Ruggedization and performance-degradation analysis of inverted organic solar cells by the control of inorganic-organic hetero interface
| Project/Area Number |
21686011
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Applied physics, general
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| Research Institution | Kanazawa University |
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Principal Investigator |
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥23,660,000 (Direct Cost: ¥18,200,000、Indirect Cost: ¥5,460,000)
Fiscal Year 2011: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2010: ¥8,840,000 (Direct Cost: ¥6,800,000、Indirect Cost: ¥2,040,000)
Fiscal Year 2009: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
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| Keywords | 太陽電池 / 長寿命化 / エネルギー効率 / 有機薄膜太陽電池 / 劣化機構 / 耐久性向上 / 交流インピーダンス / 耐久性 |
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| Research Abstract |
In this research, we aim to analysis the degradation mechanism for inverted polymer solar cells and to fabricate the high durable polymer solar cell in air.
The relationship between the morphology of a P3HT : PCBM photoactive layer and performance of its bulk-heterojunction polymer solar cells was investigated. AC impedance spectroscopy, carrier mobility measurements and AFM observation of the photoactive layer surface revealed that the degradation of the polymer solar cell was caused by the initial well-connected network within the P3HT : PCBM layer changing to a morphology. Following this result, we achieved to fabricate the high durable polymer solar cell which almost maintains the maximum PCE under continuous light irradiation for 100 h in air. In addition, the performance of the sealed cells was almost constant in open field test for 1 year under continuous light irradiation.
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Report
(4 results)
Research Products
(51 results)
