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Organic and catalysis chemistry based on low-valent boron compounds

Research Project

Project/Area Number 21685006
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Organic chemistry
Research InstitutionChuo University (2010)
The University of Tokyo (2009)

Principal Investigator

YAMASHITA Makoto  中央大学, 理工学部, 准教授 (10376486)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥28,340,000 (Direct Cost: ¥21,800,000、Indirect Cost: ¥6,540,000)
Fiscal Year 2010: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2009: ¥21,320,000 (Direct Cost: ¥16,400,000、Indirect Cost: ¥4,920,000)
Keywords有機元素化学 / ラジカル / 触媒 / ホウ素 / 酸化数 / ボリルアニオン / カルボホウ素化 / ヒドロボラート / 低原子価 / 配位子
Research Abstract

This research project has achieved the followings. (1) Exploration of chemistry of boryl anion, especially for the formation of boron-containing chemical bond with second-row p-block elements, and application of the resulting products for organic syntheses. (2) Attempt to synthesize boron-centered radical and low-oxidation state boron compound, borylene, and confirmation of photo-activated boryl radical species. (3) Syntheses and properties of transition-metal complexes bearing a boron-containing multidentate ligand and their application to catalysis.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (78 results)

All 2011 2010 2009 Other

All Journal Article (26 results) (of which Peer Reviewed: 26 results) Presentation (50 results) Remarks (2 results)

  • [Journal Article] A catalytic synthesis of dialkylamines from alkylamines using neopentyl-substituted PNP pincer-iridium complex2011

    • Author(s)
      Yamashita, M., Moroe, Y. Yano, T. Nozaki, K.
    • Journal Title

      Inorg. Chim. Acta

      Volume: 363 Pages: 15-18

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Development of highly efficient one-pot processes using orthogonal tandem catalyst2011

    • Author(s)
      Yamashita, M.
    • Journal Title

      Shokubai

      Volume: 53 Pages: 310-312

    • NAID

      10029500069

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Creation of Nucleophilic Boryl Anions and Their Properties2011

    • Author(s)
      Yamashita, M.
    • Journal Title

      Bull. Chem. Soc. Jpn.

      Volume: 84 Pages: 983-999

    • NAID

      10030214562

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mechanistic Studies on the Reversible Hydrogenation of Carbon Dioxide Catalyzed by an Ir-PNP Complex2011

    • Author(s)
      Tanaka, R.; Yamashita, M.; Chung, L. W.; Morokuma, K.; Nozaki, K.
    • Journal Title

      Organometallics

      Volume: 30 Pages: 6742-6750

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] One-Pot Carboboration of Alkynes Using Lithium Borylcyanocuprate and the Subsequent Suzuki-Miyaura Cross-Coupling of the Resulting Tetrasubstituted Alkenylborane2011

    • Author(s)
      Okuno, Y.; Yamashita, M.; Nozaki, K.
    • Journal Title

      Eur. J. Org. Chem.

      Volume: 2011 Pages: 3951-3958

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Borylcyanocuprate in a One-Pot Carboboration by a Sequential Reaction with an Electron-Deficient Alkyne and an Organic Carbon Electrophile2011

    • Author(s)
      Okuno, Y.; Yamashita, M.; Nozaki, K.
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 50 Pages: 920-923

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses and properties of triborane(5)s possessing bulky diamino substituents on terminal boron atoms2011

    • Author(s)
      Hayashi, Y.; Segawa, Y.; Yamashita, M.; Nozaki, K.
    • Journal Title

      Chem. Commun.

      Volume: 47 Pages: 5888-5890

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Borylcyanocuprate in a One-Pot Carboboration by a Sequential Reaction with an Electron-Deficient Alkyne and an Organic Carbon Electrophile2011

    • Author(s)
      Okuno, Y.; Yamashita, M.; Nozaki, K.
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 50 Pages: 920-923

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses and Properties of Triborane(5)s Possessing Bulky Diamino Substituents on Terminal Boron Atoms2011

    • Author(s)
      Hayashi, Y.; Segawa, Y.; Yamashita, M.; Nozaki, K.
    • Journal Title

      Chem.Commun.

