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Spin Dynamics Study of Next Generation Solar Energy"Rare-Earth Dye-Sensitized Solar Cells"

Research Project

Project/Area Number 21685021
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Functional materials/Devices
Research InstitutionInstitute for Molecular Science

Principal Investigator

FURUKAWA Ko  分子科学研究所, 物質分子科学研究領域, 助教 (90342633)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Keywords光学材料 / 素子 / 色素増感太陽電池 / 時間分解ESR / 希土類 / スピンダイナミクス
Research Abstract

In the steady state ESR spectroscopy, the complex spin-state of the rare-earth dye molecules was revealed exactly. Then, it was clarify that these molecules are possible to indicate the high photoelectronic conversion efficiency, due to the long relaxation time in the rare-earth dye molecules. A little sample amount of these materials prevent us to examine the mechanism of dye sensitized solar cell. However, we were successful to clarify the organic photoconductive mechanism by using time-resolved ESR spectroscopy.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (50 results)

All 2012 2011 2010 2009

All Journal Article (19 results) (of which Peer Reviewed: 19 results) Presentation (31 results)

  • [Journal Article] Structural Investigation of the Spin-singlet Phase in (TMTTF)_2I2011

    • Author(s)
      K.Furukawa, K.Sugiura, F.Iwase, T.Nakamura
    • Journal Title

      Phys.Rev.B

      Volume: 83 Issue: 18 Pages: 184419-184419

    • DOI

      10.1103/physrevb.83.184419

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Very Stable Heterofullerene Encapsulating Two Gadolinium Ions with a Magnetic Spin State of S2011

    • Author(s)
      W. Fu, J. Zhang, T. Fuhrer, H. Champion, K. Furukawa, T. Kato, J. Mahaney, B. Burke, K. Williams, K. Walker, C. Dixon, J. Ge, C. Shu, K. Harich, and H. Dorn
    • Journal Title

      J. Am. Chem. Soc

      Volume: 133 Issue: 25 Pages: 9741-9750

    • DOI

      10.1021/ja202011u

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ferromagnetic Spin Coupling between Endohedral Metallofullerene La@C_<82> and a Cyclodimeric Copper Porphyrin upon Inclusion2011

    • Author(s)
      F.Hajjaj, K.Tashiro, H.Nikawa, N.Mizorogi, T.Akasaka, S.Nagase, K.Furukawa, T.Kato, T.Aida
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Issue: 24 Pages: 9290-9292

    • DOI

      10.1021/ja203491s

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photoinduced Triplet States of Photoconductive TTF Derivatives Including a Fluorescent Group2011

    • Author(s)
      K. Furukawa, Y. Sugishima, H. Fujiwara, T. Nakamura
    • Journal Title

      Chem. Lett

      Volume: 40 Issue: 3 Pages: 292-294

    • DOI

      10.1246/cl.2011.292

    • NAID

      130004426161

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Para-Phenylene-Bridged Spirobi(triarylamine) Dimer with Perpendicularly Linked Four Redox-Activeπ-Systems2011

    • Author(s)
      A. Ito, K. Hata, K. Kawamoto, Y. Hirao, K. Tanaka, M. Shiro, K. Furukawa, and T. Kato
    • Journal Title

      Chemistry. A European Journal

      Volume: 16 Issue: 35 Pages: 10866-10878

    • DOI

      10.1002/chem.201000848

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photoinduced Triplet States of Photoconductive TTF Derivatives Including a Fluorescent Group2011

    • Author(s)
      K.Furukawa
    • Journal Title

      Chem.Lett.

      Volume: 40 Pages: 292-294

    • NAID

      10027815758

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Para-Phenylene-Bridged Spirobi(triarylamine) Dimer with Perpendicularly Linked Four Redox-Active π-Systems2011

    • Author(s)
      A.Ito
    • Journal Title

      Chemistry-A European Journal

      Volume: 16 Pages: 10866-10878

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Stable Non-Kekul Singlet Biradicaloid from meso-Free 5,10,20,25-Tetrakis(Pentafluorophenyl)-Substituted [26]Hexaphyrin(1.1.1.1.1.1)2010

    • Author(s)
      Koide, T.; Furukawa, K.; Shinokubo, H.; Shin, J.-Y.; Kim, K. S.; Kim, D.; Osuka, A
    • Journal Title

