maeda, H.Kuramochi, K.Fukui, T.Tsuji, M.Osako, S.Sakai
    • Journal Title

      Chem.Eng.J.

      Volume: 169 Issue: 1-3 Pages: 226-230

    • DOI

      10.1016/j.cej.2011.03.017

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nucleation of Ammonium Salts in Aqueous Solution by High Pressure2010

    • Author(s)
      K. Maeda, Y. Asakuma, K. Fukui
    • Journal Title

      J. Phys. Conf. Ser.

      Volume: 215 Pages: 12066-12066

    • Related Report
      2012 Final Research Report
  • [Journal Article] バイオディーゼル関連混合物の融解特性2010

    • Author(s)
      前田光治, 倉持秀敏, 大迫政浩,中川究也, 朝熊裕介, 福井啓介
    • Journal Title

      化学工学論文集

      Volume: 36 Pages: 432-434

    • NAID

      130005042827

    • Related Report
      2012 Final Research Report 2010 Annual Research Report
  • [Journal Article] 海水資源に関する電解質の溶解度モデルの開発2010

    • Author(s)
      前田光治,高本佳典,倉持秀敏,朝熊裕介.福井啓介
    • Journal Title

      Bull. Soc. Sea Water Sci. Jpn.

      Volume: 64 Pages: 329-334

    • NAID

      10028150579

    • Related Report
      2012 Final Research Report
  • [Journal Article] Nucleation of Ammonium Salts in Aqueous Solution by High Pressure2010

    • Author(s)
      K.Maeda, Y.Asakuma, K.Fukui
    • Journal Title

      J.Phys.Conf.Ser.

      Volume: 215 Pages: 12066-12066

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 海水資源に関する電解質の溶解度モデルの開発2010

    • Author(s)
      前田光治, 高本佳典, 倉持秀敏, 朝熊裕介, 福井啓介
    • Journal Title

      日本海水学会誌

      Volume: 64 Pages: 329-334

    • NAID

      10028150579

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Prediction of solid - liquid phase equilibrium in the system of Water (1) + Alcohols (2) + MgSO4 .7H2O (3) + MnSO4 .H2O (4) by the ion-specific electrolyte NRTL model2009

    • Author(s)
      K. Maeda, P. Safaeefar, H-M. Ang, H. Kuramochi, Y. Asakuma, M. O. Tade, K. Fukui
    • Journal Title

      J. Chem. Eng. Data

      Volume: 54 Pages: 423-427

    • Related Report
      2012 Final Research Report
  • [Journal Article] Separation of Fatty Acids from Binary Melts using Physical Vapor Deposition (PVD)2009

    • Author(s)
      Y-H. Kim, S-Y. Jeong, S. Nishitani, K. Maeda, Y. Asakuma, K. Fukui
    • Journal Title

      J. Chem. Technol. Biotechnol.

      Volume: 84 Pages: 316-319

    • Related Report
      2012 Final Research Report
  • [Journal Article] Solid-liquid phase equilibria in the system water + methanol + MgSO4 .7H2O+ MnSO4 .4H2O2009

    • Author(s)
      P. Safaeefar, H.M. Ang, K. Maeda, H. Kuramochi, Y. Asakuma, M.O.Tade, K. Fukui
    • Journal Title

      Fluid Phase Equilibria

      Volume: 277 Pages: 68-72

    • Related Report
      2012 Final Research Report
  • [Journal Article] Prediction of solid-liquid phase equilibrium in the system of Water(1)+Alcohols(2)+MgSO4. 7H2O(3)+MnSO4. H2O(4)by the ion-specific electrolyte NRTL model2009

    • Author(s)
      K.Maeda, P.Safaeefar, H-M.Ang, H.Kuramochi, Y.Asakuma, M.O.Tade, K.Fukui
    • Journal Title

      J.Chem.Eng.Data 54

      Pages: 423-427

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Separation of Fatty Acids from Binary Melts using Physical Vapor Deposition(PVD)2009

    • Author(s)
      Y-H.Kim, S-Y.Jeong, S.Nishitani, K.Maeda, Y.Asakuma, K.Fukui
    • Journal Title

      J.Chem.Technol.Biotechnol., 84, 316-319(2009) 84

      Pages: 316-319

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solid-liquid phase equilibria in the system water+methanol+MgSO4. 7H2O+MnSO4. 4H2O2009

    • Author(s)
      P.Safaeefar, H.M.Ang, K.Maeda, H.Kuramochi, Y.Asakuma, M.O.Tade, K.Fukui
    • Journal Title