      Volume: 47 Pages: 5888-5890

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One-Pot Carboboration of Alkynes Using Lithium Borylcyanocuprate and the Subsequent Suzuki-Miyaura Cross-Coupling Reaction of Resulting Tetrasubstituted Alkenylborane2011

    • Author(s)
      Okuno, Y.; Yamashita, M.; Nozaki, K.
    • Journal Title

      Eur.J.Org.Chem.

      Pages: 3951-3958

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Boryl Anion: Syntheses and Properties of Novel Borylmetals2010

    • Author(s)
      Yamashita, M.; Nozaki, K.
    • Journal Title

      J. Synth. Org. Chem., Jpn.

      Volume: 68 Pages: 359-369

    • NAID

      10026868464

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reduction of base-stabilized difluoroboranes to induce rearrangement reactions2010

    • Author(s)
      Yamashita, M.; Aramaki, Y.; Nozaki, K.
    • Journal Title

      New J. Chem.

      Volume: 34 Pages: 1774-1782

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nucleophilicity of a Base-Stabilized Borole Anion at the Boron Center2010

    • Author(s)
      Yamashita, M.
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 49 Pages: 2474-2475

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] High-Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System2010

    • Author(s)
      Takahashi, K.; Yamashita, M.; Ichihara, T.; Nakano, K.; Nozaki, K.
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 49 Pages: 4488-4490

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Boryltrihydroborate: Synthesis, Structure, and Reactivity as a Reductant in Ionic, Organometallic, and Radical Reactions2010

    • Author(s)
      Nozaki, K.; Aramaki, Y.; Yamashita, M.; Ueng, S.-H.; Malacria, M.; Lacote, E.; Curran, D. P.
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 132 Pages: 11449-11451

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reduction of Base-Stabilized Difluoroboranes to Induce Rearrangement Reactions2010

    • Author(s)
      Yamashita, M.; Aramaki, Y.; Nozaki, K.
    • Journal Title

      New J.Chem.

      Pages: 1774-1782

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Boryltrihydroborate : Synthesis, Structure, and Reactivity as a Reductant in Ionic, Organometallic and Radical Reactions2010

    • Author(s)
      Nozaki, K.; Aramaki, Y.; Yamashita, M.; Ueng, S.-H.; Malacria, M.; Lacote, E.; Curran, D.
    • Journal Title

      J.Am.Chem.Soc.

      Pages: 11449-11451

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System2010

    • Author(s)
      Takahashi, K.; Yamashita, M.; Ichihara, T.; Nakano, K.; Nozaki, K.
    • Journal Title

      Angew.Chem.Int.Ed.

      Pages: 4488-4490

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Group-4 Transition-Metal Boryl Complexes: Syntheses, Structures, Boron-Metal Bonding Properties, and Application as a Polymerization Catalyst2009

    • Author(s)
      Terabayashi, T.; Kajiwara, T.; Yamashita, M.; Nozaki, K.
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 131 Pages: 14162-14163

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)-Pincer Complexes2009

    • Author(s)
      Tanaka, R.; Yamashita, M.; Nozaki, K.
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 131 Pages: 14168-14169

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Diphenylphosphino- or Dicyclohexylphosphino-Tethered Boryl Pincer Ligands: Syntheses of PBP Iridium(III) Complexes and Their Conversion to Iridium-Ethylene Complexes2009

    • Author(s)
      Segawa, Y.; Yamashita, M.; Nozaki, K.
    • Journal Title

      Organometallics

      Volume: 28 Pages: 6234-6242

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses of PBP Pincer Iridium Complexes: A Supporting Boryl Ligand2009

    • Author(s)
      Segawa, Y.; Yamashita, M.; Nozaki, K.
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 131 Pages: 9201-9203

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses of PBP Pincer Iridium Complexes : A Supporting Boryl Ligand2009

