Creation of Functional Molecules Based on Borylated Porphyrins

• Project/Area Number: 21685011
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Single-year Grants
• Research Field: Synthetic chemistry
• Research Institution: Nagoya University
• Principal Investigator: SHINOKUBO Hiroshi 名古屋大学, 工学研究科, 教授 (50281100)
• Project Period (FY): 2009 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥27,430,000 (Direct Cost: ¥21,100,000、Indirect Cost: ¥6,330,000); Fiscal Year 2011: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000); Fiscal Year 2010: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000); Fiscal Year 2009: ¥12,610,000 (Direct Cost: ¥9,700,000、Indirect Cost: ¥2,910,000)
• Keywords: π共役系 / クロスカップリング / パラジウム / ホウ素 / ポルフィリン / 炭素.炭素結合生成 / 触媒 / 遷移金属 / 炭素-炭素結合生成

Research Abstract

Synthesis of novel porphyrin oligomers has been achieved with borylated porphyrins as key building blocks. Cross-coupling of tetraborylated porphyrin with tetrabromo porphyrin provided a tetrameric porphyrin tube, which has an inner cavity with a diameter of 14A. The X-ray diffraction analysis elucidated that the porphyrin tube encapsulates a C_60 molecule in its cavity and the interaction between the tube and C_60 constructs a 3D network in the solid state.

Research Products

• [Journal Article] Synthesis of Nickel(II) Azacorroles via Pd-Catalyzed Amination ofα,α'-Dichloro Dipyrrin Ni(II) Complex and Their Properties (2012)
  • Author(s): M. Horie, Y. Hayashi, S. Yamaguchi, H. Shinokubo
  • Journal Title: Chem. Eur. J. Volume: 18 Issue: 19 Pages: 5919-5923
  • DOI: 10.1002/chem.201200485
  • Peer Reviewed
• [Journal Article] Energy and Electron Transfer from Fluorescent Meso-structured Organosilica Framework to Guest Dyes (2012)
  • Author(s): N. Mizoshita, K. Yamanaka, S. Hiroto, H. Shinokubo, T. Tani, S. Inagaki
  • Journal Title: Langmuir Volume: 28 Issue: 8 Pages: 3987-3994
  • DOI: 10.1021/la204645k
  • Peer Reviewed
• [Journal Article] Oxidative Annulation ofβ-Aminoporphyrins into Provide Pyrazine-Fused Diporphyrins (2012)
  • Author(s): M. Akita, S. Hiroto, H. Shinokubo
  • Journal Title: Angew. Chem. Int. Ed Volume: 51 Issue: 12 Pages: 2894-2897
  • DOI: 10.1002/anie.201108037
  • Peer Reviewed
• [Journal Article] Mesoporous Organosilica Hybrids Consisting of Silica-Wrappedπ-πStacking Columns (2012)
  • Author(s): N. Mizoshita, T. Tani, H. Shinokubo, S. Inagaki
  • Journal Title: Angew. Chem. Int. Ed. Volume: 51 Issue: 5 Pages: 1156-1160
  • DOI: 10.1002/anie.201105394
  • Peer Reviewed
• [Journal Article] Synthesis and Oxidation of Cyclic Tetraindole (2012)
  • Author(s): S. Nakamura, S. Hiroto, H. Shinokubo
  • Journal Title: Chem. Sci Volume: 3 Issue: 2 Pages: 524-527
  • DOI: 10.1039/c1sc00665g
  • Peer Reviewed
• [Journal Article] Synthesis of Directly Connected BODIPY Oligomers through Suzuki-Miyaura Coupling (2011)
  • Author(s): Y. Hayashi, S. Yamaguchi, W. Y. Cha, D. Kim, H. Shinokubo
  • Journal Title: Org. Lett. Volume: 13 Issue: 10 Pages: 2992-2995
  • DOI: 10.1021/ol2004534
  • Peer Reviewed
• [Journal Article] Peripherally cyclometalated iridium complexes of dipyridylporphyrin (2011)
  • Author(s): Yoshida, K., Nakashima, T., Yamaguchi, S., Osuka, A., Shinokubo, H.
  • Journal Title: Dalton Trans. Volume: 40 Issue: 35 Pages: 8773-8775
  • DOI: 10.1039/c1dt10246j
  • Peer Reviewed
• [Journal Article] A Hexameric Porphyrin Triangle Constructed by Suzuki-Miyaura Cross-Coupling (2011)
  • Author(s): J. Song, S. Anabuki, N. Aratani, H. Shinokubo, A. Osuka
  • Journal Title: Chem. Lett Volume: 40 Issue: 9 Pages: 902-903
  • DOI: 10.1246/cl.2011.902
  • NAID: 10029521264
  • Peer Reviewed
• [Journal Article] A β-to-β 2,5-Thienylene-bridged Cyclic Porphyrin Tetramer : Its Rational Synthesis and Binding of C_<60> (2011)
  • Author(s): Song, J., Aratani, N., Shinokubo, H., Osuka, A.
