Fabrication of novel CO_2 electrochemical reduction cell with Nanotube electrode

• Project/Area Number: 21710079
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Environmental technology/Environmental materials
• Research Institution: Mie University
• Principal Investigator: KANECO Satoshi 三重大学, 大学院・工学研究科, 准教授 (70281079)
• Project Period (FY): 2009 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000); Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
• Keywords: 炭酸ガス / 電気化学的還元 / ナノチューブ / ギ酸 / メタン / エチレン / ナノチューブ電極 / 燃料電池 / 地球温暖化(1) / 地球温暖化

Research Abstract

We have fabricated the electrochemical reduction cell for carbon dioxide with metal and semiconductor nanotube membranes. The uniform size titanium oxide nanotubes were obtained by the electrochemical anodization processes. The anodization conditions were optimized for the efficient nanotube electrodes.

Research Products

• [Journal Article] Photocatalytic Hydrogen Production from Aqueous Methanol Solution with CuO/Al_2O_3/TiO_2 Nanocomposite Int (2010)
  • Author(s): T. Miwa, S. Kaneco, H. Katsumata, et al
  • Journal Title: J. Hydrogen Energy Volume: 35 Pages: 6554-6560
• [Journal Article] Photocatalytic Hydrogen Production from Aqueous Methanol Solution with CuO/Al_2O_3/TiO_2 Nanocomposite (2010)
  • Author(s): T.Miwa, S.Kaneco, H.Katsumata, et al.
  • Journal Title: Int.J.Hydrogen Energy Volume: 35 Pages: 6554-6560
  • Peer Reviewed
• [Journal Article] Photoelectrochemical Reduction of C_O2 at p-InP Electrode in Copper Particle-suspended Methanol (2009)
  • Author(s): S. Kaneco, Y. Ueno, H. Katsumata, T. Suzuki, K. Ohta
  • Journal Title: Chem. Eng. J Volume: 148 Pages: 57-62
• [Journal Article] Electrochemical Reduction of CO_2 in Methanol with Aid of CuO and Cu_2O (2009)
  • Author(s): S. Ohya, S. Kaneco, H. Katsumata, T. Suzuki, K. Ohta
  • Journal Title: Catal. Today Volume: 148 Pages: 329-334
• [Journal Article] Photoelectrochemical Reduction of CO_2 at p-InP Electrode in Copper Particle-suspended Methanol (2009)
  • Author(s): S.Kaneco, Y.Ueno, H.Katsumata, T.Suzuki, K.Ohta
  • Journal Title: Chem.Eng.J. 148 Pages: 57-62
  • Peer Reviewed
• [Journal Article] Electrochemical Reduction of CO_2 in Methanol with Aid of CuO and Cu_2O (2009)
  • Author(s): S.Ohya, S.Kaneco, H.Katsumata, T.Suzuki, K.Ohta
  • Journal Title: Catal.Today 148 Pages: 329-334
  • Peer Reviewed
• [Presentation] Photocatalytic Hydrogen Production from Aqueous Na_2S+Na_2SO_3 Solution with Modified ZnO Photocatalyst (2012)
  • Author(s): K.Hachisuka, S.Kaneco, H.Katsumata, T.Suzuki, K.Ohta
  • Organizer: The 1^<st> International Symposium for Sustainability by Engineering at MIU
  • Place of Presentation: 三重県津市
  • Year and Date: 2012-12-02
• [Presentation] Photocatalytic Hydrogen Production from Aqueous Methanol Solution (2012)
  • Author(s): S. Kaneco, H. Katsumata, T. Suzuki, K. Ohta
  • Organizer: 243th ACS National Meetings & Expositions
  • Place of Presentation: San Diego, California
  • Year and Date: 2012-03-25
• [Presentation] Photocatalytic Hydrogen Production from Aqueous Methanol Solution (2012)
  • Author(s): S.Kaneco, H.Katsumata, T.Suzuki, K.Ohta
  • Organizer: 243th ACS National Meetings & Expositions
  • Place of Presentation: San Diego, California(招待講演)
  • Year and Date: 2012-03-25
• [Presentation] Photocatalytic Hydrogen Production from Aqueous Na_2S+ Na_2SO_3 Solution with Modified ZnO Photocatalyst (2011)
  • Author(s): K. Hachisuka, S. Kaneco, H. Katsumata, T. Suzuki, K. Ohta
  • Organizer: The 1st International Symposium for Sustainability by Engineering at MIU
  • Place of Presentation: 三重県津市
  • Year and Date: 2011-12-02
• [Presentation] 金属光析出担持法を併用した酸化チタン光触媒を用いる水素生成法の開発 (2011)
  • Author(s): 河村嗣也,金子聡,勝又英之,鈴木透,太田清久
  • Organizer: 第42回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 長野市
  • Year and Date: 2011-11-06
• [Presentation] 金属光析出担持法を併用した酸化チタン光触媒を用いる水素生成法の開発 (2011)
  • Author(s): 金子聡, 勝又英之, 鈴木透, 太田清久
  • Organizer: 第42回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 三重県津市
