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Development of high strength. high modulus dental matrix resin with super-high cross-linked network structure

Research Project

Project/Area Number 21592496
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Dental engineering/Regenerative dentistry
Research InstitutionOkayama University

Principal Investigator

TANAKA Jiro  岡山大学, 大学院・医歯薬学総合研究科, 助教 (40171764)

Co-Investigator(Kenkyū-buntansha) IRIE Masao  岡山大学, 大学院・医歯薬学総合研究科, 助教 (90105594)
HASHIMOTO Yoshiya  大阪歯科大学, 歯学部, 講師 (20228430)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsマトリックスレジン / 架橋構造 / 水素結合 / ポリマーアロイ / 海島構造 / 内分泌撹乱作用 / 吸水特性 / コンポマー / ビニルエステル / 相互侵入網目構造 / 吸水率 / 義歯床 / 電荷移動錯体 / チキソトロピー / コンポジットレジン / 細胞毒性
Research Abstract

The urethane dimethacrylate(UDMA)/methacrylic acid(MAA) resin with the characteristic high cross-linked network structure consist of covalent and hydrogen bonds was improved the mechanical properties(MP) than the conventional dental matrix resins. And the polymerized elastic pastes of multi-functional aliphatic vinyl esters(MFVE) and poly methyl methacrylate(PMMA) were also improved the MP than the commercial acrylic denture base resin. Moreover, the saturated water uptake of vinyl methacrylate(VMA)/PMMA resin was low than that of expectation based on the hydrophilic-lipophilic balance of VMA, and was significantly low than that of MMA/PMMA resin. The characteristic properties of VMA/PMMA resin were anticipated based on the extremely high density cross-linked network structure of poly-VMA.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (49 results)

All 2012 2011 2010 2009 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (37 results) Remarks (1 results) Patent(Industrial Property Rights) (7 results) (of which Overseas: 3 results)

  • [Journal Article] ウレタンジメタクリレート系レジンをマトリックスとしたフィッシャーシーラント材料の試作と物性2011

    • Author(s)
      崎光恵, 入江正郎, 田仲持郎, 長岡紀幸, 森田学
    • Journal Title

      日本歯科理工学会誌

      Volume: Vol.30, No.1 Pages: 63-73

    • NAID

      110008440521

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] ウレタンジメタクリレート系レジンをマトリックスとしたフィッシャーシーラント材料の試作と物性2011

    • Author(s)
      江崎光恵, 入江正郎, 田仲持郎, 長岡紀幸, 森田学
    • Journal Title

      日本歯科理工学会誌

      Volume: 30 Pages: 63-73

    • NAID

      110008440521

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 歯牙硬組織に対するレジンの接着性を促進するN, N'-ジメタクリロイルシスチンによる歯面処理2009

    • Author(s)
      田仲持郎, 宝力道, 鈴木一臣
    • Journal Title

      岡山歯学会誌

      Volume: Vol.28, No.2 Pages: 157-162

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 硬組織に対するレジンの接着性を促進するN, N'-ジメタクリロイルシスチンによる歯面処理2009

    • Author(s)
      田仲持郎
    • Journal Title

      岡山歯学会雑誌 28

      Pages: 157-162

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Effect of Primers on Bonding of Resin Cements to Ceramics2012

    • Author(s)
      Irie Masao
    • Organizer
      The AADR Annual Meeting
    • Place of Presentation
      Tampa Convention Center(USA)
    • Year and Date
      2012-03-23
    • Related Report
      2011 Final Research Report
  • [Presentation] Effect of Primers on Bonding of Resin Cements to Ceramics2012

    • Author(s)
      M.IRIE, J.TANAKA, Y.TAMADA, Y.MARUO, G.NISHIGAWA, Y.YAMAMOTO, S.MINAGI, D.C.WATTS
    • Organizer
      41th Annual Meeting of The American Association for
    • Place of Presentation
      Tampa Convention Center (Tampa, USA)
    • Year and Date
      2012-03-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] Adaptation of PMMA/divinyl adipate resin for denture base2012

    • Author(s)
      Hara Tetsuya
    • Organizer
      The AADR Annual Meeting
    • Place of Presentation
      Tampa Convention Center(USA)
    • Year and Date
      2012-03-22
    • Related Report
      2011 Final Research Report
  • [Presentation] Adaptation of PMMA/divinyl adipate resin for denture base2012

    • Author(s)
      Hara T, TANAKA J, Iida S, Miyazaki T, Sakamoto S, Kuroda C, Oka M, Matsumoto T, Minagi S
    • Organizer
      41th Annual Meeting of The American Association for
    • Place of Presentation
      Tampa Convention Center (Tampa, USA)
    • Year and Date
      2012-03-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] フロアブルコンポジット:曲げ特性と歯質接着強さとの関係2012