  • Journal Title: Chem.Sci. Volume: 2 Issue: 4 Pages: 748-751
  • DOI: 10.1039/c0sc00605j
  • Peer Reviewed
• [Journal Article] Metal-Mediated Synthesis of Antiaromatic Porphyrinoids from a BODIPY Precursor (2011)
  • Author(s): T. Sakida, S. Yamaguchi, H. Shinokubo
  • Journal Title: Angew. Chem. Int. Ed Volume: 50 Issue: 10 Pages: 2280-2283
  • DOI: 10.1002/anie.201006314
  • Peer Reviewed
• [Journal Article] Synthesis of a diimidazolylporphyrin pincer palladium complex (2011)
  • Author(s): Yamamoto, J., Shimizu, T., Yamaguchi, S., Aratani, N., Shinokubo, H., Osuka, A.
  • Journal Title: J.Porphyrins Phthalocyanines Volume: 15 Issue: 07n08 Pages: 534-538
  • DOI: 10.1142/s1088424611002908
  • Peer Reviewed
• [Journal Article] Synthesis of Directly Connected BODIPY Oligomers through Suzuki-Miyaura Coupling (2011)
  • Author(s): Yosuke Hayashi
  • Journal Title: Org.Lett. Volume: 13 Issue: 12 Pages: 2992-2995
  • DOI: 10.1021/ol200799u
  • Peer Reviewed
• [Journal Article] A Porphyrin Nanobarrel That Encapsulates C60 (2010)
  • Author(s): Song, J.; Aratani, N.; Shinokubo, H.; Osuka, A
  • Journal Title: J. Am. Chem. Soc Volume: 132 Issue: 46 Pages: 16356-16357
  • DOI: 10.1021/ja107814s
  • Peer Reviewed
• [Journal Article] Pt(II)-and Pt(IV)-Porphyrin Pincer Complexes : Synthesis, Structures, and Reactivity (2010)
  • Author(s): K. Yoshida, S. Yamaguchi, A. Osuka, H. Shinokubo
  • Journal Title: Organometallics Volume: 29 Issue: 17 Pages: 3997-4000
  • DOI: 10.1021/om100644n
  • Peer Reviewed
• [Journal Article] Directly Pd(II)-Bridged Porphyrin Belts with Remarkable Curvatures (2010)
  • Author(s): J. Song, N. Aratani, J. H. Heo, D. Kim, H. Shinokubo, A. Osuka
  • Journal Title: J. Am. Chem. Soc Volume: 132 Issue: 34 Pages: 11868-11869
  • DOI: 10.1021/ja1046654
  • Peer Reviewed
• [Journal Article] η2-Porphyrin Ru(II)π-Complexes (2010)
  • Author(s): S. Yamaguchi, H. Shinokubo, A. Osuka
  • Journal Title: J. Am. Chem. Soc Volume: 132 Issue: 29 Pages: 9992-9993
  • DOI: 10.1021/ja104842h
  • Peer Reviewed
• [Journal Article] Porphyrin "Lego Block" Strategy To Construct Directly meso-βDoubly Linked Porphyrin Rings (2010)
  • Author(s): J. Song, N. Aratani, P. Kim, D. Kim, H. Shinokubo, A. Osuka
  • Journal Title: Angew. Chem., Int. Ed Volume: 49 Issue: 21 Pages: 3617-3620
  • DOI: 10.1002/anie.201000915
  • Peer Reviewed
• [Journal Article] Excess Polarizability Reveals Exciton Localization/Delocalization Controlled by Linking Positions on Porphyrin Rings in Butadiyne-Bridged Porphyrin Dimers (2010)
  • Author(s): C. She, S. Easwaramoorthi, P. Kim, S. Hiroto, I. Hisaki, H. Shinokubo, A. Osuka, D. Kim, J. T. Hupp
  • Journal Title: J. Phys. Chem. A Volume: 114 Issue: 10 Pages: 3384-3390
  • DOI: 10.1021/jp908767x
  • Peer Reviewed
• [Journal Article] Strategic Synthesis of 2, 6-Pyridylene-Bridgedβ-to-βPorphyrin Nanorings through Cross-Coupling (2010)
  • Author(s): J. Song, P. Kim, N. Aratani, D. Kim, H. Shinokubo, A. Osuka
  • Journal Title: Chem. Eur. J. Volume: 16 Issue: 10 Pages: 3009-3012
  • DOI: 10.1002/chem.200903177
  • Peer Reviewed
• [Journal Article] Synthesis of meso,meso'-Pyrrole-Bridged Diporphyrins by Cu(I)-Mediated Annulation (2010)
  • Author(s): Chihiro Maeda
  • Journal Title: Org.Lett. Volume: 12 Pages: 1820-1823
  • Peer Reviewed
• [Journal Article] Large Porphyrin Squares from the Self-Assembly of meso-Triazole-Appended L-Shaped meso-meso-Linked Zn_<11>-Triporphyrins : Synthesis and Efficient Energy Transfer (2010)
  • Author(s): Chihiro Maeda