      J. Am. Chem. Soc

      Volume: 132 Issue: 21 Pages: 7246-7247

    • DOI

      10.1021/ja101040s

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Novel Type of Career Generated System : Magnetic Investigations for TTF-Based Self-Doped Hydrogen-Bonding Conductor2010

    • Author(s)
      K. Furukawa, T. Nakamura, Y. Kobayashi, and T. Ogura
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 79 Issue: 5 Pages: 053701-053701

    • DOI

      10.1143/jpsj.79.053701

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Spin-Dynamics in Vicinity of Spin-Gap Phase Transition for Organic Conductor(TMTTF)_2X2010

    • Author(s)
      K. Furukawa, T. Hara, and T. Nakamura
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 79 Issue: 4 Pages: 043702-043702

    • DOI

      10.1143/jpsj.79.043702

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Stable non-Kekule Singlet Biradicaloid from meso-Free 5, 10, 20, 25-Tetrakis(Pentafluorophenyl) Substituted [26]Hexaphyrin(1.1.1.1.1.1)2010

    • Author(s)
      T.Koide
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 7246-7247

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Novel Type of Career Generated System : Magnetic Investigations for TTF-Based Self-Doped Hydrogen-Bonding Conductor2010

    • Author(s)
      K.Furukawa
    • Journal Title

      J.Phys.Soc.Jpn.

      Volume: 79

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spin-Dynamics in Vicinity of Spin-Gap Phase Transition for Organic Conductor(TMTTF)_2X2010

    • Author(s)
      K.Furukawa
    • Journal Title

      J.Phys.Soc.Jpn. 79

      Pages: 43702-43702

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anomalous Temperature Dependence of <B><I>g</I></B>-Tensor in Organic Conductor, (TMTTF)<SUB>2</SUB>X (X=Br, PF<SUB>6</SUB>, and SbF<SUB>6</SUB>)2009

    • Author(s)
      K. Furukawa, T. Hara, and T. Nakamura
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 78 Issue: 10 Pages: 104713-104713

    • DOI

      10.1143/jpsj.78.104713

    • NAID

      130005437122

    • ISSN
      0031-9015, 1347-4073
    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] T-shaped Three-Coordinate Copper(II) Heptaphyrin Complexes2009

    • Author(s)
      Saito, S.; Furukawa, K.; Osuka, A
    • Journal Title

      Angew. Chem. Int. Ed

      Volume: 48 Issue: 43 Pages: 8086-8089

    • DOI

      10.1002/anie.200902901

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electronic Properties of a TMTTF-Family Salt, (TMTTF)<SUB>2</SUB>TaF<SUB>6</SUB>: New Member Located on the <I>Modified</I> Generalized Phase-Diagram2009

    • Author(s)
      F. Iwase, K. Sugiura, K. Furukawa and T. Nakamura
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 78 Issue: 10 Pages: 104717-104717

    • DOI

      10.1143/jpsj.78.104717

    • NAID

      130005437222

    • ISSN
      0031-9015, 1347-4073
    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Anomalous Temperature Dependence of g-tensor in Organic Conductor, (TMTTF)_2X(X=Br, PF_6 and SbF_6)2009

    • Author(s)
      K.Furukawa
    • Journal Title

      J.Phys.Soc.Jpn. 78

      Pages: 104713-104713

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fully pai-Conjugated Helices From Oxidative Cleavage of meso-Aryl Substituted Expanded Porphyrins2009

    • Author(s)
      S.Saito
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 2128-2129

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electronic Properties of a TMTTF-Family Salt, (TMTTF)2TaF6 : New Member Located on the Modified Generalized Phase-Diagram2009

    • Author(s)
      F.Iwase
    • Journal Title

      J.Phys.Soc.Jpn. 78

      Pages: 104717-104717

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 時間分解ESRによる光誘起伝導性TTF誘導体の電荷分離状態の研究2012

    • Author(s)
      古川貢,辻本啓次郎,藤原秀紀,高橋誠弥,中村敏和
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学(神奈川県)
    • Year and Date
      2012-03-28
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] アントラセン骨格を含む環状芳香族アミンの合成と電子物性2012

    • Author(s)
      増田泰之,酒巻大輔,伊藤彰浩,田中一義,古川貢,加藤立久
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学(神奈川県)
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 4重ロタキサン型ポルフィリンーフタロシアニン超分子アレイ2012

    • Author(s)
      山田泰之,古川貢,加藤立久,田中健太郎
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学(神奈川県)
    • Year and Date
      2012-03-25
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 光誘起伝導性TTF誘導体の時間分解ESR研究2011

