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Identification of the origin of nanoscale image contrast in contact potential difference maps given by a Kelvin probe force microscope

Research Project

Project/Area Number 21686004
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionJapan Advanced Institute of Science and Technology

Principal Investigator

SASAHARA Akira  北陸先端科学技術大学院大学, マテリアルサイエンス研究科, 助教 (40321905)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥26,780,000 (Direct Cost: ¥20,600,000、Indirect Cost: ¥6,180,000)
Fiscal Year 2011: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2010: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2009: ¥19,110,000 (Direct Cost: ¥14,700,000、Indirect Cost: ¥4,410,000)
Keywords走査プローブ顕微鏡 / ケルビン力顕微鏡 / 表面電位 / 接触電位差 / 非接触型原子間力顕微鏡 / 仕事関数 / 二酸化チタン / 単分子膜 / ケルビンカ顕微鏡
Research Abstract

Mixed monolayers of acetate and trifluoroacetate anions were examined by a Kelvin probe force microscope(KPFM). Obtained contact potential difference(CPD) maps showed the CPD change on the molecules. Such nanometer scale contrast in the CPD map was independent of the perturbation of cantilever oscillation frequency, cantilever oscillation amplitude, and tunneling current flowing between the tip and sample. The results proved that the nanometer scale CPD contrast by the KPFM shows true surface potential. It was found that the control of the cantilever oscillation amplitude and the investigation of tip-induced charges on the sample surface are necessary for further precise CPD analysis.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (26 results)

All 2012 2011 2010 2009

All Journal Article (6 results) (of which Peer Reviewed: 5 results) Presentation (18 results) Book (2 results)

  • [Journal Article] Atomic scale analysis of ultra thin SiO_2films prepared on TiO_2(100) surfaces2010

    • Author(s)
      A. Sasahara, C. L. Pang, and M. Tomitori
    • Journal Title

      J. Phys. Chem. C

      Volume: 114 Pages: 20189-20194

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Surface Science Approach to Photochemistry of TiO_22010

    • Author(s)
      A. Sasahara and H. Onishi
    • Journal Title

      Solid State Phenom

      Volume: 162 Pages: 115-133

    • NAID

      120003353434

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Frequency Modulation Atomic Force Microscope Observation of TiO_2(110) Surfaces in Water2010

    • Author(s)
      A. Sasahara and M. Tomitori
    • Journal Title

      J. Vac. Sci. and Technol. B

      Volume: 28,(3)

    • NAID

      120002260318

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 身近になりつつある酸化物表面の原子スケール観察2010

    • Author(s)
      笹原亮、富取正彦
    • Journal Title

      未来材料

      Volume: 11 Pages: 2-5

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Journal Article] Atomic scale analysis of ultra thin SiO_2 films prepared on TiO_2(100) surfaces2010

    • Author(s)
      A.Sasahara, C.L.Pang, M.Tomitori
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 114 Pages: 20189-20194

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metal-to-Oxide Charge Transfer Observed by a Kelvin Probe Force Microscope2009

    • Author(s)
      A. Sasahara, K. Hiehata, and H. Onishi
    • Journal Title

      Catal. Surv. Asia

      Volume: 13,(1) Pages: 9-15

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Presentation] 周波数変調型原子間力顕微鏡を用いた色素吸着TiO_2(110)表面の光応答の純水中解析2012

    • Author(s)
      芳哲也
    • Organizer
      2012年春季第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京)
    • Year and Date
      2012-03-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] TiO_2(110)表面上のリチウム-炭酸プロピレン共吸着の走査型トンネル顕微鏡による研究2012

    • Author(s)
      辰巳仁美
    • Organizer
      2012年春季第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京)
    • Year and Date
      2012-03-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] Initial adsorption of lithium and propylene carbonate on a metal oxide surface for lithium ion battery observed by scanning tunneling microscopy2011

    • Author(s)
      辰巳仁美
    • Organizer
      19th International Colloquium on Scanning Probe Microscopy (ICSPM19)
    • Place of Presentation
      洞爺湖万世閣(北海道)
    • Year and Date
      2011-12-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] FM-AFM analysis of optical response of dye-adsorbed TiO_2(110)surfaces2011

    • Author(s)
      芳哲也
    • Organizer
      19th International Colloquium on Scanning Probe Microscopy (ICSPM19)
    • Place of Presentation
      洞爺湖万世閣(北海道)
    • Year and Date
      2011-12-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金属酸化物表面上のリチウムイオン-炭酸プロピレン共吸着層の走査型トンネル顕微鏡による研究2011

    • Author(s)
      辰巳仁美
    • Organizer
      平成23年度応用物理学会北陸・信越支部学術講演会
    • Place of Presentation
      金沢歌劇座(石川)
    • Year and Date
      2011-11-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] 周波数変調型原子間力顕微鏡による色素吸着TiO_2(110)表面の純水中光応答の解析2011

    • Author(s)
      芳哲也
    • Organizer
      平成23年度応用物理学会北陸・信越支部学術講演会
    • Place of Presentation
      金沢歌劇座(石川)
    • Year and Date
      2011-11-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] 周波数変調原子間力顕微鏡による酸化物表面の液中ナノ解析2011