  • Journal Title: Chem.Eur.J. Volume: 16 Pages: 5052-5061
  • Peer Reviewed
• [Journal Article] Porphyrin "Lego Block" Strategy To Construct Directly meso-β Doubly Linked Porphyrin Rings (2010)
  • Author(s): Jianxin Song
  • Journal Title: Angew.Chem., Int.Ed. Volume: 49 Pages: 3617-3620
  • Peer Reviewed
• [Journal Article] η^2-Porphyrin Ru(II) π-Complexes (2010)
  • Author(s): Shigeru Yamaguchi
  • Journal Title: J.Am.Chem.Soc. Volume: 132 Pages: 9992-9993
  • Peer Reviewed
• [Journal Article] Directly Pd(II)-Bridged Porphyrin Belts with Remarkable Curvatures (2010)
  • Author(s): Jianxin Song
  • Journal Title: J.Am.Chem.Soc. Volume: 132 Pages: 11868-11869
  • Peer Reviewed
• [Journal Article] Pt(II)- and Pt(IV)-Porphyrin Pincer Complexes : Synthesis, Structures, and Reactivity (2010)
  • Author(s): Keita Yoshida
  • Journal Title: Organometallics Volume: 29 Pages: 3997-4000
  • Peer Reviewed
• [Journal Article] A Porphyrin Nanobarrel that Encapsulates C_<60> (2010)
  • Author(s): Jianxin Song
  • Journal Title: J.Am.Chem.Soc. Volume: 132 Pages: 16356-16357
  • Peer Reviewed
• [Journal Article] A Pyrrole-Bridged Porphyrin Nanorings (2010)
  • Author(s): Jianxin Song
  • Journal Title: Chem.Eur.J. Volume: 16 Pages: 13320-13324
  • Peer Reviewed
• [Journal Article] Strategic Synthesis of 2,6-Pyridylene-Bridged β-to-β Porphyrin Nanorings through Cross-Coupling (2010)
  • Author(s): Jianxin Song
  • Journal Title: Chem.Eur.J. 16 Pages: 3009-3012
  • Peer Reviewed
• [Journal Article] Excess Polarizability Reveals Exciton Localization/Delocalization Controlled by Linking Positions on Porphyrin Rings in Butadiyne-Bridged Porphyrin Dimers (2010)
  • Author(s): Chunxing She
  • Journal Title: J.Phys.Chem.A 114 Pages: 3384-3390
  • Peer Reviewed
• [Journal Article] Doublyβ-functionalized meso-meso Directly Linked Porphyrin Dimer Sensitizers for Photovoltaics (2009)
  • Author(s): J. K. Park, J. Chen, H. R. Lee, S. W. Park, H. Shinokubo, A. Osuka, D. Kim
  • Journal Title: J. Phys. Chem. C Volume: 113 Issue: 52 Pages: 21956-21963
  • DOI: 10.1021/jp905675x
  • Peer Reviewed
• [Journal Article] Synthesis of Arylated Perylene Bisimides through C-H Bond Cleavage under Ruthenium Catalysis (2009)
  • Author(s): S. Nakazono, S. Easwaramoorthi, D. Kim, H. Shinokubo, A. Osuka
  • Journal Title: Org. Lett. Volume: 11 Issue: 23 Pages: 5426-5429
  • DOI: 10.1021/ol902271b
  • Peer Reviewed
• [Journal Article] Palladium-Catalyzed Dimerization of meso-Bromoporphyrins : Highly Regioselective meso-βCoupling via Unprecedented Remote C. H bond Cleavage (2009)
  • Author(s): S. Tokuji, T. Yurino, N. Aratani, H. Shinokubo, A. Osuka
  • Journal Title: Chem. Eur. J. Volume: 15 Issue: 45 Pages: 12208-12211
  • DOI: 10.1002/chem.200902143
  • Peer Reviewed
• [Journal Article] Regioselective Ru-Catalyzed Direct 2, 5, 8, 11-Alkylation of Perylene Bisimides (2009)
  • Author(s): S. Nakazono, Y. Imazaki, H. Yoo, J. Yang, T. Sasamori, N. Tokitoh, T. Cedric, H. Kageyama, D. Kim, H. Shinokubo, A. Osuka
  • Journal Title: Chem. Eur. J. Volume: 15 Issue: 31 Pages: 7530-7533
  • DOI: 10.1002/chem.200901318
  • Peer Reviewed
• [Journal Article] Post-Modification of meso-meso Linked Porphyrin Arrays via Iridium and Rhodium Catalyses for Tuning of Energy Gap (2009)
  • Author(s): J. Chen, N. Aratani, H. Shinokubo, A. Osuka
  • Journal Title: Chem. Asian J. Volume: 4 Issue: 7 Pages: 1126-1133
  • DOI: 10.1002/asia.200900053
  • Peer Reviewed
