• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of organic thin-film magnetoresistance devices based on molecular spins

Research Project

Project/Area Number 21685015
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionNagoya University

Principal Investigator

MATSUSHITA Michio  名古屋大学, 理学研究科, 准教授 (80295477)

Co-Investigator(Renkei-kenkyūsha) SUGAWARA Tadashi  東京大学, 複雑系生命システム研究センター, 特任研究員 (50124219)
AWAGA Kunio  名古屋大学, 物質科学国際研究センター, 教授 (10202772)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥27,170,000 (Direct Cost: ¥20,900,000、Indirect Cost: ¥6,270,000)
Fiscal Year 2011: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2010: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
Fiscal Year 2009: ¥13,390,000 (Direct Cost: ¥10,300,000、Indirect Cost: ¥3,090,000)
Keywords分子磁性 / 有機ラジカル / 有機導体 / 磁気抵抗 / プリンタブルエレクトロニクス / 有機薄膜トランジスタ
Research Abstract

To develop printable magneto resistance device, novel organic donor radicals, having characteristic electronic structure, were designed and synthesized. Among them, 5 molecules showed giant negative magneto resistance in their neutral crystalline films. The magneto resistance in these systems are derived from intramolecular interaction between spins in unpaired electrons inπ-organic radical moieties and conduction electrons mediated by the stacking structure ofπ-donor moieties.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (37 results)

All 2012 2011 2010 2009

All Journal Article (27 results) (of which Peer Reviewed: 27 results) Presentation (10 results)

  • [Journal Article] Ionic liquid component dependence of carrier injection and mobility for electric double layer organic thin film transistors for electronic device2012

    • Author(s)
      T. Fujimoto, M. M. Matsushita, and K. Awaga
    • Journal Title

      J. Phys. Chem. C

      Volume: 116 Pages: 5240-5245

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure, Spin Polarization, Solid-State Electrochemistry, and High n-Type Carrier Mobility of a Paramagnetic Semiconductor : Vanadyl Tetrakis(thiadiazole) porphyrazine2012

    • Author(s)
      Y. Miyoshi, K. Takahashi, T. Fujimoto, H. Yoshikawa, M. M. Matsushita, Y. Ouchi, M. Kepenekian, V. Robert, M. P. Donzello, C. Ercolani, and K. Awaga
    • Journal Title

      Inorg. Chem.

      Volume: 51 Pages: 456-462

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal Structure, Spin Polarization, Solid-State Electrochemistry, and High n-Type Carrier Mobility of a Paramagnetic Semiconductor : Vanadyl Tetrakis (thiadiazole) porphyrazine2012

    • Author(s)
      三吉康仁
    • Journal Title

      Inorg.Chem.

      Volume: 51 Issue: 1 Pages: 456-462

    • DOI

      10.1021/ic201880g

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ionic-Liquid Component Dependence of Carrier Injection and Mobility for Electric-Double-Layer Organic Thin-Film Transistors2012

    • Author(s)
      藤本卓也
    • Journal Title

      J.Phys.Chem.C

      Volume: 116 Issue: 8 Pages: 5240-5245

    • DOI

      10.1021/jp2122642

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly efficient organic optoelectronic conversion induced by electric double layers in ionic liquids2012

    • Author(s)
      Bo Li, 他6名
    • Journal Title

      Applied Physics Letters

      Volume: 100 Issue: 16 Pages: 163304-163304

    • DOI

      10.1063/1.3697988

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of photoinduced charge displacement on organic optoelectronic conversion2011

    • Author(s)
      L. Hu, A. Iwasaki, R. Suizu, Y. Noda, B. Li, H. Yoshikawa, M. M. Matsushita, and K. Awaga
    • Journal Title

      Phys. Rev.

      Volume: B84

    • NAID

      120006795655

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structural, Magnetic, and Electronic Properties of Phenolic Oxime Complexes of Cu and Ni2011

    • Author(s)
      A. M. White, B. Roach, D. K. Henderson, P. A. Tasker, M. M. Matsushita, K. Awaga, F. J. White, P. Richardson, and N. Robertson
    • Journal Title

      Inorg. Chem.

      Volume: 50 Pages: 12867-12876

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A complementary organic inverter of porphyrazine thin films : low-voltage operation using ionic liquid gatedielectrics2011

    • Author(s)
      T. Fujimoto, Y. Miyoshi, M. M. Matsushita, and K. Awaga
    • Journal Title

      Chem. Commun

      Volume: 47 Pages: 5837-5839

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Charge transport in various dimensions of small networks composed of gold nanoparticles and terthiophene wire-molecules2011

    • Author(s)
      Y. Noguchi, T. Terui, T. Katayama, M. M. Matsushita, and T. Sugawara
    • Journal Title

      Appl. Phys. Lett.

      Volume: 96

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photoconductivity and FET performance of an n-type porphyrazine semiconductor, tetrakis(thiadiazole) porphyrazine2011

    • Author(s)
      Y. Miyoshi, T. Fujimoto, H. Yoshikawa, M. M. Matsushita, K. Awaga, T. Yamada, and H. Ito
    • Journal Title

      Org. Electronics

      Volume: 12 Pages: 239-243

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrodeposition as a superior route to a thin film molecular semiconductor2011

    • Author(s)
      S. Dalgleish, H. Yoshikawa, M. M. Matsushita, K. Awaga, and N. Robertson
    • Journal Title

      Chem. Sci.

      Volume: 2 Pages: 316-320

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structural, Magnetic, and Electronic Properties of Phenolic Oxime Complexes of Cu and Ni2011

    • Author(s)
      Alexander M.Whyte, 他9名
    • Journal Title

      Inorganic Chemistry

      Volume: 50 Issue: 24 Pages: 12867-12876

    • DOI

      10.1021/ic2020644

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of photoinduced charge displacement on organic optoelectronic conversion2011

    • Author(s)
      Laigui Hu, Akito Iwasaki, Rie Suizu, Yukiko Noda, Bo Li, Hirofumi Yoshikawa, Michio M.Matsushita, Kunio Awaga, Hiroshi Ito
    • Journal Title

      Phys.Rev.B

      Volume: 84 Issue: 20 Pages: 205329-205329

    • DOI

      10.1103/physrevb.84.205329

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Charge transport in various dimensions of small networks composed of gold nano particles and terthiophene wire-molecules2011

    • Author(s)
      Yutaka Noguchi, 他5名
    • Journal Title

      Applied Physics Letters

      Volume: 98 Issue: 26

    • DOI

      10.1063/1.3605598

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Complementary Organic Inverter of Porphyrazine Thin Films : Low-Voltage Operation Using Ionic Liquid Gate Dielectrics2011

    • Author(s)
      藤本卓也
    • Journal Title

      Chem.Commun.

      Volume: 47 Issue: 20 Pages: 5837-5839

    • DOI

      10.1039/c0cc05198e

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoconductivity and FET performance of an n-type porphyrazine semiconductor2011

    • Author(s)
      Y.Miyoshi, T.Fujimoto, H.Yoshikawa, M.M.Matsushita, K.Awaga, T.Yamada, H.Ito
    • Journal Title

      Applied Physics Letters

      Volume: 12 Pages: 239-243

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrodeposition as a superior route to a thin film molecular semiconductor2011

    • Author(s)
      S.Dalgleish, H.Yoshikawa, M.M.Matsushita, K.Awaga, N.Robertson
    • Journal Title

      Chemistry of Science

      Volume: 2 Pages: 316-320

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Superperiodic conductance in a molecularly wired double-dot system self-assembled in ananogap electrode2010

    • Author(s)
      Y. Noguchi, T. Terui, Takuya Katayama, M. M. Matsushita, and T. Sugawara
    • Journal Title

      J. Appl. Phys.

      Volume: 108 Pages: 94313-94313

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dual-gate field-effect transistors ofoctathio[8] circulene thin-films with ionic liquid and SiO_2 gate dielectrics2010

    • Author(s)
      T. Fujimoto, M. M. Matsushita, and K. Awaga
    • Journal Title

      Appl. Phys. Lett.

      Volume: 97

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Influence of Magnetic Field upon the Conductance of a Unicomponent Crystal of a Tetrathiafulvalene-Based Nitronyl Nitroxide2010

    • Author(s)
      H. Komatsu, M. M. Matsushita, S. Yamamura, Y. Sugawara, K. Suzuki and T. Sugawara
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 132 Pages: 4528-4529

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Superperiodic conductance in a molecularly wired double-dot system self-assembled in a nanogap electrode2010

    • Author(s)
      Y.Noguchi, T.Terui, Takuya Katayama, M.M.Matsushita, T.Sugawara
    • Journal Title

      Journal of Applied Physics

      Volume: 108 Pages: 94313-94313

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dual-gate field-effect transistors of octathio[8]circulene thin-films with ionic liquid and SiO_2 gate dielectrics2010

    • Author(s)
      T.Fujimoto, M.M.Matsushita, K.Awaga
    • Journal Title

      Applied Physics Letters

      Volume: 97

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influence of Magnetic Field upon the Conductance of a Unicomponent Crystal of a Tetrathiafulvalene-Based Nitronyl Nitroxide2010

    • Author(s)
      H.Komatsu, M. M.Matsushita, S.Yamamura, Y.Sugawara, K.Suzuki, T.Sugawara
    • Journal Title

      The Journal of the American Chemical Society 132

      Pages: 4528-4529

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical field-effect transistors ofoctathio[8] circulene robust thin films with ionic liquids2009

    • Author(s)
      T. Fujimoto, M. M. Matsushita, and K. Awaga
    • Journal Title

      Chem. Phys. Lett.

      Volume: 483 Pages: 81-83

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and properties of TSF-based spin-polarized donor2009

    • Author(s)
      H. Komatsu, M. M. Matsushita, T. Miyagi, Y. Kawada, and T. Sugawara
    • Journal Title

      Polyhedron.

      Volume: 28 Pages: 1996-2000

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical field-effect transistors of octathio[8]circulene robust thin films with ionic liquids2009

    • Author(s)
      T.Fujimoto, M.M.Matsushita, K.Awaga
    • Journal Title

      Chemical Physics Letters 483

      Pages: 81-83

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and properties of TSF-based spin-polarized donor2009

    • Author(s)
      H.Komatsu, R.Mogi, M.M.Matsushita, T.Miyagi, Y.Kawada, T.Sugawara
    • Journal Title

      Polyhedron 28

      Pages: 1996-2000

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 環状インドールトリマー誘導体結晶の構造と物性2011

    • Author(s)
      加藤篤史・小木曽達哉・松下未知雄・阿波賀邦夫
    • Organizer
      有機結晶部会シンポジウム
    • Place of Presentation
      富山大学
    • Year and Date
      2011-10-29
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Construction of Organic Spintronic Materials2011

    • Author(s)
      M. M. Matsushita and Tadashi Sugawara
    • Organizer
      5th International Workshop on Spin Currents
    • Place of Presentation
      仙台大学国際センター
    • Year and Date
      2011-07-27
    • Related Report
      2011 Final Research Report
  • [Presentation] Construction of Organic Spintronic Materials2011

    • Author(s)
      松下未知雄、菅原正
    • Organizer
      5th International Workshop on Spin Currents
    • Place of Presentation
      仙台国際センター
    • Year and Date
      2011-07-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] 環状インドールトリマー誘導体結晶の一次元積層構造と電荷輸送特性2010

    • Author(s)
      小木曽達哉・松下未知雄・阿波賀邦夫
    • Organizer
      第4回分子科学討論会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2010-09-14
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] 3回対称性を持つ環状インドールトリマーの合成と物性2010

    • Author(s)
      小木曽達哉・松下未知雄・阿波賀邦夫
    • Organizer
      第21回基礎有機化学討論会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2010-09-10
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Giant Negative Magneto resistance in Molecule-based Coexisting Systems of Magnetism and Conductivity2010

    • Author(s)
      M. M. Matsushita
    • Organizer
      The 2nd International Symposium on Advanced Magnetic Materials and Applications
    • Place of Presentation
      仙台大学国際センター
    • Year and Date
      2010-07-15
    • Related Report
      2011 Final Research Report
  • [Presentation] Giant Negative Magnetoresistance in Molecule-based Coexisting Systems of Magnetism and Conductivity2010

    • Author(s)
      M.M.Matsushita
    • Organizer
      The 2nd International Symposium on Advanced Magnetic Materials and Applications
    • Place of Presentation
      仙台大学国際センター
    • Year and Date
      2010-07-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] オリゴチオフェン型ワイヤー分子と金ナノ粒子からなる2重ドット単電子トランジスタにおけるクーロンダイヤモンドの超周期構造と粒子間相互作用2010

    • Author(s)
      野口裕、照井通文、片山卓也、松下未知雄、菅原正
    • Organizer
      日本化学会第90回春季年会
    • Place of Presentation
      近畿大学本部キャンパス
    • Year and Date
      2010-03-29
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 有機ラジカルのスピンに基づく磁性-導電性共存系の構築2009

    • Author(s)
      松下未知雄
    • Organizer
      分子科学討論会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2009-09-23
    • Related Report
      2011 Final Research Report
  • [Presentation] 有機ラジカルのスピンに基づく磁性-導電性共存系の構築2009

    • Author(s)
      松下未知雄
    • Organizer
      第三回分子科学討論会
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2009-09-23
    • Related Report
      2009 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi