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Intermolecular interactions for polarizability and dipole moment in ionic liquid: To construct solution theory including ionic liquid

Research Project

Project/Area Number 21685001
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Physical chemistry
Research InstitutionChiba University

Principal Investigator

SHIROTA Hideaki  千葉大学, 大学院・融合科学研究科, 准教授 (00292780)

Project Period (FY) 2009 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥27,690,000 (Direct Cost: ¥21,300,000、Indirect Cost: ¥6,390,000)
Fiscal Year 2012: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2011: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2010: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2009: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000)
Keywords分子分光 / イオン液体 / 分子ダイナミクス / フェムト秒光カー効果分光 / 分子間振動 / 分子間相互作用
Research Abstract

The aim of this reserach project includes understanding the microscopic intermolecular interaction and structure of ionic liquid through the intermolecular vibration. Since the intermolecular vibrational band in condensed phases appears in the low-frequency region below 50 cm-1, low-frequency spectroscopic techniques are essential to observe the intermolecular vibrations. In this project, it is successful to build a very high spec femtosecond Raman-induced Kerr effect spectroscopy setup as a single light source apparatus which has a wide observable frequency region and high signal to noise ratio. Using this spectroscopy setup, we successfully reveal the unique natures of the intermolecular vibrational band of ionic liquid at molecular level: (1) similarity/difference between aromatic and nonaromatic ionic liquids, (2) generality of heavy atom substitution (cation vs. anion and aromatic vs. nonaromatic), (3) similarity/difference between ionic liquid and (neutral) molecular liquid, and (4) dicationic vs. monocationic ionic liquids These results have been summarized in a book chapter (Ionic Liquids: Theory, Properties, New Approaches, Chapter 9) and a review article (ChemPhysChem, 2012, 13, 1638: classified as VIP (Very Important Paper)). Also, we have started some collaboration works with domestic and international groups through this research project.

Report

(5 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (111 results)

All 2013 2012 2011 2010 2009 Other

All Journal Article (52 results) (of which Peer Reviewed: 48 results) Presentation (51 results) (of which Invited: 1 results) Book (2 results) Remarks (6 results)

  • [Journal Article] E. W. Castner, Jr.Differences in Ion Interactions for Isoelectronic Ionic Liquid Homologs2013

    • Author(s)
      H. Y. Lee, H. Shirota
    • Journal Title

      J. Phys. Chem. Lett

      Volume: 4(9) Pages: 1477-1483

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dicationic versusMonocationic Ionic Liquids: Distinctive Ionic Dynamics and Dynamical Heterogeneity2013

    • Author(s)
      T. Ishida, H. Shirota.
    • Journal Title

      J. Phys. Chem. B

      Volume: 117(4) Pages: 1136-1150

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] How does the Ionic Liquid Organizational Landscape Change when Nonpolar Cationic Alkyl Groups are Replaced by Polar Isoelectronic Diethers?2013

    • Author(s)
      H. K. Kashyap, C. S. Santos, R. P. Daly, J. J.Hettige, N. S. Murthy, H. Shirota, E. W.Castner, Jr., C. J. Margulis.
    • Journal Title

      J. Phys. Chem. B

      Volume: 117(4) Pages: 1130-1135

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] How does the Ionic Liquid Organizational Landscape Change when Nonpolar Cationic Alkyl Groups are Replaced by Polar Isoelectronic Diethers?2013

    • Author(s)
      Hemant K. Kashyap, Cherry S. Santos, Ryan P. Daly, Jeevapani J. Hettige, N. Sanjeeva Murthy, Hideaki Shirota, Edward W. Castner, Jr., Claudio J. Margulis.
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 117 Issue: 4 Pages: 1130-1135

    • DOI

      10.1021/jp311032p

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dicationic versus Monocationic Ionic Liquids: Distinctive Ionic Dynamics and Dynamical Heterogeneity.2013

    • Author(s)
      Tateki Ishida, Hideaki Shirota.
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 117 Issue: 4 Pages: 1136-1150

    • DOI

      10.1021/jp3110425

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] フェムト秒ラマン誘起カー効果分光による液体・溶液のテラヘルツ領域の分子運動の観測2012

    • Author(s)
      城田秀明
    • Journal Title

      日本赤外線学会誌

      Volume: 22(1) Pages: 40-49

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Comparison of Low-FrequencySpectra between Aromatic and Nonaromatic Cation Based Ionic Liquids Using Femtosecond Raman-Induced Kerr Effect Spectroscopy.2012

    • Author(s)
      H. Shirota.
    • Journal Title

      ChemPhysChem

      Volume: 13(7) Pages: 1638-1648

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Intermolecular/Interionic Vibrations of1-Methyl-3-n-octylimidazolium Tetrafluoroborate Ionic Liquid and H2O Mixtures2012

    • Author(s)
      H. Shirota, R. Biswas.
    • Journal Title

      J. Phys. Chem. B

      Volume: 116(46) Pages: 13765-13773

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] High-Pressure Crystallization of1-Methyl-3-trimethylsilylmethylimidazolium Tetrafluoroborate Ionic Liquid2012

    • Author(s)
      L. Hawelek, H. Shirota, J. Kusz, K.Grzybowska, M. Mierzwa, M. Paluch, A. Burian, J. Ziolo.
    • Journal Title

      Chem. Phys. Lett.