    • Author(s)
      入江正郎
    • Organizer
      第30回日本接着歯学会学術大会
    • Place of Presentation
      函館市民会館
    • Year and Date
      2012-01-22
    • Related Report
      2011 Final Research Report
  • [Presentation] フロアブルコンポジット:曲げ特性と歯質接着強さとの関係について2012

    • Author(s)
      入江正郎, 田仲持郎, 玉田宜之, 丸尾幸憲, 西川悟郎
    • Organizer
      第30回日本接着歯学会学術大会
    • Place of Presentation
      函館市民会館(函館)
    • Year and Date
      2012-01-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] 多様な特性を簡単に創造出来る医療用ポリマー素材2011

    • Author(s)
      田仲持郎
    • Organizer
      知恵の見本市2011
    • Place of Presentation
      岡山大学創立五十周年記念館
    • Year and Date
      2011-11-02
    • Related Report
      2011 Final Research Report
  • [Presentation] 多様な特性を簡単に創造出来る医療用ポリマー素材2011

    • Author(s)
      田仲持郎
    • Organizer
      知恵の見本市2011
    • Place of Presentation
      岡山大学創立五十周年記念館(岡山)
    • Year and Date
      2011-11-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] 動的粘弾性挙動制御に基づく歯科インプラント上部構造体浮き上がり量の抑制2011

    • Author(s)
      田仲持郎
    • Organizer
      第58回日本歯科理工学会学術講演会
    • Place of Presentation
      奥羽大学歯学部
    • Year and Date
      2011-10-23
    • Related Report
      2011 Final Research Report
  • [Presentation] 動的粘弾性挙動制御に基づく歯科インプラント上部構造体浮き上がり量の抑制2011

    • Author(s)
      田仲持郎, 宝力道, 入江正郎, 鈴木一臣
    • Organizer
      平成23年度第58回秋期日本歯科理工学会学術講演会
    • Place of Presentation
      奥羽大学歯学部(郡山)
    • Year and Date
      2011-10-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] 簡単な操作で多様な特性を創造出来る医療用ポリマー素材2011

    • Author(s)
      田仲持郎
    • Organizer
      平成23年度日本歯科理工学会近畿・中四国支部夏期セミナー
    • Place of Presentation
      南淡路休暇村
    • Year and Date
      2011-08-29
    • Related Report
      2011 Final Research Report
  • [Presentation] 簡便な操作で多様な特性を創造出来る医療用ポリマー素材2011

    • Author(s)
      田仲持郎
    • Organizer
      平成23年度日本歯科理工学会近畿・中四国支部夏期セミナー
    • Place of Presentation
      南淡路休暇村(南あわじ市)
    • Year and Date
      2011-08-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] Flexural properties of thermo-polymerized PMMA/ethylene glycol dimethacrylates pastes2011

    • Author(s)
      Tanaka Jiro
    • Organizer
      International Dental Materials Congress 2011
    • Place of Presentation
      Yonsei University(Korea)
    • Year and Date
      2011-05-28
    • Related Report
      2011 Final Research Report
  • [Presentation] Flexural properties of thermo-polymerized PMMA/ethylente glycol dimethacrylates2011

    • Author(s)
      Tanaka J, Stansbury JW, Antonucci JM, Suzuki K
    • Organizer
      International Dental Materials Congress 2011
    • Place of Presentation
      Eun-Myung, Auditorium, Yonsei Univ. (Seoul)
    • Year and Date
      2011-05-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] PMMA/アジピン酸ジビニル系レジンの義歯床への応用2011

    • Author(s)
      原哲也
    • Organizer
      第120回日本補綴歯科学会学術大会
    • Place of Presentation
      広島国際会議場
    • Year and Date
      2011-05-21
    • Related Report
      2011 Final Research Report
  • [Presentation] PMMA/アジピン酸ジビニル系レジンの義歯床への応用2011

    • Author(s)
      原哲也, 田仲持郎, 鈴木一臣, 皆木省吾
    • Organizer
      日本補綴歯科学会第120回記念学術大会
    • Place of Presentation
      広島国際会議場(広島)
    • Year and Date
      2011-05-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] 簡単な操作で多様な特性を創造出来る医療用ポリマーアロイ2010

    • Author(s)
      田仲持郎
    • Organizer
      知恵の見本市2010
    • Place of Presentation
      岡山大学創立五十周年記念館
    • Year and Date
      2010-11-05
    • Related Report
      2011 Final Research Report
  • [Presentation] 簡便な操作で多様な特性を創造出来る医療用ポリマーアロイ2010

