| Budget Amount *help |
¥28,340,000 (Direct Cost: ¥21,800,000、Indirect Cost: ¥6,540,000)
Fiscal Year 2010: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2009: ¥21,320,000 (Direct Cost: ¥16,400,000、Indirect Cost: ¥4,920,000)
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| Research Abstract |
This research project has achieved the followings. (1) Exploration of chemistry of boryl anion, especially for the formation of boron-containing chemical bond with second-row p-block elements, and application of the resulting products for organic syntheses. (2) Attempt to synthesize boron-centered radical and low-oxidation state boron compound, borylene, and confirmation of photo-activated boryl radical species. (3) Syntheses and properties of transition-metal complexes bearing a boron-containing multidentate ligand and their application to catalysis.
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