• [Journal Article] Unusual Interchromophoric Interactions inβ,β'-Directly and Doubly Linked Corrole Dimers : Prohibited Electronic Communication and Abnormal Singlet Ground States (2009)
  • Author(s): S. Cho, J. M. Lim, S. Hiroto, P. Kim, H. Shinokubo, A. Osuka, D. Kim
  • Journal Title: J. Am. Chem. Soc Volume: 131 Issue: 18 Pages: 6412-6420
  • DOI: 10.1021/ja900220y
  • Peer Reviewed
• [Journal Article] Functionalization of BODIPY Dyes through Iridium and Rhodium Catalyses : A Complementary Approach toα-andβ-Substituted BODIPYs (2009)
  • Author(s): J. Chen, M. Mizumura, H. Shinokubo, A. Osuka
  • Journal Title: Chem. Eur. J. Volume: 15 Issue: 24 Pages: 5924-5949
  • DOI: 10.1002/chem.200802541
  • Peer Reviewed
• [Journal Article] Synthesis of Arylated Perylene Bisimides through C-H Bond Cleavage under Ruthenium Catalysis (2009)
  • Author(s): Satomi Nakazono
  • Journal Title: Org.Lett. 11 Pages: 5426-2429
  • Peer Reviewed
• [Journal Article] Regioselective Ru-Catalyzed Direct 2,5,8,11-Alkylation of Perylene Bisimides (2009)
  • Author(s): Satomi Nakazono
  • Journal Title: Chem.Eur.J. 15 Pages: 7530-7533
  • Peer Reviewed
• [Journal Article] Post-Modification of meso-meso Linked Porphyrin Arrays via Iridium and Rhodium Catalyses for Tuning of Energy Gap (2009)
  • Author(s): Jinping Chen
  • Journal Title: Chem.Asian J. 4 Pages: 1126-11333
  • Peer Reviewed
• [Journal Article] Functionalization of BODIPY Dyes through Iridium and Rhodium Catalyses : A Complementary Approach to α- and β-Substituted BODIPYs (2009)
  • Author(s): Jinping Chen
  • Journal Title: Chem.Eur.J. 15 Pages: 5924-5949
  • Peer Reviewed
• [Journal Article] Porphyrin Derivatives with Carbon-Metal Bonds (2009)
  • Author(s): Satoru Hiroto
  • Journal Title: J.Synth.Org.Chem.Jpn. 17 Pages: 688-700
  • Peer Reviewed
• [Journal Article] Unusual Interchromophoric Interactions in β,β'-Directly and Doubly Linked Corrole Dimers : Prohibited Electronic Communication and Abnormal Singlet Ground States (2009)
  • Author(s): Sung Cho
  • Journal Title: J.Am.Chem.Soc. 131 Pages: 6412-6420
  • Peer Reviewed
• [Journal Article] Doubly β-functionalized meso-meso Directly Linked Porphyrin Dimer Sensitizers for Photovoltaics (2009)
  • Author(s): Jong Kang
  • Journal Title: J.Phys.Chem.C 113 Pages: 21956-21963
  • Peer Reviewed
• [Journal Article] Palladium-Catalyzed Dimerization of meso-Bromoporphyrins : Highly Regioselective meso-β Coupling via Unprecedented Remote C-H bond Cleavage (2009)
  • Author(s): Sumito Tokuji
  • Journal Title: Chem.Eur.J. 15 Pages: 12208-12211
  • Peer Reviewed
• [Presentation] 縮環ペリレンビスイミドとナフタレンイミドの合成とその物性 (2012)
  • Author(s): 伊藤覚,廣戸聡,忍久保洋
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2012-03-27
• [Presentation] 縮環ペリレンビスイミドとナフタレンイミドの合成とその物性 (2012)
  • Author(s): 伊藤覚
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学(神奈川県)
  • Year and Date: 2012-03-27
• [Presentation] インドールからなる環状多量体とその類縁体 (2012)
  • Author(s): 近藤剛資,中村翔一,廣戸聡,忍久保洋
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2012-03-26
• [Presentation] インドールからなる環状多量体とその類縁体 (2012)
  • Author(s): 近藤剛資
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応義塾大学(神奈川県)
  • Year and Date: 2012-03-26
• [Presentation] Synthesis of Novel Porphyrins via Transition Metal Catalysis (2011)
  • Author(s): H. Shinokubo
  • Organizer: The 6th International Conference on Cutting-Edge Organic Chemistry in Asia
  • Place of Presentation: Hong Kong
  • Year and Date: 2011-12-14
• [Presentation] Synthesis of Novel Porphyrins via Transition Metal Catalysis (2011)
  • Author(s): Hiroshi Shinokubo
  • Organizer: The 6th International Conference on Cutting-Edge Organic Chemistry in Asia
  • Place of Presentation: Hong Kong (Hong Kong)(招待講演)
  • Year and Date: 2011-12-14
• [Presentation] Synthesis and Properties of Fused Perylene Bisimides and Naphtalene Monoimide (2011)
  • Author(s): S. Ito, S. Hiroto, H. Shinokubo
  • Place of Presentation: Nagoya
  • Year and Date: 2011-11-28
• [Presentation] Synthesis of Cyclic Oligomers Containing Indole and Benzofuran (2011)
  • Author(s): T. Kondo, S. Nakamura, S. Hiroto, H. Shinokubo
  • Place of Presentation: Nagoya
  • Year and Date: 2011-11-28
• [Presentation] Synthesis of Cyclic Oligomers Containing Indole and Benzofuran (2011)
  • Author(s): Takeshi Kondo
  • Organizer: Nagoya University Global COE International Symposium
  • Place of Presentation: 名古屋大学(愛知県)
  • Year and Date: 2011-11-28
• [Presentation] Synthesis and Properties of Fused Perylene Bisimides and Naphtalene Monoimide (2011)
  • Author(s): Satoru Ito
  • Organizer: Nagoya University Global COE International Symposium
  • Place of Presentation: 名古屋大学(愛知県)
  • Year and Date: 2011-11-28
• [Presentation] インドール環状四量体の合成と構造 (2011)
  • Author(s): 中村翔一,廣戸聡,忍久保洋
  • Organizer: 第22回基礎有機化学討論会
  • Place of Presentation: つくば
  • Year and Date: 2011-09-22
• [Presentation] インドール環状四量体の合成と構造 (2011)
  • Author(s): 中村翔一
  • Organizer: 第22回基礎有機化学討論会
  • Place of Presentation: つくば国際会議場(茨城県)
  • Year and Date: 2011-09-22
• [Presentation] ペリレンビスイミドの直接ホウ素化を利用した窒素含有多環芳香族化合物の合成 (2011)
  • Author(s): 廣戸聡,伊藤覚,忍久保洋
  • Organizer: 第22回基礎有機化学討論会
  • Place of Presentation: つくば
  • Year and Date: 2011-09-21
• [Presentation] ペリレンビスイミドの直接ホウ素化を利用した窒素含有多環芳香族化合物の合成 (2011)
  • Author(s): 廣戸聡
  • Organizer: 第22回基礎有機化学討論会
  • Place of Presentation: つくば国際会議場(茨城県)
  • Year and Date: 2011-09-21
• [Presentation] Synthesis of Novel Porphyrins via Transition Metal Catalysis (2011)
  • Author(s): Hiroshi Shinokubo
  • Organizer: 錯体化学会第61回討論会
  • Place of Presentation: 岡山理科大学(岡山県)(招待講演)
  • Year and Date: 2011-09-18
• [Presentation] Synthesis of Novel Porphyrins via Transition Metal Catalysis (2011)
  • Author(s): H. Shinokubo
  • Organizer: 錯体化学会第61回討論会ミニシンポジウムCarbon-rich Coordination Chemistry
  • Place of Presentation: Okayama
  • Year and Date: 2011-09-17
• [Presentation] ジアリールエテンの遷移金属触媒反応による新規合成法の開発 (2011)
  • Author(s): 神谷拓輝,柳澤周一,鈴木勝也,廣戸聡,伊丹健一郎,忍久保洋
  • Organizer: 第58回有機金属化学討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2011-09-09
• [Presentation] 遷移金属触媒反応によるインドール類の環状多量体合成 (2011)
  • Author(s): 中村翔一,近藤剛資,廣戸聡,忍久保洋
  • Organizer: 第58回有機金属化学討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2011-09-09
• [Presentation] 遷移金属触媒反応によるインドール類の環状多量体合成 (2011)
  • Author(s): 中村翔一
  • Organizer: 第58回有機金属化学討論会
  • Place of Presentation: 名古屋大学(愛知県)
  • Year and Date: 2011-09-09
• [Presentation] ジアリールエテンの遷移金属触媒反応による新規合成法の開発 (2011)
  • Author(s): 神谷拓輝
  • Organizer: 第58回有機金属化学討論会
  • Place of Presentation: 名古屋大学(愛知県)
  • Year and Date: 2011-09-09
• [Presentation] イリジウム触媒によるペリレンビスイミドの位置選択的直接ホウ素化反応の開発 (2011)
  • Author(s): 廣戸聡,寺岡拓朗,伊藤覚,忍久保洋
  • Organizer: 第58回有機金属化学討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2011-09-08
• [Presentation] Functionalization ofπ-Systems through Transition Metal Catalysis (2011)
  • Author(s): H. Shinokubo
  • Organizer: 14th Asian Chemical Congress 2011
  • Place of Presentation: Bangkok
  • Year and Date: 2011-09-08
• [Presentation] Synthesis of Novel Porphyrins via Transition Metal Catalysis (2011)
  • Author(s): Hiroshi Shinokubo
