Development of supported molecular catalysts on star-shape polymers and their use as catalysts for green-sustainable synthetic process
| Project/Area Number |
21656209
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Catalyst/Resource chemical process
|
|---|
| Research Institution | Tokyo Metropolitan University (2010-2011)
Nara Institute of Science and Technology (2009) |
|---|
Principal Investigator |
NOMURA Kotohiro 首都大学東京, 大学院・理工学研究科, 教授 (20304165)
|
|---|
| Project Period (FY) |
2009 – 2011
|
| Project Status |
Completed (Fiscal Year 2011)
|
| Budget Amount *help |
¥3,370,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,300,000)
|
|---|
| Keywords | 固定化触媒 / リビング重合 / 均一系錯体触媒 / オレフィンメタセシス / 環境調和型合成技術 / 開環メタセシス重合 / 球状ポリマー |
|---|
| Research Abstract |
Soluble' star shape polymers containing pyridine ligand at the chain ends, prepared by adopting sequential living ring-opening metathesis polymerizations of norbornene and cross-linking reagent using Mo-alkylidene catalyst via' core-first' approach, have been employed as ligands for Ru catalyzed chemoselective hydrogen transfer reductions of various ketones. The catalyst can be recovered quantitatively, and reused without decreasing in the activity and the selectivity.
|
Report
(4 results)
Research Products
(35 results)