    • Author(s)
      Segawa, Y., Yamashita, M., Nozaki, K.
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 9201-9203

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)-Pincer Complexes2009

    • Author(s)
      Tanaka, R., Yamashita, M., Nozaki, K.
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 14168-14169

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Group 4 Transition Metal Boryl Complexes : Syntheses, Structures, Boron-Metal Bonding Properties, and Application as a Polymerization Catalyst2009

    • Author(s)
      Terabayashi, T., Kajiwara, T.Yamashita, M., Nozaki, K.
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 14162-14163

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Diphenylphosphino-or Dicyclohexylphosphino-Tethered Boryl Pincer Ligands : Syntheses of PBP Iridium(III)Complexes and Their Conversion to Iridium-Ethylene Complexes2009

    • Author(s)
      Segawa, Y., Yamashita, M., Nozaki, K.
    • Journal Title

      Organometallics 28

      Pages: 6234-6242

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Syntheses and properties of transition metal complexes bearing a boron-based PBP-pincer ligand2011

    • Author(s)
      Makoto Yamashita
    • Organizer
      IUPAC World Chemistry Congress
    • Place of Presentation
      Puerto Rico
    • Year and Date
      2011-08-02
    • Related Report
      2010 Final Research Report
  • [Presentation] Ir-PNP錯体を用いた二酸化炭素の触媒的水素化:実験と計算化学を併用した機構解析2011

    • Author(s)
      田中亮・山下誠・Chung, Lung Wa・諸熊奎治・野崎京子
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学横浜キャンパス
    • Year and Date
      2011-03-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] Homogeneous Transition Metal Catalysts Possessing a Multidentate Ligand towards Petrochemistry2011

    • Author(s)
      YAMASHITA, Makoto; TAKAHASHI, Kohei; TANAKA, Ryo; NOZAKI, Kyoko
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学横浜キャンパス
    • Year and Date
      2011-03-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] リチウムボリルトリヒドロボラートの合成と反応2011

    • Author(s)
      荒巻吉孝・山下誠・Ueng, Shau-Hua・Malacria, Max・Lacote, Emmanuel・Curran, Dennis P.・野崎京子
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学横浜キャンパス
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] 次世代石油化学プロセスを目指した均一系触媒開発:100万トンのアルコール合成を夢見る有機金属化学2011

    • Author(s)
      山下誠
    • Organizer
      「私たちに役立つ触媒って何?」講演会
    • Place of Presentation
      東工大大岡山キャンパス
    • Year and Date
      2011-01-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] ネオペンチル置換PCPピンサー型配位子を有するイリジウム錯体の合成と炭化水素の脱水素化反応へ向けた応用2011

    • Author(s)
      谷口諒・山下 誠・野崎 京子
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学 岡山
    • Related Report
      2010 Final Research Report
  • [Presentation] Syntheses and properties of transition metal complexes bearing a boron-based PBP-pincer ligand2011

    • Author(s)
      Makoto Yamashita
    • Organizer
      IME Boron XIV
    • Place of Presentation
      Naiagarafalls, Ontario, Canada
    • Related Report
      2010 Final Research Report
  • [Presentation] Synthesis and Properties of Lithium Boryltrihydroborate2011

    • Author(s)
      Yoshitaka Aramaki, Makoto Yamashita, Shau-Hua Ueng, Max Maracria, Emmanuel Lacote, Dennis P. Curran, Kyoko Nozaki
    • Organizer
      IME Boron XIV
    • Place of Presentation
      Naiagarafalls, Ontario, Canada
    • Related Report
      2010 Final Research Report
  • [Presentation] Rational Design of Ru-Catallysts for normal-Selective Hydroformylation and Tandem Hydroformylation/Hydrogenation(合理的にデザインしたRu触媒による直鎖選択的ヒドロホルミル化とタンデム型ヒドロホルミル化/水素化)2011