  • Organizer: 14th Asian Chemical Congress 2011
  • Place of Presentation: Bangkok (Thailand)(招待講演)
  • Year and Date: 2011-09-08
• [Presentation] イリジウム触媒によるペリレンビスイミドの位置選択的直接ホウ素化反応の開発 (2011)
  • Author(s): 廣戸聡
  • Organizer: 第58回有機金属化学討論会
  • Place of Presentation: 名古屋大学(愛知県)
  • Year and Date: 2011-09-08
• [Presentation] Synthesis of Novel Porphyrins via Transition Metal Catalysis (2011)
  • Author(s): H. Shinokubo
  • Organizer: JSPS-NTU/NUS Joint Seminar
  • Place of Presentation: Singapore
  • Year and Date: 2011-08-01
• [Presentation] Synthesis of Novel Porphyrins via Transition Metal Catalysis (2011)
  • Author(s): Hiroshi Shinokubo
  • Organizer: JSPS-NTU/NUS Joint Seminar
  • Place of Presentation: Singapor (Singapore)(招待講演)
  • Year and Date: 2011-08-01
• [Presentation] Synthesis of Functionalπ-Systems via Transition Metal Catalysis Nagoya University Global COE in Chemistry (2011)
  • Author(s): H. Shinokubo
  • Organizer: 4th Annual Symposium
  • Place of Presentation: Nagoya
  • Year and Date: 2011-06-15
• [Presentation] Synthesis of Functional π-Systems via Transition Metal Catalysis (2011)
  • Author(s): Hiroshi Shinokubo
  • Organizer: Nagoya University Global COE in Chemistry 4th Annual Symposium
  • Place of Presentation: 名古屋大学(愛知県)
  • Year and Date: 2011-06-15
• [Presentation] Synthesis of a π-Extended Quinone Based on Hexa-peri-Hexabenzocoronene (2011)
  • Author(s): Ryuichi Yamaguchi
  • Organizer: Nagoya University Global COE in Chemistry 4th Annual Symposium
  • Place of Presentation: 名古屋大学(愛知県)
  • Year and Date: 2011-06-15
• [Presentation] BODIPYの位置選択的臭素化反応の開発とその応用 (2011)
  • Author(s): 林陽介
  • Organizer: 第91日本化学会春季年会
  • Place of Presentation: (要旨集)
  • Year and Date: 2011-03-11
• [Presentation] 直接ホウ素化によるヘキサベンゾコロネンの修飾反応の開発 (2011)
  • Author(s): 伊藤覚
  • Organizer: 第91日本化学会春季年会
  • Place of Presentation: (要旨集)
  • Year and Date: 2011-03-11
• [Presentation] アリール縮環BODIPY誘導体合成法の開発 (2011)
  • Author(s): 田丸雅朝
  • Organizer: 第91日本化学会春季年会
  • Place of Presentation: (要旨集)
  • Year and Date: 2011-03-11
• [Presentation] インドールおよびその類縁体からなる環状四量体の合成 (2011)
  • Author(s): 近藤剛資
  • Organizer: 第91日本化学会春季年会
  • Place of Presentation: (要旨集)
  • Year and Date: 2011-03-11
• [Presentation] ポルフィリンピンサー型錯体の合成と性質 (2011)
  • Author(s): 山口滋
  • Organizer: 第91日本化学会春季年会
  • Place of Presentation: (要旨集)
  • Year and Date: 2011-03-11
• [Presentation] 二重ピリジル架橋ポルフィリン多量体の合成と性質 (2011)
  • Author(s): 穴吹翔馬
  • Organizer: 第91日本化学会春季年会
  • Place of Presentation: (要旨集)
  • Year and Date: 2011-03-11
• [Presentation] ヘキサベンゾコロネンの位置選択的C-Hホウ素化反応とその応用 (2010)
  • Author(s): 山口龍一,廣戸聡,忍久保洋
  • Organizer: 第57回有機金属化学討論会
  • Place of Presentation: 東京
  • Year and Date: 2010-09-18
• [Presentation] ヘキサベンゾコロネンの位置選択的C-Hホウ素化反応とその応用 (2010)
  • Author(s): 山口龍一
  • Organizer: 第57回有機金属化学討論会
  • Place of Presentation: 中央大学(東京都)
  • Year and Date: 2010-09-18
• [Presentation] ポルフィリンピンサー金属錯体の合成と性質 (2010)
  • Author(s): 山口滋,大須賀篤弘,忍久保洋
  • Organizer: 第57回有機金属化学討論会
  • Place of Presentation: 東京
  • Year and Date: 2010-09-16
• [Presentation] ポルフィリンピンサー金属錯体の合成と性質 (2010)
  • Author(s): 山口滋
  • Organizer: 第57回有機金属化学討論会
  • Place of Presentation: 中央大学(東京都)
  • Year and Date: 2010-09-16
• [Presentation] ブタジイン架橋BODIPY二量体の合成とその反芳香族性 (2010)
  • Author(s): 崎田孝文,山口滋,忍久保洋
  • Organizer: 第21回基礎有機化学討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2010-09-11
• [Presentation] ポルフィリンピンサー白金錯体の合成と性質 (2010)
  • Author(s): 吉田恵太
  • Organizer: 第21回基礎有機化学討論会
  • Place of Presentation: 名古屋大学(愛知県)
  • Year and Date: 2010-09-10
• [Presentation] ペリレンビスイミドの位置選択的ホウ素化反応の開発と応用 (2010)
  • Author(s): 寺岡拓朗
  • Organizer: 第21回基礎有機化学討論会
  • Place of Presentation: 名古屋大学(愛知県)
  • Year and Date: 2010-09-10
• [Presentation] ポルフィリンピンサー白金錯体の合成と性質 (2010)
  • Author(s): 吉田恵太,山口滋,忍久保洋
  • Organizer: 第21回基礎有機化学討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2010-09-09
• [Presentation] ペリレンビスイミドの位置選択的ホウ素化反応の開発と応用 (2010)
  • Author(s): 寺岡拓朗,廣戸聡,忍久保洋
  • Organizer: 第21回基礎有機化学討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2010-09-09
• [Presentation] η2-ポルフィリンRu(II)π-錯体の合成 (2010)
  • Author(s): 山口滋,忍久保洋,大須賀篤弘
  • Organizer: 第21回基礎有機化学討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2010-09-09
• [Presentation] β,β'ビスピリジルポルフィリンピンサー白金錯体の合成とその性質 (2010)
  • Author(s): 穴吹翔馬,山本純,忍久保洋,荒谷直樹,大須賀篤弘
  • Organizer: 第21回基礎有機化学討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2010-09-09
• [Presentation] β結合BODIPY多量体の合成とその性質 (2010)
  • Author(s): 林陽介,山口滋,忍久保洋
  • Organizer: 第21回基礎有機化学討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2010-09-09
• [Presentation] η^2-ポルフィリンRu(II)π-錯体の合成 (2010)
  • Author(s): 山口滋
  • Organizer: 第21回基礎有機化学討論会
  • Place of Presentation: 名古屋大学(愛知県)
  • Year and Date: 2010-09-09
• [Presentation] β,β'ビスピリジルポルフィリンピンサー白金錯体の合成とその性質 (2010)
  • Author(s): 穴吹翔馬
  • Organizer: 第21回基礎有機化学討論会
  • Place of Presentation: 名古屋大学(愛知県)
  • Year and Date: 2010-09-09
• [Presentation] β結合BODIPY多量体の合成とその性質 (2010)
  • Author(s): 林陽介
  • Organizer: 第21回基礎有機化学討論会
  • Place of Presentation: 名古屋大学(愛知県)
  • Year and Date: 2010-09-09
• [Presentation] Synthesis of Large Functional Molecules through Transition Metal Catalysis (2010)
  • Author(s): H. Shinokubo
  • Organizer: 2010 Japan-China Joint Symposium on Functional Supramolecular Architectures
  • Place of Presentation: Changchun
  • Year and Date: 2010-07-26
• [Presentation] Synthesis of Large Functional Molecules through Transition Metal Catalysis (2010)
  • Author(s): Hiroshi Shinokubo
  • Organizer: 2010 Japan-China Joint Symposium on Functional Supramolecular Architectures
  • Place of Presentation: Changchun, China
  • Year and Date: 2010-07-26
• [Presentation] β,β'-ビスイミダゾリルポルフィリンピンサー錯体の合成と性質 (2010)
  • Author(s): 山本純,志水朋洋,忍久保洋,大須賀篤弘
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2010-03-29
• [Presentation] パラジウム触媒を用いたポルフィリンの特殊な置換位置での二量化反応 (2010)
  • Author(s): 徳地澄人,百合野大雅,忍久保洋,大須賀篤弘
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2010-03-29
• [Presentation] η2-Ru-ポルフィリンπ錯体の合成 (2010)
  • Author(s): 山口滋,忍久保洋,大須賀篤弘
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2010-03-29
• [Presentation] パラジウム触媒を用いたポルフィリンの特殊な置換位置での二量化反応 (2010)
  • Author(s): 徳地澄人
  • Organizer: 第90日本化学会春季年会
  • Place of Presentation: 近畿大学(大阪府)
  • Year and Date: 2010-03-29
• [Presentation] ポルフィリンピンサー白金錯体の合成と性質 (2010)
  • Author(s): 吉田恵太,山口滋,忍久保洋
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2010-03-28
• [Presentation] ブタジイン架橋BODIPY二量体の合成とその物性 (2010)
  • Author(s): 崎田孝文,山口滋,忍久保洋
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2010-03-28
• [Presentation] β-アミノポルフィリンの合成及びその物性 (2010)
  • Author(s): 秋田将成,廣戸聡,忍久保洋
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2010-03-27
• [Presentation] β結合BODIPY多量体の合成とその性質 (2010)
  • Author(s): 林陽介,山口滋,忍久保洋
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2010-03-27
• [Presentation] アザインドール環を用いたポルフィリン集合体の形成 (2010)
  • Author(s): 前田千尋,忍久保洋,大須賀篤弘
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2010-03-27
• [Presentation] アザインドール環を用いたポルフィリン集合体の形成 (2010)
  • Author(s): 前田千尋