    • Author(s)
      田仲持郎
    • Organizer
      知恵の見本市2010
    • Place of Presentation
      岡山大学創立五十周年記念館(岡山)
    • Year and Date
      2010-11-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] 試作レジンセメントの粘弾性特性に及ぼすフィラーの影響2010

    • Author(s)
      宝力道
    • Organizer
      第56回日本歯科理工学会学術講演会
    • Place of Presentation
      長良川国際会議場
    • Year and Date
      2010-10-10
    • Related Report
      2011 Final Research Report
  • [Presentation] ビニルエステル/ポリマー系軟性樹脂組成物(第10報)-VE/PEMA系混和物の理論的硬化時間に及ぼすVEの分子構造の影響-2010

    • Author(s)
      田仲持郎
    • Organizer
      第56回日本歯科理工学会学術講演会
    • Place of Presentation
      長良川国際会議場
    • Year and Date
      2010-10-10
    • Related Report
      2011 Final Research Report
  • [Presentation] ビニルエステル/ポリマー系軟性樹脂組成物(第10報)-VE/PEMA系混和物の理論的硬化時間に及ぼすVEの分子構造の影響-2010

    • Author(s)
      田仲持郎, 橋本典也, 武田昭二, 鈴木一臣
    • Organizer
      第56回日本歯科理工学会学術講演会
    • Place of Presentation
      長良川国際会議場(岐阜)
    • Year and Date
      2010-10-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] 試作レジンセメントの粘弾性特性に及ぼすフィラーの影響2010

    • Author(s)
      宝力道, 田仲持郎, 鈴木一臣
    • Organizer
      第56回日本歯科理工学会学術講演会
    • Place of Presentation
      長良川国際会議場(岐阜)
    • Year and Date
      2010-10-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] 機能再生・再建への応用を目指した医療用ポリマーアロイの創製2010

    • Author(s)
      田仲持郎
    • Organizer
      機能再生・再建科学専攻シンポジウム
    • Place of Presentation
      岡山大学
    • Year and Date
      2010-08-24
    • Related Report
      2011 Final Research Report
  • [Presentation] 操作性に優れる医療用ポリマーアロイ2010

    • Author(s)
      田仲持郎
    • Organizer
      中国地域さんさんコンソ新技術説明会
    • Place of Presentation
      JSTホール
    • Year and Date
      2010-08-20
    • Related Report
      2011 Final Research Report
  • [Presentation] 操作性に優れる医療用ポリマーアロイ2010

    • Author(s)
      田仲持郎
    • Organizer
      中国地域さんさんコンソ新技術説明会
    • Place of Presentation
      JSTホール(東京)
    • Year and Date
      2010-08-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] Characteristic Flexural Properties of Thermo-Polymerized Divinyl Adipate/PMMA Pastes2010

    • Author(s)
      Tanaka Jiro
    • Organizer
      88^<th> General Session & Exhibition of the IADR
    • Place of Presentation
      Centre Convencions Internacional Barcelona
    • Year and Date
      2010-07-16
    • Related Report
      2011 Final Research Report
  • [Presentation] Characteristic Flexural Properties of Thermo-Polymerized Divinyl Adipate/PMMA Pastes2010

    • Author(s)
      Tanaka J, Stansbury JW, Antonucci JM, Hashimoto Y, Takeda S, Suzuki K
    • Organizer
      88th IADR
    • Place of Presentation
      Centre Convencions International Barcelona (Barcelona, Sapin)
    • Year and Date
      2010-07-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] ビニルエステル/ポリマー系軟性樹脂組成物(第9報)-ジビニルエステル/PMMA系混和物重合体の曲げ特性に及ぼす重合性基間距離の影響-2010

    • Author(s)
      田仲持郎
    • Organizer
      第55回日本歯科理工学会学術講演会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2010-04-18
    • Related Report
      2011 Final Research Report
  • [Presentation] ビニルエステル/ポリマー系軟性樹脂組成物(第9報)-ジビニルエステル/PMMA系混和物重合体の曲げ特性に及ぼす重合基間距離の影響-2010

    • Author(s)
      田仲持郎, 橋本典也, 武田昭二, 鈴木一臣
    • Organizer
      第55回日本歯科理工学会学術講演会
    • Place of Presentation
      タワーホール船堀(東京)
    • Year and Date
      2010-04-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] 簡単な操作で多様な特性を創り出せる医療用レジンマトリックス素材2010

    • Author(s)
      田仲持郎
    • Organizer
      Bio Japan 2010-World Business Forum-
    • Place of Presentation
      横浜パシフィコ
    • Related Report
      2011 Final Research Report
  • [Presentation] 簡便な操作で多様な特性を創り出せる医療用レジンマトリックス素材(Medical resin matrix meterials make various characteristics possible with easy handling)2010