    • Author(s)
      高橋 講平・山下 誠・田中 善幸・野崎 京子
    • Organizer
      第58回有機金属化学討論会
    • Place of Presentation
      名古屋大学千種キャンパス 愛知
    • Related Report
      2010 Final Research Report
  • [Presentation] Ir-PNP錯体による二酸化炭素-水素とギ酸の触媒的相互変換2011

    • Author(s)
      田中亮・山下誠・野崎京子
    • Organizer
      日本化学会第91春季年会
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Ir-PNP錯体を用いた二酸化炭素の触媒的水素化:実験と計算化学を併用した機構解析2011

    • Author(s)
      田中 亮・山下 誠・Chung Lung Wa・諸熊 奎治・野崎 京子
    • Organizer
      日本化学会第91春季年会
    • Related Report
      2010 Final Research Report
  • [Presentation] Ru触媒の合理的デザインによる1-アルケンからの直鎖アルデヒドの選択的合成およびタンデム反応による直鎖アルコールの直接合成2011

    • Author(s)
      高橋講平・山下誠・野崎京子・田中善幸
    • Organizer
      日本化学会第91春季年会
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] リチウムボリルトリヒドロボラートの合成と反応2011

    • Author(s)
      荒巻 吉孝・山下 誠・Ueng, Shau-Hua・Malacria, Max・Lacote, Emmanuel・Curran, Dennis P.・野崎 京子
    • Organizer
      日本化学会第91春季年会
    • Related Report
      2010 Final Research Report
  • [Presentation] Reduction of Base-Stabilized Difluoroborane Compounds witb One-Electron Reducing Agent2010

    • Author(s)
      Yoshitaka Aramaki, Makoto Yamashita, Kyoko Nozaki
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Honolulu
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Application of nucleophilic boryl anion to organic synthesis and organotransition metal chemistry2010

    • Author(s)
      Makoto Yamashita
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Honolulu
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Syntheses and properties of group 9 metal PBP-pincer complexes2010

    • Author(s)
      Makoto Yamashita
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Honolulu
    • Year and Date
      2010-12-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] Syntheses and Properties of Group 9 Metal Complexes Bearing a Boron-Based PBP Pincer Ligand2010

    • Author(s)
      長谷川万紀・瀬川泰知・山下誠・野崎京子
    • Organizer
      第10回蓼科有機化学会議
    • Place of Presentation
      蓼科
    • Year and Date
      2010-11-13
    • Related Report
      2010 Annual Research Report
  • [Presentation] High-Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru dual catalyst system2010

    • Author(s)
      Kohei Takahashi, Makoto Yamashita, Takeo Ichihara, Koji Nakano, Kyoko Nozaki
    • Organizer
      第60回錯体化学討論会・第60回記念錯体化学OSAKA国際会議
    • Place of Presentation
      大阪国際交流センター
    • Year and Date
      2010-09-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] PBPピンサー型配位子を有するロジウム錯体の合成と性質2010

    • Author(s)
      長谷川万紀・瀬川泰知・山下誠一野崎京子
    • Organizer
      第60回錯体化学討論会・第60回記念錯体化学OSAKA国際会議
    • Place of Presentation
      大阪国際交流センター
    • Year and Date
      2010-09-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] 塩基安定化ジフルオロボフンの還元2010

    • Author(s)
      荒巻吉孝・山下誠・野崎京子
    • Organizer
      第21回基礎有機化学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2010-09-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] Application of Boryllithium toward Preparation of Cyanoborylcuprate and Bora-Brook Rearrangement2010

    • Author(s)
      Makoto Yamashita; Hirotoshi Sakaino; Fumihiro Ito; Yuri Okuno; Kyoko Nozaki
    • Organizer
      24th International Conference on Organometallic Chemistry
    • Place of Presentation
      Taipei
    • Year and Date
      2010-07-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] Catalytic Hydrogenation of Carbon Dioxide Using Ir (III)-pincer Complexes and Its Mechanistic Investigation2010

    • Author(s)
      Ryo Tanaka; Makoto Yamashita; Kyoko Nozaki
    • Organizer
      24th International Conference on Organometallic Chemistry
    • Place of Presentation
      Taipei
    • Year and Date
      2010-07-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] High-Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System2010