      Volume: 546 Pages: 150-152

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] H. Y. Lee, C. S. Santos, N. S. Murthy, and E. W. Castner, Jr. Comparing Intermediate Range Order for Alkyl- vs. Ether-Substituted Cations in Ionic Liquids2012

    • Author(s)
      A. Triolo, O. Russina, R. Caminiti, H. Shirota
    • Journal Title

      Chem. Commun.

      Volume: 48(41) Pages: 4959-4961

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Shear Relaxation of Ammonium- and Phosphonium-Based Ionic Liquids with Oxyethylene Chain2012

    • Author(s)
      T. Yamaguchi, K. Mikawa, S. Koda, H.Fukazawa, H. Shirota.
    • Journal Title

      Chem. Phys. Lett.

      Volume: 521 Pages: 69-73

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Comparing Intermediate Range Order for Alkyl- vs. Ether-Substituted Cations in Ionic Liquids.2012

    • Author(s)
      Alessandro Triolo, Olga Russina, Ruggero Caminiti, Hideaki Shirota, Heather Y. Lee, Cherry S. Santos, N. Sanjeeva Murthy, Edward W Castner, Jr.
    • Journal Title

      Chemical Communications

      Volume: 48 Issue: 41 Pages: 4959-4961

    • DOI

      10.1039/c2cc31550e

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparison of low-frequency spectra between aromatic and nonaromatic cation based ionic liquids using femtosecond Raman-induced Kerr effect spectroscopy.(「イオン液体」特集号,招待,VIP (Very Important Paper) に選定)2012

    • Author(s)
      Hideaki Shirota.
    • Journal Title

      ChemPhysChem

      Volume: 13 Issue: 7 Pages: 1638-1648

    • DOI

      10.1002/cphc.201100731

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] フェムト秒ラマン誘起カー効果分光による液体・溶液のテラヘルツ領域の分子運動の観測(「赤外領域における液体,生体高分子の分光測定」特集号,招待)2012

    • Author(s)
      城田秀明
    • Journal Title

      日本赤外線学会誌

      Volume: 22 Pages: 40-49

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-Pressure Crystallization of 1-Methyl-3-trimethylsilylmethylimidazolium Tetrafluoroborate Ionic Liquid.2012

    • Author(s)
      Lukasz Hawelek, Hideaki Shirota, Joachim Kusz, Katarzyna Grzybowska, Michal Mierzwa, Marian Paluch, Andrzej Burian, Jerzy Ziolo.
    • Journal Title

      Chemical Physics Letters

      Volume: 546 Pages: 150-152

    • DOI

      10.1016/j.cplett.2012.07.041

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Intermolecular/Interionic Vibrations of 1-Methyl-3-n-octylimidazolium Tetrafluoroborate Ionic Liquid and H2O Mixtures.2012

    • Author(s)
      Hideaki Shirota, Ranjit Biswas.
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 116 Issue: 46 Pages: 13765-13773

    • DOI

      10.1021/jp307436t

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Shear Relaxation of Ammonium- and Phosphonium-Based Ionic Liquids with Oxyethylene Chain2012

    • Author(s)
      Tsuyoshi Yamaguchi, Ken-ichi Mikawa, Shinobu Koda, Hiroki Fukazawa, Hideaki Shirota
    • Journal Title

      Chemical Physics Letters

      Volume: 521 Pages: 69-73

    • DOI

      10.1016/j.cplett.2011.11.053

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparing Intermediate Range Order for Alkyl-vs.Ether-Substituted Cations in Ionic Liquids2012

    • Author(s)
      Alessandro Triolo, Olga Russina, Ruggero Caminiti, Hideaki Shirota, Heather Y.Lee, Cherry S.Santos, N.Sanjeeva Murthy, Edward W.Castner, Jr.
    • Journal Title

      Chemical Communications

      Volume: (印刷中)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparison of Low-Frequency Spectra between Aromatic and Nonaromatic Cation Based Ionic Liquids Using Femtosecond Raman-Induced Kerr Effect Spectroscopy2012

    • Author(s)
      Hideaki Shirota
    • Journal Title

      ChemPhysChem

      Volume: (印刷中)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrafast Dynamics in Room Temperature Ionic Liquids Studied by Femtosecond Raman-Induced Kerr Effect Spectroscopy2012

    • Author(s)
      Tatsuya Kato, Hideaki Shirota
    • Journal Title

      Proceedings of TSRP-2012

      Pages: 32-34

    • Related Report
      2011 Annual Research Report
  • [Journal Article] Intermolecular Vibrations andDiffusive Orientational Dynamics of CsCondensed Ring Aromatic MolecularLiquids2011

    • Author(s)
      H. Shirota.
    • Journal Title

      J. Phys. Chem. A

      Volume: 115 (50) Pages: 14262-14275

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Glass Transition Dynamics of Room Temperature Ionic Liquid:1-Methyl-3-trimethylsilylmethylimidazoliumTetrafluoroborate2011

    • Author(s)
      G. Jarosz, M. Mierzwa, J. Ziolo, M. Paluch, H. Shirota, K. L. Ngai.
    • Journal Title

