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High-time resolution measurements of atmospheric methane by use of cavity enhanced absorption spectroscopy

Research Project

Project/Area Number 21710009
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Environmental dynamic analysis
Research InstitutionKyoto University

Principal Investigator

TAKAHASHI Kenshi  Kyoto University, 生存圏研究所, 准助教 (10303596)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2009: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsキャビティ増幅吸収分光法 / 超高感度分析 / 迅速分析 / レーザー / メタン / 半導体レーザー / 積分型吸収分光法
Research Abstract

A laser-based instrument using a technique of cavity enhanced absorption spectroscopy (CEAS) was developed to measure atmospheric methane accurately and precisely. The limit-of-detection of the developed instrument achieved 1 ppb for 1 second signal averaging, which is enough high to detect atmospheric methane on a real-time basis. The instrument was utilized in a Japanese cypress forest in Shiga prefecture, Japan, to investigate the spatio-temporal behavior of methane above and within the forest canopy. An automated chamber measurement system was coupled to the laser-based instrument developed in this study, thereby methane exchange fluxes between the foliage, trunk, and forest soils and the atmosphere were calculated. The chamber fluxes were obtained with 15-min time resolution.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (22 results)

All 2011 2010 2009 Other

All Journal Article (14 results) (of which Peer Reviewed: 14 results) Presentation (6 results) Remarks (2 results)

  • [Journal Article] Characterization of aerosol particles in the Tokyo metropolitan area using two different particle mass spectrometers2011

    • Author(s)
      J.-H.Xing, K.Takahashi, A.Yabushita, T.Kinugawa, T.Nakayama, Y.Matsumi, K.Tonokura, A.Takami, T.Imamura, K.Sato, M.Kawasaki, T.Hikida, A.Shimono
    • Journal Title

      Aerosol Sci.Tech. 45

      Pages: 315-326

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of aerosol particles in the Tokyo metropolitan area using two different particle mass spectrometers2011

    • Author(s)
      Xing, et al., (他12名、2番目)
    • Journal Title

      Aerosol Science and Technology

      Volume: 45 Pages: 315-326

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics and mechanism of chlorine-atom-initiated oxidation of allyl alcohol, 3-buten-2-ol, and 2-methyl-3-buten-2-ol2010

    • Author(s)
      K.Takahashi, J.-H.Xing, M.D.Hurley, T.J.wallington
    • Journal Title

      J.Phys.Chem.A 114

      Pages: 4224-4231

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fluorescence detection of atmospheric nitrogen dioxide using a blue light-emitting diode as an excitation source2010

    • Author(s)
      Y.Matsumi, F.Taketani, K.Takahashi, T.Nakayama, M.Kawai, Y.Miyao
    • Journal Title

      Appl.Opt. 49

      Pages: 3762-3767

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] OH-initiated oxidation of small unsaturated alcohols2010

    • Author(s)
      K.Takahashi, M.D.Hurley, T.J.Wallington
    • Journal Title

      Int.J.Chem.Kinet. 42

      Pages: 151-158

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] OH-initiated oxidation of small unsaturated alcohols2010

    • Author(s)
      Takahashi, et al., (他2名、1番目)
    • Journal Title

      International Journal of Chemical Kinetics

      Volume: 42 Pages: 151-158

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fluorescence detection of atmospheric nitrogen dioxide using a blue light-emitting diode as an excitation source2010

    • Author(s)
      Matsumi, et al., (他5名、3番目)
    • Journal Title

      Applied Optics

      Volume: 49 Pages: 3762-3767

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics and mechanism of chlorine-atom-initiated oxidation of allyl alcohol, 3-buten-2-ol, and 2-methyl-3-buten-2-ol2010

    • Author(s)
      Takahashi, et al., (他3名、1番目)
    • Journal Title

      The Journal of Physical Chemistry

      Volume: A114 Pages: 4224-4231

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Internal mixing of pollutants for submicron particles observed during springtime in Japan2009

    • Author(s)
      J.Matsumoto, M.Narukawa, K.Takahashi, Y.Matsumi, A.Yabushita, A.Shimizu, I.Matsui, N.Sugimoto
    • Journal Title