    • Author(s)
      古川貢,辻本啓次郎,藤原秀紀,中村敏和
    • Organizer
      第50回電子スピンサイエンス学会年会
    • Place of Presentation
      仙台国際センター(宮城県)
    • Year and Date
      2011-11-17
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] パルスQ-bandシステムを利用した生体系物質のPELDORによる距離測定の試み2011

    • Author(s)
      古川貢,平岡和佳子,稲波修,中村敏和
    • Organizer
      第50回電子スピンサイエンス学会年会
    • Place of Presentation
      仙台国際センター(宮城県)
    • Year and Date
      2011-11-16
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Spin Dynamics Study of Functional Materials2011

    • Author(s)
      K. Furukawa
    • Organizer
      MDF Workshop Open-shell Organic Molecules-Synthesis and Electronic Structure Freedom
    • Place of Presentation
      Umeda Sky Building(Osaka)
    • Year and Date
      2011-10-08
    • Related Report
      2011 Final Research Report
  • [Presentation] Spin Dynamics Study of Functional Materials2011

    • Author(s)
      K.Furukawa
    • Organizer
      MDF Workshop Open-shell Organic Molecules-Synthesis and Electronic Structure Freedom
    • Place of Presentation
      Umeda Sky Building (Osaka)
    • Year and Date
      2011-10-08
    • Related Report
      2011 Annual Research Report
  • [Presentation] 磁性及び構造的観点からの(TMTTF)_2SCNの電子状態研究2011

    • Author(s)
      杉浦晃一,古川貢,中村敏和
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学(富山県)
    • Year and Date
      2011-09-23
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 光誘起機能性物質の時間分解ESRによるスピンダイナミクス研究2011

    • Author(s)
      古川貢,辻本啓次郎,藤原秀紀,中村敏和
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター(北海道)
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 蛍光性部位を有するTTF複合分子の光機能性2011

    • Author(s)
      藤原秀紀,林定快,笹部圭祐,辻本啓次郎,中澄博行,古川貢,中村敏和,内田隆介,松崎弘幸,岡本博
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター(北海道)
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 光伝導性TTF誘導体の光誘起スピンダイナミクス2011

    • Author(s)
      古川貢,辻本啓次郎,杉島泰雄,藤原秀紀,中村敏和
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(神奈川県)
    • Year and Date
      2011-03-28
    • Related Report
      2011 Final Research Report
  • [Presentation] (TMTTF)_2SCNの電子状態と磁気相関の解明~リエントラント反強磁性の構造学的理解~2011

    • Author(s)
      杉浦晃一,古川貢,中村敏和
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟大学(新潟県)
    • Year and Date
      2011-03-26
    • Related Report
      2011 Final Research Report
  • [Presentation] (TMTTF)2SCNの電子状態と磁気相関の解明~リエントラント反強磁性の構造学的理解~2011

    • Author(s)
      杉浦晃一
    • Organizer
      日本物理学会 第66回年次大会
    • Place of Presentation
      新潟大学(新潟県)
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] 非対称アニオンを持つ有機導体(TMTTF) 2SCNの電子構造と結晶構造2010

    • Author(s)
      杉浦晃一,古川貢,中村敏和
    • Organizer
      第49回電子スピンサイエンス学会年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Year and Date
      2010-11-12
    • Related Report
      2011 Final Research Report
  • [Presentation] 非対称アニオンを持つ有機導体(TMTTF)2SCNの電子構造と結晶構造2010

    • Author(s)
      杉浦晃一
    • Organizer
      第49回電子スピンサイエンス学会年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Year and Date
      2010-11-12
    • Related Report
      2010 Annual Research Report
  • [Presentation] 光誘起伝導性TTF誘導体のスピンダイナミクス研究2010

    • Author(s)
      古川貢,辻本啓次郎,杉島泰雄,藤原秀紀,中村敏和
    • Organizer
      第49回電子スピンサイエンス学会年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Year and Date
      2010-11-11
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Time-Resolved ESR Study of Spin Dynamics for Photo-induced Functional Materials2010

    • Author(s)
      K. Furukawa, Y. Sugishima, K. Tsujimoto, H. Fujiwara, T. Nakamura
    • Organizer
      TTF-Derivatives, Asia-Pacific EPR/ESR Symposium
    • Place of Presentation
      Jeju(Korea)
    • Year and Date
      2010-10-11
    • Related Report
      2011 Final Research Report
  • [Presentation] Time-Resolved ESR Study of Spin Dynamics for Photo-induced Functional Materials, TTF-Derivatives2010

