Diblock Copolymer of Cellulose and Poly(methyl methacrylate) Induced by Mechano Chemical Polymerization and its Composite Material
| Project/Area Number |
21580208
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Wood science
|
|---|
| Research Institution | University of Shizuoka |
|---|
Principal Investigator |
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
TAKESHI Ohura 名城大学, 農学部, 准教授 (60315851)
岩田 忠久 東京大学, 大学院・農学生命科学研究科, 准教授 (30281661)
|
|---|
| Project Period (FY) |
2009 – 2011
|
| Project Status |
Completed (Fiscal Year 2011)
|
| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
|
|---|
| Keywords | 環境材料 / 複合材料 / ナノ粒子 / メカノケミカル反応 / セルロース / 1,4グリコシド結合の切断 / ブロック共重合体 / 表面化学修飾 / 透明膜 / β1,4グリコシド結合の切断 |
|---|
| Research Abstract |
The mechanical fracture of microcrystalline cellulose(MCC) in vacuum at 77 K resulted in the production of chain-end-type radicals of MCC(MCC mechano radicals), which were induced by scission of.-1, 4 glycosidic linkages and trapped on the MCC solid surface. A novel block copolymer of MCC and MMA(MCC-block-PMMA) was synthesized on the MCC surface initiated by the MCC mechano radicals. The chemically modified MCC nano particles covered with PMMA chains of MCC-block-PMMA was produced. The composite of chemically modified cellulose nano particles and PMMA improved its physical property. Furthermore, the transparent sheet of the chemically modified cellulose nano particles was obtained.
|
Report
(4 results)
Research Products
(29 results)