    • Author(s)
      芳哲也、笹原亮、富取正彦
    • Organizer
      誘電・絶縁材料研究会
    • Place of Presentation
      新潟県新潟市
    • Year and Date
      2011-07-08
    • Related Report
      2011 Final Research Report
  • [Presentation] 二酸化チタン単結晶表面に作製したチタン-ケイ素複合酸化物の研究2010

    • Author(s)
      笹原亮、Chi Lun Pang、富取正彦
    • Organizer
      第30回表面科学学術講演会
    • Place of Presentation
      大阪府吹田市
    • Year and Date
      2010-11-06
    • Related Report
      2011 Final Research Report
  • [Presentation] 二酸化チタン単結晶表面に作製したチタン-ケイ素複合酸化物の研究2010

    • Author(s)
      笹原亮, Chi Lun Pang, 富取正彦
    • Organizer
      第30回表面科学学術講演会
    • Place of Presentation
      大阪大学(大阪)
    • Year and Date
      2010-11-06
    • Related Report
      2010 Annual Research Report
  • [Presentation] Nanoscale analysis of dye-modified titanium dioxide surfaces by scanning probe microscopy2010

    • Author(s)
      A. Sasahara
    • Organizer
      Asia-Pacific Interfinish 2010
    • Place of Presentation
      Biopolice, Singapore
    • Year and Date
      2010-10-21
    • Related Report
      2011 Final Research Report
  • [Presentation] Nanoscale analysis of dye-modified titanium dioxide surfaces by scanning probe microscopy2010

    • Author(s)
      A.Sasahara
    • Organizer
      Asia-Pacific Interfinish 2010
    • Place of Presentation
      The BIOPOLIS (Singapore)(招待講演)
    • Year and Date
      2010-10-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] FM-AFM observation of TiO_2(100) surfaces in water2010

    • Author(s)
      C. L. Pang, A. Sasahara, and M. Tomitori
    • Organizer
      13th International Conference on Noncontact Atomic Force Microscopy
    • Place of Presentation
      Kanazawa, Ishikawa
    • Year and Date
      2010-08-02
    • Related Report
      2011 Final Research Report
  • [Presentation] Scanning Probe Microscope Studies of Dye-Adsorbed Titanium Dioxide Surfaces2010

    • Author(s)
      A. Sasahara, Naoki Koide, Liyuan Han, Hiroshi Onish, and Masahiko Tomitori
    • Organizer
      NIMS Conference
    • Place of Presentation
      Tsukuba, Ibaraki
    • Year and Date
      2010-07-13
    • Related Report
      2011 Final Research Report
  • [Presentation] Scanning Probe Microscope Studies of Dye-Adsorbed Titanium Dioxide Surfaces2010

    • Author(s)
      A.Sasahara, Naoki Koide, Liyuan Han, Hiroshi Onish, Masahiko Tomitori
    • Organizer
      NIMS Conference
    • Place of Presentation
      つくば国際会議場(茨城)(招待講演)
    • Year and Date
      2010-07-13
    • Related Report
      2010 Annual Research Report
  • [Presentation] Analysis of a Rutile TiO_2(110) Surface in Water by Noncontact Atomic Force Microscope2010

    • Author(s)
      A. Sasahara and M. Tomitori
    • Organizer
      7th International Workshop on Metal Oxides(IWOX-IV)
    • Place of Presentation
      Echigo-Yuzawa, Niigata
    • Year and Date
      2010-01-13
    • Related Report
      2011 Final Research Report
  • [Presentation] 担持金属触媒モデル表面のナノスケール電荷分布解析2009

    • Author(s)
      笹原亮
    • Organizer
      第29回表面科学学術講演会
    • Place of Presentation
      東京都江戸川区
    • Year and Date
      2009-10-29
    • Related Report
      2011 Final Research Report
  • [Presentation] Noncontact Atomic Force Microscope Observation of TiO2(110) Surface in Pure Water2009

    • Author(s)
      A. Sasahara, Y. Jeong, and M. Tomitori
    • Organizer
      12th International Conference on Noncontact Atomic Force Microscopy
    • Place of Presentation
      New Haven, US
    • Year and Date
      2009-08-10
    • Related Report
      2011 Final Research Report
  • [Presentation] 非接触型原子間力顕微鏡を用いた二酸化チタン表面の水中観察2009

    • Author(s)
      笹原亮、富取正彦
    • Organizer
      2009年春季第56回応用物理学会学術講演会
    • Place of Presentation
      茨城県つくば市
    • Year and Date
      2009-03-31
    • Related Report
      2011 Final Research Report
  • [Book] Measuring and Compensating Electrostatic Forces2011

    • Author(s)
      A. Sasahara and H. Onishi
    • Total Pages
      220
    • Publisher
      Springer, Berlin
    • Related Report
      2011 Final Research Report
  • [Book] Kelvin Probe Force Microscopy : Measuring and Compensating Electrostatic Forces2011

    • Author(s)
      笹原亮
    • Publisher
      Springer
    • Related Report
      2011 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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