| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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| Research Abstract |
Reactions of alkynes and alkenes with hydropolysilanes, which have a consecutive silicon chain terminated with hydrogen, have proved to efficiently proceed in the presence of AlCl_3 or B(C_6F_5)_3 without losing the structural integrity of the silicon chain to afford adducts in high yields. These hydropolysilanes also react with alcohols in the presence of copper catalysts to furnish alkoxypolysilanes. Furthermore, rhodium complexes have proved to be efficient in catalytic formation of arylpolysiloxanes when aryl halides are reacted with hydropolysiloxane.
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