      Asian Journal of Atmospheric Environment 3-1

      Pages: 27-41

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics of the reactions of chlorine atoms with a series of acetates at 296K2009

    • Author(s)
      J.-H.Xing, K.Takahashi, M.D.Hurley, T.J.Wallington
    • Journal Title

      Chem.Phys.Lett. 474

      Pages: 268-272

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics of the reaction of chlorine atoms with isoprene (2-methyl 1,3-butadiene, CH_2=C(CH_3)CH=CH_2) at 297±2K2009

    • Author(s)
      J.-H.Xing, K.Takahashi, M.D.Hurley, T.J.Wallington
    • Journal Title

      Chem.Phys.Lett. 472

      Pages: 39-43

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics of the reactions of chlorine atoms with a series of acetates at 296K2009

    • Author(s)
      Xing, et al., (他3名、2番目)
    • Journal Title

      Chemical Physics Letters 474

      Pages: 268-272

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Internal mixing of pollutants for submicron particles observed during springtime in Japan2009

    • Author(s)
      Matsumoto, et al., (他7名、3番目)
    • Journal Title

      Asian Journal of Atmospheric Environment 3-1

      Pages: 27-41

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics and mechanism of the reaction of chlorine atoms with isoprene (2-methyl 1,3-butadiene, CH_2=C(CH_3)CH=CH_2) at 297 ± 2 K2009

    • Author(s)
      Xing, et aL, (他3名、2番目)
    • Journal Title

      Chemical Physics Letters 472

      Pages: 39-43

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] ヒノキ林における葉群、幹、土壌からのメタンフラックスおよび濃度プロファイルの観測2011

    • Author(s)
      金澤瑛, (他3名、3番目)
    • Organizer
      日本農業気象学会2011年大会
    • Place of Presentation
      鹿児島大学
    • Year and Date
      2011-03-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] 近赤外レーザーによる暖温帯ヒノキ林におけるメタンフラックスの長期観測2010

    • Author(s)
      高橋けんし(他4名、1番目)
    • Organizer
      第16回大気化学討論会
    • Place of Presentation
      首都大学東京八王子キャンパス
    • Year and Date
      2010-11-18
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Methane flux measurements by diode laser spectroscopy in a Japanese cypress forest2010

    • Author(s)
      Kenshi Takahashi
    • Organizer
      Symposium on the use of new techniques to understand gas exchange and carbon dynamics in the forest ecosystem
    • Place of Presentation
      京都大学吉田キャンパス
    • Year and Date
      2010-11-01
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] レーザー計測技術による生物圏・大気圏の微量気体交換過程の研究2010

    • Author(s)
      高橋けんし
    • Organizer
      第4回分子科学シンポジウム
    • Place of Presentation
      東京大学駒場キャンパス(招待講演)
    • Year and Date
      2010-07-10
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Field application of near-infrared laser spectroscopy : Trace gas exchange between the atmosphere and biosphere2009

    • Author(s)
      Kenshi Takahashi
    • Organizer
      Workshop on Chemistry in the Earth's Atmosphere-Cross-cutting Aspects of Molecular Science and Atmospheric Chemistry-
    • Place of Presentation
      Tokyo Institute of Technology, Tokyo.(Invited talk)
    • Year and Date
      2009-09-08
    • Related Report
      2010 Final Research Report
  • [Presentation] Field application of near-infrared laser spectroscopy : Trace gas exchange between the atmosphere and biosphere (Invited talk)2009

    • Author(s)
      Kenshi Takahashi
    • Organizer
      Workshop on Chemistry in the Earth's Atmosphere-Cross-cuting Aspects of Molecular Science and Atmospheric Chemistry-
    • Place of Presentation
      Tokyo Institute of Technology, Tokyo
    • Year and Date
      2009-09-08
    • Related Report
      2009 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://www.rish.kyoto-u.ac.jp/~tkenshi/index.html

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://www.rish.kyoto-u.ac.jp/~tkenshi/index.html

    • Related Report
      2010 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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