  • Organizer: 第90日本化学会春季年会
  • Place of Presentation: 近畿大学(大阪府)
  • Year and Date: 2010-03-27
• [Presentation] β結合BODIPY多量体の合成とその性質 (2010)
  • Author(s): 林陽介
  • Organizer: 第90日本化学会春季年会
  • Place of Presentation: 近畿大学(大阪府)
  • Year and Date: 2010-03-27
• [Presentation] ペリレンビスイミドの位置選択的ホウ素化反応の開発と応用 (2010)
  • Author(s): 寺岡拓朗,廣戸聡,忍久保洋
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 大阪
  • Year and Date: 2010-03-26
• [Presentation] ペリレンビスイミドの位置選択的ホウ素化反応の開発と応用 (2010)
  • Author(s): 寺岡卓朗
  • Organizer: 第90日本化学会春季年会
  • Place of Presentation: 近畿大学(大阪府)
  • Year and Date: 2010-03-26
• [Presentation] 遷移金属触媒反応による新しいポルフィリンの合成 (2010)
  • Author(s): 忍久保洋
  • Organizer: 近畿化学協会有機金属部会平成21年度第4回例会
  • Place of Presentation: 大阪
  • Year and Date: 2010-02-02
• [Presentation] 遷移金属触媒反応による新しいポルフィリンの合成 (2010)
  • Author(s): 忍久保洋
  • Organizer: 有機金属部会平成21年度第4回例会
  • Place of Presentation: 大阪科学技術センター(大阪府)
  • Year and Date: 2010-02-02
• [Presentation] Synthesis ofβ-Bridged Cyclic Porphyrin Arrays through Cross-Coupling (2009)
  • Author(s): J. Song, N. Aratani, H. Shinokubo, A. Osuka
  • Organizer: The 11th International Kyoto Conference on New Aspects of Organic Chemistry
  • Place of Presentation: Kyoto
  • Year and Date: 2009-11-10
• [Presentation] Synthesis of β-Bridged Cyclic Porphyrin Arrays through Cross-Coupling (2009)
  • Author(s): 忍久保洋
  • Organizer: The 11th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-11)
  • Place of Presentation: RIHGA Royal Hotel Kyoto(京都府)
  • Year and Date: 2009-11-10
• [Presentation] Synthesis of Novel Porphyrins through Transition Metal Catalysis International Symposium on Chemistry and Materials Science (2009)
  • Author(s): H. Shinokubo
  • Place of Presentation: Okazaki
  • Year and Date: 2009-11-02
• [Presentation] Synthesis of Novel Porphyrins through Transition Metal Catalysis (2009)
  • Author(s): 忍久保洋
  • Organizer: International Symposium on Chemistry and Materials Science
  • Place of Presentation: 分子科学研究所(愛知県)
  • Year and Date: 2009-11-02
• [Presentation] β-(2-ピリジル)ポルフィリンのルテニウムカチオンへの配位挙動 (2009)
  • Author(s): 山口滋,忍久保洋,大須賀篤弘
  • Organizer: 第20回基礎有機化学討論会
  • Place of Presentation: 桐生
  • Year and Date: 2009-09-29
• [Presentation] β-(2-ピリジル)ポルフィリンのルテニウムカチオンへの配位挙動 (2009)
  • Author(s): 山口滋
  • Organizer: 第20回基礎有機化学討論会
  • Place of Presentation: 群馬大学(群馬県)
  • Year and Date: 2009-09-29
• [Presentation] パラジウム触媒を用いたポルフィリンの異常な置換位置での二量化反応 (2009)
  • Author(s): 徳地澄人,百合野大雅,荒谷直樹,忍久保洋,大須賀篤弘
  • Organizer: 第56回有機金属化学討論会
  • Place of Presentation: 京都
  • Year and Date: 2009-09-10
• [Presentation] パラジウム触媒を用いたポルフィリンの異常な置換位置での二量化反応 (2009)
  • Author(s): 徳地澄人
  • Organizer: 第56回有機金属化学討論会
  • Place of Presentation: 同志社大学(京都府)
  • Year and Date: 2009-09-10
• [Book] 有機合成化学 (2012)
  • Author(s): 大嶌幸一郎
  • Total Pages: 408
  • Publisher: 東京化学同人
• [Book] ジアリールエテンの新規合成法の開発 (2011)
  • Author(s): 廣戸聡,忍久保洋
  • Publisher: シーエムシー出版
• [Book] フォトクロミズムの新展開と光メカニカル機能材料 (2011)
  • Author(s): 入江正浩
  • Total Pages: 337
  • Publisher: シーエムシー出版
• [Remarks]
  • URL: http://www.apchem.nagoya-u.ac.jp/hshino/sub/research/research.html
• [Remarks]
  • URL: http://www.apchem.nagoya-u.ac.jp/hshino/sub/publication/publication.html
• [Remarks]
  • URL: http://www.apchem.nagoya-u.ac.jp/hshino/sub/research/research.html
• [Remarks]
  • URL: http://kenpro.mynu.jp:8001/Profiles/0060/0006050/profile.html
• [Remarks]
  • URL: http://www.apchem.nagoya-u.ac.jp/hshino/sub/research/research.html
• [Remarks]
  • URL: http://kenpro.mynu.jp:8001/Profiles/0060/0006050/profile.html