      J. Phys. Chem. B

      Volume: 115(44) Pages: 12709-12716

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Low-frequency Modes of the Benzoic Acid Dimer in Chloroform Observed by the Optical Kerr Effect2011

    • Author(s)
      S. Yamaguchi, K. Mazur, I. A. Heisler, H. Shirota, K. Tominaga, S. R. Meech
    • Journal Title

      J. Chem. Phys.

      Volume: 135(13)

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Microscopic Aspects inDicationic Ionic Liquids through theLow-Frequency Spectra by Femtosecond Raman-Induced Kerr Effect Spectroscopy2011

    • Author(s)
      H. Shirota, T. Ishida.
    • Journal Title

      J. Phys. Chem. B

      Volume: 115(37) Pages: 10860-10870

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Intermolecular Vibrational Spectra of C_3v CXY_3 Molecular Liquids, CHCl_3, CHBr_3, CFBr_3, and CBrCl_32011

    • Author(s)
      H. Shirota, T. Kato.
    • Journal Title

      J. Phys. Chem. A

      Volume: 115(32) Pages: 8797-8807

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] IntermolecularVibrational Modes and Orientational Dynamics of Cooperative Hydrogen-Bonding Dimer of 7-Azaindole in Solution2011

    • Author(s)
      T. Kato, H. Shirota.
    • Journal Title

      J. Chem. Phys.

      Volume: 134(16)

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ultrafast Dynamics in1-Butyl-3-Methylimidazolium-Based Ionic Liquids: A Femtosecond Raman-Induced Kerr Effect Spectroscopic Study2011

    • Author(s)
      H. Fukazawa, T. Ishida, H. Shirota.
    • Journal Title

      J. Phys. Chem. B

      Volume: 115(16) Pages: 4621-4631

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Comparison between Dicationic and Monocationic Ionic Liquids: Liquid Density, Thermal Properties, Surface Tension, and Shear Viscosity2011

    • Author(s)
      H. Shirota, T. Mandai, H. Fukazawa, T. Kato.
    • Journal Title

      J. Chem. Eng. Data

      Volume: 56(5) Pages: 2453-2459

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ultrafast Dynamics in 1-Butyl-3-methylimidazolium-Based Ionic Liquids : A Femtosecond Raman-Induced Kerr Effect Spectroscopic Study2011

    • Author(s)
      Hiroki Fukazawa, Tateki Ishida, Hideaki Shirota
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 115 Issue: 16 Pages: 4621-4631

    • DOI

      10.1021/jp200370f

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Intermolecular Vibrational Modes and Orientational Dynamics of Cooperative Hydrogen-Bonding Dimer of 7-Azaindole in Solution2011

    • Author(s)
      Tatsuya Kato, Hideaki Shirota
    • Journal Title

      Journal of Chemical Physics

      Volume: 134 Issue: 16

    • DOI

      10.1063/1.3583642

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparison between Dicationic and Monocationic Ionic Liquids : Liquid Density, Thermal Properties, Surface Tension, and Shear Viscosity2011

    • Author(s)
      Hideaki Shirota, Toshihiko Mandai, Hiroki Fukazawa, Tatsuya Kato
    • Journal Title

      Journal of Chemical & Engineering Data

      Volume: 56 Issue: 5 Pages: 2453-2459

    • DOI

      10.1021/je2000183

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Intermolecular Vibrational Spectra of C_<3v> CXY_3 Molecular Liquids, CHCl_3, CHBr_3, CFBr_3, and CBrCl_32011

    • Author(s)
      Hideaki Shirota, Tatsuya Kato
    • Journal Title

      Journal of Physical Chemistry A

      Volume: 115 Issue: 32 Pages: 8797-8807

    • DOI

      10.1021/jp203255u

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microscopic Aspects in Dicationic Ionic Liquids through the Low-Frequency Spectra by Femtosecond Raman-Induced Kerr Effect Spectroscopy2011

    • Author(s)
      Hideaki Shirota, Tateki Ishida
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 115 Issue: 37 Pages: 10860-10870

    • DOI

      10.1021/jp206266e

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low-frequency Modes of the Benzoic Acid Dimer in Chloroform Observed by the Optical Kerr Effect2011

    • Author(s)
      Sayuri Yamaguchi, Kamila Mazur, Ismael A.Heisler, Hideaki Shirota, Keisuke Tominaga, Stephen R.Meech
    • Journal Title

      Journal of Chemical Physics

      Volume: 135 Issue: 13

    • DOI

      10.1063/1.3635778

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Glass Transition Dynamics of Room Temperature Ionic Liquid : 1-Methyl-3-trimethylsilylmethylimidazolium Tetrafluoroborate2011

    • Author(s)
      Georgina Jarosz, Michal Mierzwa, Jerzy Ziolo, Marian Paluch, Hideaki Shirota, Kia L.Ngai
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 115 Issue: 44 Pages: 12709-12716

    • DOI

      10.1021/jp207291k

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Intermolecular Vibrations and Diffusive Orientational Dynamics of C_s Condensed Ring Aromatic Molecular Liquids2011

    • Author(s)
      Hideaki Shirota
    • Journal Title

      Journal of Physical Chemistry A

      Volume: 115 Issue: 50 Pages: 14262-14275

    • DOI

      10.1021/jp208389n

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Heavy Atom Substitution Effects in Non-Aromatic Ionic Liquids: UltrafastDynamics and Physical Properties2010

    • Author(s)
      H. Shirota, H. Fukazawa, T. Fujisawa, J. F.Wishart.
    • Journal Title

      J. Phys. Chem. B

      Volume: 114(29) Pages: 9400-9412

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Microscopic Study of Ionic Liquid-H2O Systems: Alkyl-Group Dependence of1-Alkyl-3-Methylimidazolium Cation2010

    • Author(s)
      T. Masaki, K. Nishikawa, H. Shirota.
    • Journal Title

      J. Phys. Chem. B

      Volume: 114(19) Pages: 6323-6331

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Microscopic Study of Ionic Liquid-H_2O Systems : Alkyl-Group Dependence of 1-Alkyl-3-methylimidazolium Cation.2010

    • Author(s)
      Takashi Masaki, Keiko Nishikawa, Hideaki Shirota
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 114 Pages: 6323-6331

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Heavy Atom Substitution Effects in Non-Aromatic Ionic Liquids : Ultrafast Dynamics and Physical Properties.2010

    • Author(s)
      Hideaki Shirota, Hiroki Fukazawa, Tomotsumi Fujisawa, James F.Wishart
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 114 Pages: 9400-9412

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrafast Dynamics in Room Temperature Ionic Liquids Studied by Femtosecond Raman-Induced Kerr Effect Spectroscopy.2010

    • Author(s)
      Hideaki Shirota
    • Journal Title

      Proceedings of APSRC-2010 & TSRP-2010

      Volume: 1 Pages: 177-180

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Interionic Interaction and Dynamics in Ionic Liquids : Effect of Anion Symmetry.2010

    • Author(s)
      Hiroki Fukazawa, Hideaki Shirota
    • Journal Title

      Proceedings of APSRC-2010 & TSRP-2010

      Volume: 2 Pages: 267-268

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Intermolecular Vibrational Dynamics in Cooperative Hydrogen-Bonding Complex : 7-Azaindole.2010

    • Author(s)
      Tatsuya Kato, Hideaki Shirota
    • Journal Title

      Proceedings of APSRC-2010 & TSRP-2010

      Volume: 2 Pages: 306-307

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Comparison of Interionic/Intermolecular Vibrational Dynamics between Ionic Liquids and Concentrated Electrolyte Solutions2009

    • Author(s)
      T. Fujisawa, K. Nishikawa, H. Shirota.
    • Journal Title

      J. Chem. Phys.

      Volume: 131(24)

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ultrafast Dynamics in Aprotic Molecular Liquids: A Femtosecond Raman-Induced Kerr Effect Spectroscopic Study.2009

    • Author(s)
      H. Shirota. T. Fujisawa, H. Fukazawa, K.Nishikawa.
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 82(11) Pages: 1347-1366

    • NAID

      10027169922

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Atom Substitution Effects of [XF_6]^- in Ionic Liquids. 1. Experimental Study2009

    • Author(s)
      H.Shirota, K.Nishikawa, T.Ishida
    • Journal Title

      Journal of Physical Chemistry B 113

      Pages: 9831-9839

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atom Substitution Effects of [XF_6]^- in Ionic Liquids. 2. Theoretical Study2009

    • Author(s)
      T.Ishida, K.Nishikawa, H.Shirota
    • Journal Title

      Journal of Physical Chemistry B 113

      Pages: 9840-9851

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrafast Dynamics in Aprotic Molecular Liquids : A Femtosecond Raman-Induced Kerr Effect Spectroscopic Study2009

    • Author(s)
      H.Shirota, T.Fujisawa, H.Fukazawa, K.Nishikawa
    • Journal Title

      Bulletin of the Chemical Society of Japan 82

      Pages: 1347-1366

    • NAID

      10027169922

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparison of Interionic/Intermolecular Vibrational Dynamics between Ionic Liquids and Concentrated Electrolyte Solutions2009

    • Author(s)
      T.Fujisawa, K.Nishikawa, H.Shirota
    • Journal Title

      Journal of Chemical Physics 131

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparison between Dicationic and Monocationic Ionic Liquids : Liquid Density, Thermal Properties, Surface Tension, and Shear Viscosity.

    • Author(s)
      Hideaki Shirota, Toshihiko Mandai, Hiroki Fukazawa, Tatsuya Kato
    • Journal Title

      Journal of Chemical & Engineering Data

      Volume: (印刷中)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrafast Dynamics in 1-Butyl-3-methylimidazolium-Based Ionic Liquids : A Femtosecond Raman-Induced Kerr Effecr Spectroscopic Study.

    • Author(s)
      Hiroki Fukazawa, Tateki Ishida, Hideaki Shirota
    • Journal Title

      Journal of Physical Chemistry B

      Volume: (印刷中)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Intermolecular Dynamics in Liquids Studied by A Third-Order Nonlinear Spectroscopy.

    • Author(s)
      Hideaki Shirota
    • Journal Title

      Proceedings of ICCMSE 2010

      Volume: (印刷中)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Probing Dimerization of 7-Azaindol in Solutions by Femtosecond Raman-Induced Kerr Effect Spectroscopy2013

    • Author(s)
      Hideaki Shirota, Takao Fukuda, Tatsuya Kato.
    • Organizer
      XVIth International Conference on Time-Resolved Vibrational Spectroscopy
    • Place of Presentation
      Beppu, Japan
    • Year and Date
      2013-05-23
    • Related Report
      2012 Final Research Report
  • [Presentation] MicroscopicAspect of Ionic Liquid and Water Mixtures Probed by Femtosecond Raman-Induced Kerr Effect Spectroscopy2012

    • Author(s)
      Hideaki Shirota, Ranjit Biswas.
    • Organizer
      2012EMLG/JMLG Annual Meeting
    • Place of Presentation
      Eger, Hungary
    • Year and Date
      2012-09-05
    • Related Report
      2012 Final Research Report
  • [Presentation] フェムト秒ラマン誘起カー効果分光法でみるテラヘルツ領域の分子運動-溶液中の7-アザインドールを例にして-2012

    • Author(s)
      城田秀明
    • Organizer
      アジア連携分子研研究会
    • Place of Presentation
      岡崎
    • Year and Date
      2012-06-02
    • Related Report
      2012 Final Research Report
  • [Presentation] Low-Frequency Vibration al Dynamics in Liquids: Molecular Liquid vs2012

    • Author(s)
      Hideaki Shirota
    • Organizer
      Ionic Liquid. Mini Discussion Meet ing on Dynamics & Relaxations in Comp lex Systems
    • Place of Presentation
      Chiba
    • Year and Date
      2012-03-03
    • Related Report
      2012 Final Research Report
  • [Presentation] Low-Frequency Vibrational Dynamics in Liquids : Molecular Liquid vs.Ionic Liquid2012

    • Author(s)
      Hideaki Shirota
    • Organizer
      Mini Discussion Meeting on Dynamics & Relaxations in Complex Systems
    • Place of Presentation
      Chiba
    • Year and Date
      2012-03-03
    • Related Report
      2011 Annual Research Report
  • [Presentation] Intermolecular Dynamics of 7-Azaindole in Solutions by means of Femtosecond Raman-Induced Kerr Effect Spectroscopy2012

    • Author(s)
      Tatsuya Kato, Hideaki Shirota
    • Organizer
      International Conference on Statistical Mechanics of Liquids: From Water to Biomolecules
    • Place of Presentation
      Okazaki,Japan
    • Year and Date
      2012-02-13
    • Related Report
      2012 Final Research Report
  • [Presentation] Intermolecular Dynamics of 7-Azaindole in Solutions by means od Femtosecond Raman-Induced Kerr Effect Spectroscopy2012

    • Author(s)
      Tatsuya Kato, Hideaki Shirota
    • Organizer
      International Conference on Statistical Mechanics of Liquids : From Water to Biomolecules
    • Place of Presentation
      Okazaki
    • Year and Date
      2012-02-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] Ultrafast Dynamics in Room Temperature Ionic Liquids Studied by FemtosecondRaman-Induced Kerr Effect Spectroscopy2012

    • Author(s)
      Tatsuya Kato, Hideaki Shirota
    • Organizer
      11th Trombay Symposium on Radiation & Photochemistry
    • Place of Presentation
      Mumbai, India
    • Year and Date
      2012-01-04
    • Related Report
      2012 Final Research Report
  • [Presentation] Ultrafast Dynamics in Room Temperature Ionic Liquids Studied by Femtosecond Raman-Induced Kerr Effect Spectroscopy2012

    • Author(s)
      Tatsuya Kato, Hideaki Shirota
    • Organizer
      11th Trombay Symposium on Radiation & Photochemistry
    • Place of Presentation
      Mumbai(招待講演)
    • Year and Date
      2012-01-04
    • Related Report
      2011 Annual Research Report
  • [Presentation] 粘性緩和法による側鎖にエーテル基を含むアンモニウムおよびホスホニウム系イオン液体の研究2011

    • Author(s)
      三河健一,山口毅,香田忍,深澤宏紀,城田秀明
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-22
    • Related Report
      2012 Final Research Report
  • [Presentation] 粘性緩和法による側鎖にエーテル基を含むアンモニウムおよびホスホニウム系イオン液体の研究2011

    • Author(s)
      三河健一, 山口毅, 香田忍, 深澤宏紀, 城田秀明
    • Organizer
      分子科学討論会
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] Interionic Vibrations of Ionic Liquids Probed by Femtosecond Raman-Induced Kerr Effect Spectroscopy2011

    • Author(s)
      Hideaki Shirota
    • Organizer
      2011 EMLG/JMLG Annual Meeting
    • Place of Presentation
      Warsaw, Poland
    • Year and Date
      2011-09-15
    • Related Report
      2012 Final Research Report
  • [Presentation] Interionic Vibrations of Ionic Liquids Probed by Femtosecond Raman-Induced Kerr Effect Spectroscopy2011

    • Author(s)
      Hideaki Shirota
    • Organizer
      EMLG/JMLG Annual Meeting : New Outlook on Molecular Liquids, from Short Scale to Long Scale Dynamics
    • Place of Presentation
      Warsaw(招待講演)
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 芳香族イオン液体のイオン間相互作用とダイナミクス2011

    • Author(s)
      深澤宏紀,城田秀明
    • Organizer
      日本化学会第91回春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2011-03-27
    • Related Report
      2012 Final Research Report
  • [Presentation] 溶液中における7-アザインドール会合体の超高速ダイナミクス2011

    • Author(s)
      加藤達也,城田秀明
    • Organizer
      日本化学会第91回春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2011-03-27
    • Related Report
      2012 Final Research Report
  • [Presentation] 溶液中における7-アザインドール会合体の超高速ダイナミクス2011

    • Author(s)
      加藤達也, 城田秀明
    • Organizer
      日本化学会第91回春季年会
    • Place of Presentation
      神奈川大学, 横浜
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] 芳香族イオン液体のイオン間相互作用とダイナミクス2011

    • Author(s)
      深澤宏紀, 城田秀明
    • Organizer
      日本化学会第91回春季年会
    • Place of Presentation
      神奈川大学, 横浜
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] Intermolecular Dynamics in Liquids Studied by A Third-Order Nonlinear Spectroscopy.2010

    • Author(s)
      Hideaki Shirota
    • Organizer
      8^<th> International Conference of Computational Methods in Science and Engineering
    • Place of Presentation
      Kos, Greece
    • Year and Date
      2010-10-05
    • Related Report
      2012 Final Research Report
  • [Presentation] Intermolecular Dynamics in Liquids Studied by A Third-Order Nonlinear Spectroscopy.2010

    • Author(s)
      Hideaki Shirota
    • Organizer
      8^<th> International Conference of Computational Methods in Science and Engineering
    • Place of Presentation
      Kypriotis International Conference Center, Kos, Greece(招待講演)
    • Year and Date
      2010-10-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] Intermolecular Vibrational Dynamics inCooperative Hydrogen-Bonding Complex:7-Azaindole2010

    • Author(s)
      Tatsuya Kato, Hideaki Shirota
    • Organizer
      3^<rd> Asia Pacific Symposium on Radiation Chemistry and10^<th> Trombay Symposium on Radiation & Photochemistry
    • Place of Presentation
      Lonavala, India
    • Year and Date
      2010-09-15
    • Related Report
      2012 Final Research Report
  • [Presentation] Interionic Interaction and Dynamics in Ionic Liquids: Effect of Anion Symmetry2010

    • Author(s)
      Hiroki Fukazawa, Hideaki Shirota.
    • Organizer
      3rd Asia Pacific Symposium on Radiation Chemistry and10th Trombay Symposium on Radiation & Photochemistry
    • Place of Presentation
      Lonavala, India
    • Year and Date
      2010-09-15
    • Related Report
      2012 Final Research Report
  • [Presentation] Ultrafast Dynamics inRoom Temperature Ionic Liquids Studied by Femtosecond Raman-Induced Kerr Effect Spectroscopy2010

    • Author(s)
      Hideaki Shirota
    • Organizer
      3^<rd> Asia Pacific Symposium on Radiation Chemistry and10^<th> Trombay Symposium on Radiation & Photochemistry
    • Place of Presentation
      Lonavala, India
    • Year and Date
      2010-09-15
    • Related Report
      2012 Final Research Report
  • [Presentation] Ultrafast Dynamics in Room Temperature Ionic Liquids Studied by Femtosecond Raman-Induced Kerr Effect Spectroscopy.2010

    • Author(s)
      Hideaki Shirota
    • Organizer
      3^<rd> Asia Pacific Symposium on Radiation Chemistry and 10^<th> Trombay Symposium on Radiation & Photochemistry
    • Place of Presentation
      Treasure Island Resorts, Lonavala, India(招待講演)
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] Interionic Interaction and Dynamics in Ionic Liquids : Effect of Anion Symmetry.2010

    • Author(s)
      Hiroki Fukazawa, Hideaki Shirota
    • Organizer
      3^<rd> Asia Pacific Symposium on Radiation Chemistry and 10^<th> Trombay Symposium on Radiation & Photochemistry
    • Place of Presentation
      Treasure Island Resorts, Lonavala, India
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] Intermolecular Vibrational Dynamics in Cooperative Hydrogen-Bonding Complex : 7-Azaindole.2010

    • Author(s)
      Tatsuya Kato, Hideaki Shirota
    • Organizer
      3^<rd> Asia Pacific Symposium on Radiation Chemistry and 10^<th> Trombay Symposium on Radiation & Photochemistry
    • Place of Presentation
      Treasure Island Resorts, Lonavala, India(ポスター賞受賞)
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] FemtosecondRaman-Induced Kerr Effect SpectroscopicStudy of Aprotic Molecular Liquids2010

    • Author(s)
      Hideaki Shirota
    • Organizer
      Ohokayama Workshop on Fundamental Photochemical Processes in CondensedMedia
    • Place of Presentation
      東京
    • Year and Date
      2010-06-25
    • Related Report
      2012 Final Research Report
  • [Presentation] Femtosecond Raman-Induced Kerr Effect Spectroscopic Study of Aprotic Molecular Liquids.2010

    • Author(s)
      Hideaki Shirota
    • Organizer
      Ohokayama Workshop on Fundamental Photochemical Processes in Condensed Media
    • Place of Presentation
      東工大, 東京(招待講演)
    • Year and Date
      2010-06-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Femtosecond Raman-InducedKerr Effect Spectroscopic Study on Ionic Liquids2010

    • Author(s)
      H. Shirota
    • Organizer
      239^<th> American Chemical Society National Meeting
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2010-03-22
    • Related Report
      2012 Final Research Report
  • [Presentation] Femtosecond Raman-Induced Kerr Effect Spectroscopic Study on Ionic Liquids2010

    • Author(s)
      城田秀明
    • Organizer
      239^<th> American Chemical Society National Meeting
    • Place of Presentation
      Moscone Center, San Francisco, CA, USA.
    • Year and Date
      2010-03-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] 非芳族性イオン液体の重原子置換効果:イオン間振動ダイナミクスと物性2009

    • Author(s)
      城田秀明、藤澤知績、深澤宏紀、西川恵子、ウィシャートF.ジェームズ
    • Organizer
      第32回溶液化学シンポジウム
    • Place of Presentation
      新潟
    • Year and Date
      2009-11-18
    • Related Report
      2012 Final Research Report
  • [Presentation] フェムト秒光Kerr効果分光法によるイオン液体中のイオン間相互作用の検討:高濃度電解質溶液との比較2009

    • Author(s)
      藤澤知績、西川恵子、城田秀明
    • Organizer
      第32回溶液化学シンポジウム
    • Place of Presentation
      新潟
    • Year and Date
      2009-11-18
    • Related Report
      2012 Final Research Report
  • [Presentation] フェムト秒光 Kerr 効果分光法によるイオン液体中のイオン間相互作用の検討:高濃度電解質溶液との比較2009

    • Author(s)
      藤澤知績、西川恵子、城田秀明
    • Organizer
      第32回溶液化学シンポジウム
    • Place of Presentation
      朱鷺メッセ, 新潟
    • Year and Date
      2009-11-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] 非芳族性イオン液体の重原子置換効果:イオン間振動ダイナミクスと物性2009

    • Author(s)
      城田秀明、藤澤知績、深澤宏紀、西川恵子、ウィシャート F.ジェームズ
    • Organizer
      第32回溶液化学シンポジウム
    • Place of Presentation
      朱鷺メッセ, 新潟
    • Year and Date
      2009-11-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] 非プロトン性分子液体の分子間振動ダイナミクス2009

    • Author(s)
      城田秀明
    • Organizer
      第32回溶液化学シンポジウム・プレシンポジウム
    • Place of Presentation
      新潟
    • Year and Date
      2009-11-17
    • Related Report
      2012 Final Research Report
  • [Presentation] 非プロトン性分子液体の分子間振動ダイナミクス2009

    • Author(s)
      城田秀明
    • Organizer
      第32回溶液化学シンポジウム・プレシンポジウム
    • Place of Presentation
      新潟大学, 新潟
    • Year and Date
      2009-11-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] 非プロトン性溶媒のフェムト秒ダイナミクス2009

    • Author(s)
      城田秀明、藤澤知績、深澤宏紀、西川恵子
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2009-09-22
    • Related Report
      2012 Final Research Report
  • [Presentation] フェムト秒ラマン誘起カー効果分光法によるイオン液体中でのイオン間相互作用の検討:高濃度電解質溶液との比較2009

    • Author(s)
      藤澤知績、西川恵子、城田秀明
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2009-09-22
    • Related Report
      2012 Final Research Report
  • [Presentation] フェムト秒ラマン誘起カー効果分光法によるイオン液体中でのイオン間相互作用の検討:高濃度電解質溶液との比較2009

    • Author(s)
      藤澤知績、西川恵子、城田秀明
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名古屋大学, 名古屋
    • Year and Date
      2009-09-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] 非プロトン性溶媒のフェムト秒ダイナミクス2009

    • Author(s)
      城田秀明、藤澤知績、深澤宏紀、西川恵子
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名古屋大学, 名古屋
    • Year and Date
      2009-09-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] Interionic Vibrational Dynamics and Interaction in Room Temperature Ionic Liquids: Heavy Atom Substitution Effects2009

    • Author(s)
      H. Shirota, T. Fujisawa, H. Fukazawa, K.Nishikawa, J.F. Wishart
    • Organizer
      6^<th> International Discussion Meeting on Relaxations in Complex Systems
    • Place of Presentation
      Rome, Italy
    • Year and Date
      2009-09-01
    • Related Report
      2012 Final Research Report
  • [Presentation] Interionic Vibrational Dynamics and Interaction in Room Temperature Ionic Liquids : Heavy Atom Substitution Effects2009

    • Author(s)
      H.Shirota, H.Fukazawa, T.Fujisawa, K.Nishikawa, T.Ishida J.F.Wishart.
    • Organizer
      6^<th> International Discussion Meeting on Relaxations in Complex Systems
    • Place of Presentation
      University di Roma, Rome, Italy
    • Year and Date
      2009-09-01
    • Related Report
      2009 Annual Research Report
  • [Presentation] Intermolecular Vibrational Dynamics in Aprotic Molecular Liquids. International Symposium on2009

    • Author(s)
      H. Shirota, T. Fujisawa, H. Fukazawa, K.Nishikawa
    • Organizer
      Reaction Dynamics of Many-Body Chemical Systems
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2009-06-23
    • Related Report
      2012 Final Research Report
  • [Presentation] Intermolecular Vibrational Dynamics in Aprotic Molecular Liquids2009

    • Author(s)
      城田秀明, 藤澤知績, 深澤宏紀, 西川恵子
    • Organizer
      International Symposium on "Reaction Dynamics of Many-Body Chemical Systems"
    • Place of Presentation
      Kyoto Garden Palace, Kyoto, Japan
    • Year and Date
      2009-06-23
    • Related Report
      2009 Annual Research Report
  • [Presentation] Heavy Atom Substitution Effects in Non-Aromatic Ionic Liquids2009

    • Author(s)
      H. Shirota, T. Fujisawa, H. Fukazawa, K.Nishikawa, J.F. Wishart.
    • Organizer
      3^<rd> Congress on Ionic Liquids
    • Place of Presentation
      Cairns, Australia
    • Year and Date
      2009-06-02
    • Related Report
      2012 Final Research Report
  • [Presentation] Heavy Atom Substitution Effects in Non-Aromatic Ionic Liquids2009

    • Author(s)
      城田秀明, 藤澤知績, 深澤宏紀, 西川恵子, ウィシャート F.ジェームズ
    • Organizer
      3^<rd> Congress on Ionic Liquids
    • Place of Presentation
      Cairns Convention Centre, Cairns, Australia
    • Year and Date
      2009-06-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] Comparison between ionic liquids and concentrated electrolyte solutions by femtosecond optical Kerr effect spectroscopy2009

    • Author(s)
      T. Fujisawa, K. Nishikawa, H. Shirota
    • Organizer
      3^<rd> Congress on Ionic Liquids
    • Place of Presentation
      Cairns, Australia
    • Year and Date
      2009-06-01
    • Related Report
      2012 Final Research Report
  • [Presentation] Comparison between ionic liquids and concentrated electrolyte solutions by femtosecond optical Kerr effect spectroscopy2009

    • Author(s)
      藤澤知績, 西川恵子, 城田秀明
    • Organizer
      3^<rd> Congress on Ionic Liquids
    • Place of Presentation
      Cairns Convention Centre, Cairns, Australia
    • Year and Date
      2009-06-01
    • Related Report
      2009 Annual Research Report
  • [Presentation] Femtosecond Optical Kerr Effect Spectroscopy of Ionic Liquids: Comparison with Concentrated Electrolyte Solutions2009

    • Author(s)
      T. Fujisawa, K. Nishikawa, H. Shirota
    • Organizer
      6^<th> International Discussion Meeting on Relaxations in Complex Systems
    • Place of Presentation
      Rome, Italy
    • Related Report
      2012 Final Research Report
  • [Presentation] Femtosecond Optical Kerr Effect Spectroscopy of Ionic Liquids : Comparison with Concentrated Electrolyte Solutions2009

    • Author(s)
      藤澤知績, 西川恵子, 城田秀明
    • Organizer
      6^<th> International Discussion Meeting on Relaxations in Complex Systems
    • Place of Presentation
      Universita di Roma, Rome, Italy
    • Related Report
      2009 Annual Research Report
  • [Presentation] フェムト秒ラマン誘起カー効果分光法でみるテラヘルツ領域の分子運動-溶液中の7-アザインドールを例にして-

    • Author(s)
      城田秀明
    • Organizer
      アジア連携分子研研究会
    • Place of Presentation
      岡崎
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Microscopic Aspect of Ionic Liquid and Water Mixtures Probed by Femtosecond Raman-Induced Kerr Effect Spectroscopy

    • Author(s)
      Hideaki Shirota, Ranjit Biswas
    • Organizer
      2012 EMLG/JMLG Annual Meeting
    • Place of Presentation
      Eger, Hungary
    • Related Report
      2012 Annual Research Report
  • [Book] In Ionic Liquids: Theory, Properties, New Approaches, Alexander Kokorin, Ed. (InTech: Rijeka, Croatia)2011

    • Author(s)
      H. Shirota, H. Fukazawa
    • Publisher
      AtomSubstitution Effects in Ionic Liquids: A Microscopic View by Femtosecond Raman-Induced Kerr Effect Spectroscopy
    • Related Report
      2012 Final Research Report
  • [Book] "Atom Substitution Effects in Ionic Liquids : A Microscopic View by Femtosecond Raman-Induced Kerr Effect Spectroscopy" in Ionic Liquids : Theory, Properties, New Approaches. A.Kokorin, Ed.2011

    • Author(s)
      H.Shirota, H.Fukazawa
    • Publisher
      InTech, Rijeka, Croatia
    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://pchem2.s.chiba-u.ac.jp/chem/lab/shirotalab/home-eng.html

    • Related Report
      2012 Final Research Report
  • [Remarks] Hirsch Index 本研究プロジェクト期間(4年間)に18(2009年)から26(2013年)に増加。

    • Related Report
      2012 Final Research Report
  • [Remarks] 分子分光学研究室

    • URL

      http://pchem2.s.chiba-u.ac.jp/chem/lab/shirotalab/home-eng.html

    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://pchem2.s.chiba-u.ac.jp/chem/lab/shirotalab/home-eng.html

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://pchem2.s.chiba-u.ac.jp/chem/lab/shirotalab/home-eng.html

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://pchem2.s.chiba-u.ac.jp/chem/lab/shirotalab/home-eng.html

    • Related Report
      2009 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2019-07-29  

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