      Fluid Phase Equilibria, 277, 68-72(2009) 277

      Pages: 68-72

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Molecular Dynamics of Crystallization Processes2012

    • Author(s)
      K. Maeda, K. Fukui
    • Organizer
      10th Japan-Korea Symposium on Materials & Interface International Symposium on Frontiers in Chemical Engineering
    • Place of Presentation
      Kyoto, JP
    • Year and Date
      2012-11-07
    • Related Report
      2012 Final Research Report
  • [Presentation] Novel Charge/Discharge Method for Lead Acid Battery by High-Pressure Crystallization2012

    • Author(s)
      N. Arakawa, K. Maeda, M. Moritoki, K. Fukui, H. Kuramochi, H. Miki
    • Organizer
      1st Asian Crystallization Technology Symposium (ACTS2012)
    • Place of Presentation
      Seoul, KR
    • Year and Date
      2012-05-23
    • Related Report
      2012 Final Research Report
  • [Presentation] Molecular Dynamics of Crystallization Processes2012

    • Author(s)
      K.Maeda, K.Fukui
    • Organizer
      10th Japan-Korea Symposium on Materials & Interface International Symposium on Frontiers in Chemical Engineering
    • Place of Presentation
      Coop Inn Kyoto(Kyoto)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Novel Charge/Discharge Method for Lead Acid Battery by High-Pressure Crystallization2012

    • Author(s)
      N. Arakawa, K. Maeda, M. Moritoki, K. Fukui, H. Kuramochi, H. Miki
    • Organizer
      1st Asian Crystallization. Technology Symposium
    • Place of Presentation
      Korea Univ.(Seoul),Korea
    • Related Report
      2012 Annual Research Report
  • [Presentation] New Mutual Antisolvent Crystallization Method for Organic and Inorganic Substances2011

    • Author(s)
      N. Arakawa, K. Maeda, K. Fukui
    • Organizer
      Chemeca2011
    • Place of Presentation
      Sydney, AU
    • Year and Date
      2011-09-19
    • Related Report
      2012 Final Research Report
  • [Presentation] New Mutual Antisolvent Crystallization Method for Organic and Inorganic Substances2011

    • Author(s)
      N.Arakawa, K.Maeda, K.Fukui
    • Organizer
      CHEMECA2011, No.403
    • Place of Presentation
      Sydney, AU
    • Year and Date
      2011-09-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] スプレー蒸発法による無機塩+脂肪酸の混晶作成2010

    • Author(s)
      前田光治,森下誠司,朝熊裕介,福井啓介
    • Organizer
      分離技術会年会
    • Place of Presentation
      分離技術会年会
    • Year and Date
      2010-06-04
    • Related Report
      2012 Final Research Report
  • [Presentation] スプレー蒸発法による無機塩+脂肪酸の混晶作成2010

    • Author(s)
      前田光治, 森下誠司, 朝熊裕介, 福井啓介
    • Organizer
      分離技術会年会
    • Place of Presentation
      明治大学(東京都)
    • Year and Date
      2010-06-04
    • Related Report
      2010 Annual Research Report
  • [Presentation] Measurement of the Solubility of Sodium Nitrate in Ethanol and Water Solutions2009

    • Author(s)
      A. Rossiter, P. Safaeefar, K. Black, K. Maeda, H.M. Ang
    • Organizer
      Chemeca 2009
    • Place of Presentation
      Perth, AU
    • Related Report
      2012 Final Research Report
  • [Presentation] MEASUREMENT OF THE SOLUBILITY OF SODIUM NITRATE IN ETHANOL AND WATER SOLUTIONS2009

    • Author(s)
      A.Rossiter, P.Safaeefar, K.Black, K.Maeda, H.M.Ang
    • Organizer
      Chemeca(2009)
    • Place of Presentation
      Perth, Australia
    • Related Report
      2009 Annual Research Report
  • [Book] 分離プロセス工学の基礎2009

    • Author(s)
      前田光治他
    • Total Pages
      240
    • Publisher
      朝倉書店
    • Related Report
      2012 Final Research Report
  • [Book] 分離プロセス工学の基礎2009

    • Author(s)
      前田光治, 他
    • Total Pages
      240
    • Publisher
      朝倉書店
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.eng.u-hyogo.ac.jp/mse/mse10/maeda/member/index.html

    • Related Report
      2012 Final Research Report
  • [Remarks]

    • URL

      http://www.eng.u-hyogo.ac.jp/mse/mse9/sanki4.html

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.eng.u-hyogo.ac.jp/mse/mse9/sanki4.html

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.eng.u-hyogo.ac.jp/mse/mse9/sanki4.html

    • Related Report
      2009 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi