Synthesis of macrocyclic compounds that change their conformation depending on the external environment of stimulus
| Project/Area Number |
21590035
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
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| Research Institution | Tokushima Bunri University |
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Principal Investigator |
AZUMAYA Isao 徳島文理大学, 香川薬学部, 教授 (50276755)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | McMurry coupling / ジアゾ化合物 / 分子認識 / 環境応答分子 / 環状分子 / 外部環境応答 / 機能性材料 / 分子包接 / 立体配座 / 大環状化合物 / 芳香族アミド / アゾベンゼン / 単結晶X線構造解析 |
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| Research Abstract |
In this project, large macrocyclic compounds that could change the size of the cavity depending on the external environment or stimulus were synthesized. The macrocyclic compound which contains the amide linkages changed its conformation by chemical introduction or removal of alkyl groups on the amide nitrogens. Furthermore, the macrocyclic compound which contains the azo linkages changed its conformation by irradiating of UV light or heating.
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Report
(4 results)
Research Products
(20 results)
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[Journal Article] Calix[3] amide-based Anion Receptors : High Affinity for Fluoride Ions and a Twisted Binding Model2011
Author(s)
Katagiri, K.; Furuyama, T.; Masu, H.; Kato, T.; Matsumura, M.; Uchiyama, M.; Tanatani, A.; Tominaga, M.; Kagechika, H.; Yamaguchi, K.; Azumaya, I.
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Journal Title
Supramolecular Chemistry
Volume: 23巻
Issue: 1-2
Pages: 125-130
DOI
Related Report
Peer Reviewed
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