    • Author(s)
      Kohei Takahashi, Makoto Yamashita, Takeo Ichihara, Koji Nakano, Kyoko Nozaki
    • Organizer
      International Symposium on Homogeneous Catalysis
    • Place of Presentation
      Poznan, Poland
    • Year and Date
      2010-07-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] Syntheses and Properties of New Borylmetals2010

    • Author(s)
      Makoto Yamashita
    • Organizer
      U-Tokyo/Yonsei U joint symposium
    • Place of Presentation
      Yonsei University
    • Year and Date
      2010-06-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] C-OH結合を生成する還元的脱離の観測2010

    • Author(s)
      林佑実, 和田真治, 山下誠, 野崎京子
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] Rh/Ru混合触媒系を用いた末端オレフィンのヒドロホルミル化-水素化による直鎖アルコールの一段階合成2010

    • Author(s)
      高橋講平・山下誠・市原健生・中野幸司・野崎京子
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] PBPピンサー型配位子を有するロジウム錯体の合成と性質2010

    • Author(s)
      長谷川万紀・瀬川泰知・山下誠・野崎京子
    • Organizer
      第60回錯体化学討論会・第60回記念錯体化学OSAKA国際会議
    • Related Report
      2010 Final Research Report
  • [Presentation] Ir-PNP錯体を用いた二酸化炭素の水素化によるギ酸合成2010

    • Author(s)
      田中亮・山下誠・野崎京子
    • Organizer
      第57回有機金属化学討論会
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Kinetic Analysis of C-OH Bond-Forming Reductive Elimination2010

    • Author(s)
      林佑実・和田真治・山下誠・野崎京子
    • Organizer
      第57回有機金属化学討論会
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] 塩基安定化ジフルオロボランの還元2010

    • Author(s)
      荒巻吉孝・山下誠・野崎京子
    • Organizer
      第21回基礎有機化学討論会
    • Related Report
      2010 Final Research Report
  • [Presentation] C-OH結合を生成する還元的脱離の観測2010

    • Author(s)
      林佑実・和田真治・山下誠・野崎京子
    • Organizer
      日本化学会第90春季年会
    • Related Report
      2010 Final Research Report
  • [Presentation] Ir-PNP錯体触媒を用いた二酸化炭素の水素化における反応機構解析2010

    • Author(s)
      田中亮・山下誠・野崎京子
    • Organizer
      日本化学会第90春季年会
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] PBPピンサー型配位子を有するロジウム錯体の合成と性質2010

    • Author(s)
      長谷川万紀・瀬川泰知・山下誠・野崎京子
    • Organizer
      日本化学会第90春季年会
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] Rh/Ru混合触媒系を用いた末端オレフィンのヒドロホルミル化-水素化による直鎖アルコールの一段合成2010

    • Author(s)
      高橋講平・山下誠・市原健生・中野幸司・野崎京子
    • Organizer
      日本化学会第90春季年会
    • Related Report
      2010 Final Research Report
  • [Presentation] ベンゾイルボランと求核種の反応:Bora-Brook転位2010

    • Author(s)
      境野裕健・山下誠・野崎京子
    • Organizer
      日本化学会第90春季年会
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] ボリルクプラートとアルキン、炭素求電子剤との反応によるカルボホウ素化2010

    • Author(s)
      奥野友里・山下誠・野崎京子
    • Organizer
      日本化学会第90春季年会
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] Syntheses and Properties of Group 9 Metal Complexes Bearing a Boron-Based PBP Pincer Ligand2010

    • Author(s)
      Yasutomo Segawa, Maki Hasegawa, Makoto Yamashita, Kyoko Nozaki
    • Organizer
      第6回有機元素化学セミナー
    • Related Report
      2010 Final Research Report
  • [Presentation] Carboboration of Alkyne : Sequential Reaction with Cyanoborylcupurate and Carbon Electrophile2009