    • Author(s)
      田仲持郎
    • Organizer
      Bio Japan 2010-World Business Forum-
    • Place of Presentation
      横浜パシフィコ(横浜)
    • Related Report
      2010 Annual Research Report
  • [Presentation] ジビニルエステル/PMMA系分子複合レジンを用いる義歯床用レジン素材の開発2009

    • Author(s)
      田仲持郎
    • Organizer
      平成21年度日本補綴歯科学会関西支部・中四国支部総会ならびに合同学術大会
    • Place of Presentation
      淡路夢舞台国際会議場
    • Year and Date
      2009-11-15
    • Related Report
      2011 Final Research Report
  • [Presentation] ジビニルエステル/PMMA系分子複合レジンを用いる義歯床用レジン素材の開発2009

    • Author(s)
      田仲持郎
    • Organizer
      平成21年度(社)日本補綴歯科学会関西・中四国支部合同学術大会
    • Place of Presentation
      淡路夢舞台国際会議場(兵庫県)
    • Year and Date
      2009-11-15
    • Related Report
      2009 Annual Research Report
  • [Presentation] ビニルエステル/ポリマー系軟性樹脂組成物(第8報)-義歯床用レジンとしての可能性-2009

    • Author(s)
      田仲持郎
    • Organizer
      第54回日本歯科理工学会学術講演会
    • Place of Presentation
      かごしま県民交流センター
    • Year and Date
      2009-10-02
    • Related Report
      2011 Final Research Report
  • [Presentation] ビニルエステル/ポリマー系軟性樹脂組成物(第8報)-義歯床用レジンとしての可能性-2009

    • Author(s)
      田仲持郎
    • Organizer
      平成21年度秋期第54回日本歯科理工学会学術講演会
    • Place of Presentation
      かごしま県民交流センター(鹿児島県)
    • Year and Date
      2009-10-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] ビニルエステル/ポリマー系軟性樹脂組成物(第7報)-樹脂組成物重合体の機械的性質に及ぼすポリマーの影響-2009

    • Author(s)
      田仲持郎
    • Organizer
      第53回日本歯科理工学会学術講演会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2009-04-12
    • Related Report
      2011 Final Research Report
  • [Presentation] Characteristic Viscoelasticity of Denture Liner Using Vinyl Ester/PEMA Paste2009

    • Author(s)
      Tanaka Jiro
    • Organizer
      87^<th> General Session & Exhibition of the IADR
    • Place of Presentation
      Miami Beach Convention Centre(USA)
    • Year and Date
      2009-04-02
    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://www.dent.okayama-u.ac.jp/rikou/Welcom.html

    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 組成物及びその製造方法2012

    • Inventor(s)
      田仲持郎
    • Industrial Property Rights Holder
      国立大学法人岡山大学
    • Industrial Property Number
      2012-061041
    • Filing Date
      2012-03-16
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Patent(Industrial Property Rights)] Process for Producing Resin Composition and Process for Producing Molded Article.2011

    • Inventor(s)
      Tanaka Jiro, Kazuomi Suzuki
    • Industrial Property Rights Holder
      National University Corporation Okayama University
    • Filing Date
      2011-08-12
    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 医療用樹脂組成物及び製造方法並びに医療用キット2011

    • Inventor(s)
      田仲持郎
    • Industrial Property Rights Holder
      国立大学法人岡山大学
    • Filing Date
      2011-01-19
    • Related Report
      2011 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] Process for Producing Resin Composition and Process for Producing Molded Article2011

    • Inventor(s)
      Jiro TANAKA, Kazuomi SUZUKI
    • Industrial Property Rights Holder
      Okayama University
    • Filing Date
      2011-08-12
    • Related Report
      2011 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 医療用樹脂組成物及びその製造方法並びに医療用キット2011

    • Inventor(s)
      田仲持郎
    • Industrial Property Rights Holder
      岡山大学
    • Filing Date
      2011-01-20
    • Related Report
      2010 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 医療用樹脂組成物及びその製造方法並びに医療用キット2010

    • Inventor(s)
      田仲持郎
    • Industrial Property Rights Holder
      国立大学法人岡山大学
    • Industrial Property Number
      2010-010216
    • Filing Date
      2010-01-20
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Patent(Industrial Property Rights)] 歯科・整形外科用樹脂組成物,その製造方法及び歯科・整形外科用成型品の製造方法2010

    • Inventor(s)
      田仲持郎,鈴木一臣
    • Industrial Property Rights Holder
      国立大学法人岡山大学
    • Acquisition Date
      2010-04-16
    • Related Report
      2011 Final Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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