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Development of formaldehyde-free technics for anti-yellowing finishing of nylon fibers

Research Project

Project/Area Number 21700736
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field General human life sciences
Research InstitutionOsaka Municipal Technical Research Institute

Principal Investigator

OHE Takeru  地方独立行政法人大阪市立工業研究所, 研究員 (10416315)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordsナイロン繊維 / 糖 / 黄変防止 / ホルムアルデヒド / シックハウス症候群 / メイラード反応 / マイクロ波加熱 / メラノイジン反応
Research Abstract

It is well known that nylon fibers turn yellow during long storage in wooden boxes or corrugated cartons, where the nylon fibers react with various aromatic aldehydes gradually generated from wood or crude paper. In general, in the textile fields, formaldehyde is a useful reagent to prevent nylon products from turning yellow, but it is also one of the main materials causing the sick building syndrome. In this work, we investigated reaction conditions between nylon fibers and various reducing sugars to prevent nylon fibers from turning yellow due to aromatic aldehydes. As a result, the reaction with reducing sugar in organic solvent or water solution containing sodium hydrosulfite prevented the nylon fibers most effectively from being changed not only to yellow by the reaction with vanillin, one of aromatic aldehydes, but also to brown by the melanoidin reaction as a side reaction.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (21 results)

All 2011 2010 2009 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (14 results) Remarks (4 results)

  • [Journal Article] Anti-yellowing of Nylon Fiber Using a Reaction with Reducing Sugar2010

    • Author(s)
      大江猛、吉村由利香
    • Journal Title

      繊維学会誌 Vol.66、No.8

      Pages: 187-193

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Anti-yellowing of Nylon Fiber Using a Reaction with Reducing Sugar2010

    • Author(s)
      Takeru Ohe, Yurika Yoshimura
    • Journal Title

      繊維学会誌

      Volume: 66 Pages: 187-193

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anti-yellowing of Nylon Fiber Using a Reaction with Reducing Sugar (2) -Reaction in Aqueous Solution Containing a Reducing Reagent-

    • Author(s)
      大江猛、吉村由利香
    • Journal Title

      繊維学会誌 印刷中

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Presentation] PET繊維とエチレンジアミンとの水系反応における界面活性剤添加の効果2011

    • Author(s)
      大江猛、吉村由利香
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      東京
    • Year and Date
      2011-03-27
    • Related Report
      2010 Final Research Report
  • [Presentation] PET繊維とエチレンジアミンとの水系反応における界面活性剤添加の効果2011

    • Author(s)
      大江猛、吉村由利香
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(横浜市)
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] 糖類を用いたナイロン繊維の黄変防止技術2010

    • Author(s)
      大江猛、吉村由利香
    • Organizer
      日本不織布協会第2回産官学の集い
    • Place of Presentation
      大阪
    • Year and Date
      2010-07-09
    • Related Report
      2010 Final Research Report
  • [Presentation] 糖類を用いたナイロン繊維の黄変防止技術2010

    • Author(s)
      大江猛、吉村由利香
    • Organizer
      日本不織布協会第2回産官学の集い
    • Place of Presentation
      太閤園(大阪市)
    • Year and Date
      2010-07-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] 還元糖とナイロン繊維の水系反応と繊維の黄変防止効果2010

    • Author(s)
      大江猛、吉村由利香
    • Organizer
      平成22年度繊維学会年次大会
    • Place of Presentation
      東京
    • Year and Date
      2010-06-16
    • Related Report
      2010 Final Research Report
  • [Presentation] 還元糖とナイロン繊維の水系反応と繊維の黄変防止効果2010

    • Author(s)
      大江猛、吉村由利香
    • Organizer
      平成22年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2010-06-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] 水系での還元糖とナイロン繊維との反応および黄変防止の効果2010

    • Author(s)
      大江猛、吉村由利香
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-28
    • Related Report
      2010 Final Research Report
  • [Presentation] 水系での還元糖とナイロン繊維との反応および黄変防止の効果2010

    • Author(s)
      大江猛、吉村由利香
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(東大阪市)
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 糖類を利用した合成繊維の機能加工に関する研究2010

    • Author(s)
      大江猛
    • Organizer
      大阪工研協会第34回分析機器展
    • Place of Presentation
      大阪
    • Related Report
      2010 Final Research Report
  • [Presentation] 糖類を利用した合成繊維の機能加工に関する研究2010

    • Author(s)
      大江猛
    • Organizer
      大阪工研協会第34回分析機器展
    • Place of Presentation
      大阪市立工業研究所(大阪市)
    • Related Report
      2009 Annual Research Report
  • [Presentation] 糖類を利用したナイロン繊維の黄変防止技術2009

    • Author(s)
      大江猛
    • Organizer
      平成21年度大阪市立工業研究所技術シーズ発表会
    • Place of Presentation
      大阪
    • Year and Date
      2009-11-12
    • Related Report
      2010 Final Research Report
  • [Presentation] 糖類を利用したナイロン繊維の黄変防止技術2009

    • Author(s)
      大江猛
    • Organizer
      大阪市立工業研究所技術シーズ発表会
    • Place of Presentation
      大阪産業創造館(大阪市)
    • Year and Date
      2009-11-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] 還元糖を利用したナイロン繊維の黄変防止技術2009

    • Author(s)
      大江猛、吉村由利香
    • Organizer
      平成21年度繊維学会年次大会
    • Place of Presentation
      東京
    • Year and Date
      2009-06-11
    • Related Report
      2010 Final Research Report
  • [Presentation] 還元糖を利用したナイロン繊維の黄変防止技術2009

    • Author(s)
      大江猛、吉村由利香
    • Organizer
      平成21年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2009-06-11
    • Related Report
      2009 Annual Research Report
  • [Remarks] 吉村由利香、大江猛、マイクロ波を用いた繊維加工(特集:繊維加工)、繊維学会誌、Vol.66、No.10、2010、pp.P339-343

    • Related Report
      2010 Final Research Report
  • [Remarks] 所属の広報誌

    • Related Report
      2010 Final Research Report
  • [Remarks] 安全性の高い糖を使ったナイロン繊維の黄変防止加工、平成22年度工研テクノレポート、印刷中

    • Related Report
      2010 Final Research Report
  • [Remarks] 安全性の高い糖を使ったナイロン繊維の黄変防止加工、平成21年度工研テクノレポート

    • Related Report
      2010 Final Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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