| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Research Abstract |
Some[ 2. 2] paracyclophane-based planar-chiral organocatalysts and ligands were synthesized and evaluated. Bisthiourea organocatalyst whose functionalities are directly connected with[ 2. 2] paracyclophane backbone, acid-base organocatalyst, in which phosphine unit is connected with a cyclopanol via a spacer benzene ring, and C_2-symmetric bis(oxazoline) ligand, both of whose functionalities are connected with[ 2. 2] paracyclophane via a spacer, were found to catalyze organic transformations with high enantiocontrol.
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