    • Author(s)
      奥野友里, 山下誠, 野崎京子
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry(IKCOC-11)
    • Place of Presentation
      京都
    • Year and Date
      2009-11-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] Group 4 Transition Metal Boryl Complexes : Syntheses, Structures, and Application as a Precursor for Polymerization Catalyst2009

    • Author(s)
      寺林知美, 山下誠, 野崎京子
    • Organizer
      The 1st FAPS Polymer Congress
    • Place of Presentation
      名古屋
    • Year and Date
      2009-10-20
    • Related Report
      2009 Annual Research Report
  • [Presentation] Rh/Ru混合触媒系を用いた末端オレフィンのヒドロホルミル化-水素化による直鎖アルコールの一段合成2009

    • Author(s)
      高橋講平・山下誠・市原健生・中野幸司・野崎京子
    • Organizer
      第104回触媒討論会
    • Place of Presentation
      宮崎
    • Year and Date
      2009-09-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] Syntheses and Properties of Group-9 Transition Metal Complexes Bearing a PBP Pincer Ligand2009

    • Author(s)
      Yasutomo Segawa, Maki Hasegawa, Makoto Yamashita, Kyoko Nozaki
    • Organizer
      第26回有機合成化学セミナー
    • Year and Date
      2009-09-16
    • Related Report
      2010 Final Research Report
  • [Presentation] アルキンのカルボホウ素化反応2009

    • Author(s)
      奥野友里・山下誠・野崎京子
    • Organizer
      第26回有機合成化学セミナー
    • Year and Date
      2009-09-16
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] 塩基安定化ボリレンの合成2009

    • Author(s)
      荒巻吉孝・山下誠・野崎京子
    • Organizer
      第26回有機合成化学セミナー
    • Year and Date
      2009-09-16
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] 4族金属ボリル錯体の合成と性質2009

    • Author(s)
      寺林知美・山下誠・野崎京子
    • Organizer
      第26回有機合成化学セミナー
    • Year and Date
      2009-09-16
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] Syntheses and Properties of Group-9 Transition Metal Complexes Bearing a PBP Pincer Ligand2009

    • Author(s)
      瀬川泰知, 長谷川万紀, 山下誠, 野崎京子
    • Organizer
      第26回有機合成化学セミナー
    • Place of Presentation
      群馬
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)-Pincer Complexes2009

    • Author(s)
      田中亮, 山下誠, 野崎京子
    • Organizer
      15th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesi
    • Place of Presentation
      Glasgow, Scotland
    • Year and Date
      2009-07-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] Boron-Carbon Bond Formation Using Borylmetals2009

    • Author(s)
      奥野友里, 山下誠, 野崎京子
    • Organizer
      The 9th International Conference on Heteroatom Chemistry(ICHAC-9)
    • Place of Presentation
      Oviedo, spain
    • Year and Date
      2009-07-01
    • Related Report
      2009 Annual Research Report
  • [Presentation] Syntheses of Group 4 Borylmetal Complexes and Application to Polymerization Reaction2009

    • Author(s)
      山下誠, 寺林知美, 野崎京子
    • Organizer
      The 9th International Conference on Heteroatom Chemistry(ICHAC-9)
    • Place of Presentation
      Oviedo, spain
    • Year and Date
      2009-07-01
    • Related Report
      2009 Annual Research Report
  • [Presentation] Rh/Ru混合触媒系を用いた末端オレフィンのヒドロホルミル化-水素化による直鎖アルコールの一段合成2009

    • Author(s)
      高橋講平・山下誠・市原 健生・中野幸司・野崎京子
    • Organizer
      第104回触媒討論会
    • Related Report
      2010 Final Research Report
  • [Presentation] Ir-PNPトリヒドリド錯体を用いた二酸化炭素の水素化反応とその反応機構の考察2009

    • Author(s)
      田中亮・山下誠・野崎京子
    • Organizer
      第59回錯体化学討論会
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.chuo-u.ac.jp/~element/

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://www.chem.chuo-u.ac.jp/~element/

    • Related Report
      2010 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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