Organic and catalysis chemistry based on low-valent boron compounds
| Project/Area Number |
21685006
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (A)
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Organic chemistry
|
|---|
| Research Institution | Chuo University (2010)
The University of Tokyo (2009) |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2009 – 2010
|
| Project Status |
Completed (Fiscal Year 2010)
|
| Budget Amount *help |
¥28,340,000 (Direct Cost: ¥21,800,000、Indirect Cost: ¥6,540,000)
Fiscal Year 2010: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2009: ¥21,320,000 (Direct Cost: ¥16,400,000、Indirect Cost: ¥4,920,000)
|
|---|
| Keywords | 有機元素化学 / ラジカル / 触媒 / ホウ素 / 酸化数 / ボリルアニオン / カルボホウ素化 / ヒドロボラート / 低原子価 / 配位子 |
|---|
| Research Abstract |
This research project has achieved the followings. (1) Exploration of chemistry of boryl anion, especially for the formation of boron-containing chemical bond with second-row p-block elements, and application of the resulting products for organic syntheses. (2) Attempt to synthesize boron-centered radical and low-oxidation state boron compound, borylene, and confirmation of photo-activated boryl radical species. (3) Syntheses and properties of transition-metal complexes bearing a boron-containing multidentate ligand and their application to catalysis.
|
Report
(3 results)
Research Products
(78 results)
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
[Journal Article] Boryltrihydroborate: Synthesis, Structure, and Reactivity as a Reductant in Ionic, Organometallic, and Radical Reactions2010
Author(s)
Nozaki, K.; Aramaki, Y.; Yamashita, M.; Ueng, S.-H.; Malacria, M.; Lacote, E.; Curran, D. P.
-
Journal Title
J. Am. Chem. Soc.
Volume: 132
Pages: 11449-11451
Related Report
Peer Reviewed
-
-
[Journal Article] Boryltrihydroborate : Synthesis, Structure, and Reactivity as a Reductant in Ionic, Organometallic and Radical Reactions2010
Author(s)
Nozaki, K.; Aramaki, Y.; Yamashita, M.; Ueng, S.-H.; Malacria, M.; Lacote, E.; Curran, D.
-
Journal Title
J.Am.Chem.Soc.
Pages: 11449-11451
Related Report
Peer Reviewed
-
-
-
-
-
-
-
-
-
-
-
-
-
[Presentation] リチウムボリルトリヒドロボラートの合成と反応2011
Author(s)
荒巻吉孝・山下誠・Ueng, Shau-Hua・Malacria, Max・Lacote, Emmanuel・Curran, Dennis P.・野崎京子
Organizer
日本化学会第91春季年会
Place of Presentation
神奈川大学横浜キャンパス
Year and Date
2011-03-27
Related Report
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
