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Glucose production from cellulose using ionic liquids

Research Project

Project/Area Number 21655057
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Environmental chemistry
Research InstitutionYamaguchi University

Principal Investigator

KAMIMURA Akio  山口大学, 大学院・医学系研究科, 教授 (30194971)

Research Collaborator OYAMA Natsumi  山口大学, 大学院・医学系研究科, 修士課程学生
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,340,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥240,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2009: ¥1,400,000 (Direct Cost: ¥1,400,000)
Keywordsセルロース / イオン液体 / グルコース / マイクロ波 / 解重合 / 加水分解 / マイクロウエーブ
Research Abstract

A new method to produce glucose from cellulose was developed. A mixture of cellulose, hydrochloric acid, and lithium chloride in hydrophobic ionic liquids provided efficient hydrolysis of cellulose to give glucose more than 40% yield. A selective formation of glucose was achieved under these conditions. Glucose was isolated without contamination of ionic liquids, which potentially inhibit fermentation of glucose to produce ethanol. The ionic liquids were recovered in more than 99% and used for the hydrolysis for several iterations without loss of efficiency. The yield of glucose increased as the amounts of lithium chloride increased.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (7 results)

All 2011 Other

All Presentation (6 results) Remarks (1 results)

  • [Presentation] 疎水性イオン液体を用いたセルロースの解重合反応2011

    • Author(s)
      大山奈津美, 上村明男, 吉本誠
    • Organizer
      第2回イオン液体科学研究会
    • Place of Presentation
      京都市、キャンパスプラザ京都
    • Year and Date
      2011-12-17
    • Related Report
      2011 Final Research Report
  • [Presentation] 疎水性イオン液体を用いたセルロースの解重合反応2011

    • Author(s)
      大山奈津美
    • Organizer
      第2回イオン液体科学研究会
    • Place of Presentation
      キャンパスプラザ京都(京都)
    • Year and Date
      2011-12-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] イオン液体/マイクロ波照射を用いたセルロースの新しい解重合2011

    • Author(s)
      大山奈津美, 上村明男
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      徳島市、徳島大学常三島キャンパス
    • Year and Date
      2011-11-12
    • Related Report
      2011 Final Research Report
  • [Presentation] Combination use of ionic liquids and microwave irradiation : a new method for feedstock recycling of polymers2011

    • Author(s)
      Akio Kamimura
    • Organizer
      9th Green Chemistry Conference
    • Place of Presentation
      Alcala、Spain
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] Combination use of ionic liquids and microwave irradiation : a new method for feedstock recycling of polymers2011

    • Author(s)
      Akio Kamimura, Shigehiro Yamamoto, Natsumi Oyama, Hiroki Okagawa, Makoto Yoshimoto, Kouji Kaiso
    • Organizer
      9th Green Chemistry Conference
    • Place of Presentation
      Universidad de Alcala de Henares, Alcala, Spain
    • Year and Date
      2011-09-14
    • Related Report
      2011 Final Research Report
  • [Presentation] イオン液体/マイクロ波照射を用いたセルロースの新しい解重合2011

    • Author(s)
      大山奈津美・上村明男
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川県神奈川大学
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://perkin.chem.yamaguchi-u.ac.jp

    • Related Report
      2011 Final Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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