    • Author(s)
      K.Furukawa
    • Organizer
      Asia-Pacific EPR/ESR Symposium
    • Place of Presentation
      Jeju (Korea)
    • Year and Date
      2010-10-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] TMTCF系の修正一般化相図の構造的理解2010

    • Author(s)
      古川貢,杉浦晃一,中村敏和
    • Organizer
      日本物理学会2010年秋季大会
    • Place of Presentation
      大阪府立大学(大阪府)
    • Year and Date
      2010-09-24
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] 光誘起伝導物質におけるスピンダイナミクスと蛍光部位との相関2010

    • Author(s)
      古川貢,辻本啓次郎,杉島泰雄,藤原秀紀,中村敏和
    • Organizer
      第4回分子科学討論会
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      2010-09-16
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] TMTTF)_2X系の示す競合電子相の構造的理解2010

    • Author(s)
      古川貢,杉浦晃一,岩瀬文達,中村敏和
    • Organizer
      第4回分子科学討論会
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      2010-09-15
    • Related Report
      2011 Final Research Report
  • [Presentation] (TMTTF)_2X系の示す競合電子相の構造的理解2010

    • Author(s)
      古川貢
    • Organizer
      第4回分子科学討論会
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] Time-Resolved ESR Study for Photo-induced Functional Materials2010

    • Author(s)
      K. Furukawa, K. Tsujimoto, Y. Sugishima, H. Fujiwara, and T. Nakamura
    • Organizer
      TTF-Derivatives, ISSP-MDF Joint International meeting,"Spin-related phenomena in organic materials"
    • Place of Presentation
      東京大学物性研究所(東京都)
    • Year and Date
      2010-07-01
    • Related Report
      2011 Final Research Report
  • [Presentation] Time-Resolved ESR Study for Photo-induced Functional Materials, TTF-Derivatives2010

    • Author(s)
      K.Furukawa
    • Organizer
      ISSP-MDF Joint International meeting, "Spin-related phenomena in organic materials"
    • Place of Presentation
      東京大学物性研究所(東京都)
    • Year and Date
      2010-07-01
    • Related Report
      2010 Annual Research Report
  • [Presentation] 一次元有機導体(TMTTF) 2Xの構造と電子相との相関2010

    • Author(s)
      古川貢,杉浦晃一,岩瀬文達,中村敏和
    • Organizer
      CMRC研究会「分子結晶における構造物性研究」
    • Place of Presentation
      高エネルギー加速器研究所(茨城県)
    • Year and Date
      2010-04-23
    • Related Report
      2011 Final Research Report
  • [Presentation] 一次元有機導体(TMTTF)_2Xの構造と電子相との相関2010

    • Author(s)
      古川貢
    • Organizer
      CMRC研究会「分子結晶における構造物性研究」
    • Place of Presentation
      高エネルギー加速器研究所(茨城県)
    • Year and Date
      2010-04-23
    • Related Report
      2010 Annual Research Report
  • [Presentation] 光誘起機能性物質TTF誘導体のスピンダイナミクス2010

    • Author(s)
      古川貢,杉島泰雄,藤原秀紀,中村敏和
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪府)
    • Year and Date
      2010-03-28
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 光伝導性TTF誘導体の光誘起スピンダイナミクス2010

    • Author(s)
      古川貢
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(神奈川県)
    • Year and Date
      2010-03-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] Spin Dynamics of Photo-Induced Functional Materials2009

    • Author(s)
      K. Furukawa
    • Organizer
      The 3rd Japanese-Russian Workshop on Open Shell Compounds and Molecular Spin Devices
    • Place of Presentation
      淡路夢舞台(兵庫県)
    • Year and Date
      2009-11-15
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 光誘起伝導性物質TTF誘導体のスピンダイナミクス研究2009

    • Author(s)
      古川貢,杉島泰雄,藤原秀紀,中村敏和
    • Organizer
      第48回電子スピンサイエンス学会年会
    • Place of Presentation
      神戸大学(兵庫県)
    • Year and Date
      2009-11-12
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 光誘起機能性物質の時間分解ESRによるスピンダイナミクス研究2009

    • Author(s)
      古川貢,杉島泰雄,藤原秀紀,中村敏和
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名古屋大学(愛知県)
    • Year and Date
      2009-09-22
    • Related Report
      2011 Final Research Report 2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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