  • Year and Date: 2011-11-06
• [Presentation] Environmental Purification Technology (2011)
  • Author(s): S. Kaneco
  • Organizer: International Conference : TAMI Colloquium
  • Place of Presentation: Malaysia
  • Year and Date: 2011-09-08
• [Presentation] Environmental Purification Technology (2011)
  • Author(s): S.Kaneco
  • Organizer: International Conference : TAMI Colloqium
  • Place of Presentation: Malaysia(招待講演)
  • Year and Date: 2011-09-08
• [Presentation] 修飾型酸化亜鉛亜鉛光触媒による水素生成 (2011)
  • Author(s): 蜂須賀功真,金子聡,勝又英之,鈴木透,太田清久
  • Organizer: 第30回分析化学中部夏期セミナー
  • Place of Presentation: 三重県津市
  • Year and Date: 2011-08-31
• [Presentation] 金属光析出担持法を併用したTiO_2 (2011)
  • Author(s): 河村嗣也,金子聡,勝又英之,鈴木透,太田清久
  • Organizer: 光触媒を用いる水素生成法の開発
  • Place of Presentation: 三重県津市
  • Year and Date: 2011-08-31
• [Presentation] 金属光析出担持法を併用したTiO_2光触媒を用いる水素生成法の開発 (2011)
  • Author(s): 河村嗣也, 金子聡, 勝又英之, 鈴木透, 太田清久
  • Organizer: 第30回分析化学中部夏期セミナー
  • Place of Presentation: 三重県津市
  • Year and Date: 2011-08-31
• [Presentation] Renewable Hydrogen and Carbon Sequestration Technologies for Sustainable Environment (2011)
  • Author(s): S. Kaneco
  • Organizer: International Conference on Chemical Innovation 2011
  • Place of Presentation: Malaysia
  • Year and Date: 2011-05-23
• [Presentation] Renewable Hydrogen and Carbon Sequestration Technologies for Sustainable Environment (2011)
  • Author(s): S.Kaneco
  • Organizer: International Conference on Chemical Innovation 2011
  • Place of Presentation: Malaysia(招待講演)
  • Year and Date: 2011-05-23
• [Presentation] Electrochemical reduction of carbon dioxide at modified electrode in methanol-based electrolyte (2010)
  • Author(s): S. Ohya, S. Kaneco, H. Katsumata
  • Organizer: Pacifichem 2010
  • Place of Presentation: アメリカハワイ
• [Presentation] Electrochemical reduction of carbon dioxide at modified electrode in methanol-based electrolyte (2010)
  • Author(s): S.Ohya ; S.Kaneco ; H.Katsumata, et al.
  • Organizer: Pacifichem 2010
  • Place of Presentation: 米国ハワイ
• [Presentation] メタノール溶媒系の炭酸ガス電解還元における酸化銅の電極触媒特性 (2009)
  • Author(s): 大矢真也,金子聡,勝又英之,鈴木透,太田清久
  • Organizer: 第40回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 岐阜市
• [Presentation] Electrocatalytic Reduction of Carbon Dioxide on CuO in Methanol (2009)
  • Author(s): S. Ohya, S. Kaneco, H. Katsumata, T. Suzuki, K. Ohta
  • Organizer: 10th International Conference on CO_2 Utilization
  • Place of Presentation: 中国天津
• [Presentation] Electrocatalytic Reduction of Carbon Dioxide on CuO in Methanol (2009)
  • Author(s): S.Ohya, S.Kaneco, H.Katsumata, T.Suzuki, K.Ohta
  • Organizer: 10^<th> International Conference on CO_2 Utilization
  • Place of Presentation: 中国天津
• [Presentation] メタノール溶媒系の炭酸ガス電解還元における酸化銅の電極触媒特性 (2009)
  • Author(s): 大矢真也・金子聡・勝又英之・鈴木透・太田清久
  • Organizer: 第40回中部化学関係学協会支部連合秋季大会
  • Place of Presentation: 岐阜大学
• [Book] ACS Symposium Series (2012)
  • Author(s): S. Kaneco, T. Miwa, K. Hachisuka, H. Katsumata, T. Suzuki, S. C. Verma, K. Sugihara
• [Book] Photocatalytic Hydrogen Production from Aqueous Alcohol Solution with Titanium Dioxide Nanocomposites (2012)
  • Author(s): S.Kaneco, T.Miwa, K.Hachisuka, H.Katsumata, T.Suzuki, S.C.Verma, K.Sugihara
  • Publisher: ACS Symposium Series
• [Book] Photo/Electrochemistry & Photobiology in the Environment, Energy and Fuel (2009)
  • Author(s): Satoshi Kaneco
  • Total Pages: 196
  • Publisher: Research Signpost Publisher
• [Patent(Industrial Property Rights)] 二酸化炭素還元用粉末圧縮電極 (2011)
  • Inventor(s): 金子聡
  • Industrial Property Rights Holder: 金子聡
  • Industrial Property Number: 2011-053818
  • Filing Date: 2011-03-11
• [Patent(Industrial Property Rights)] 二酸化炭素還元用粉末圧縮電極 (2011)
  • Inventor(s): 金子聡, 他
  • Industrial Property Rights Holder: 金子聡
  • Industrial Property Number: 2011-053818
  • Filing Date: 2011-03-11
• [Patent(Industrial Property Rights)] 銅及び銅酸化物触媒を利用した大気環境修復方法 (2009)
  • Inventor(s): 三輪託也・林和己・金子聡・勝又英之・鈴木透・太田清久
  • Industrial Property Rights Holder: 金子聡
  • Industrial Property Number: 2009-143802
  • Filing Date: 2009-06-17