Studies on strigols, signaling molecules of symbiotic associations with fungi and phytohormones inhibiting shoot branching
Project/Area Number |
21710214
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Single-year Grants |
Research Field |
Living organism molecular science
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Research Institution | Keio University |
Principal Investigator |
SHOJI Mitsuru Keio University, 薬学部, 准教授 (30339139)
|
Project Period (FY) |
2009 – 2010
|
Project Status |
Completed (Fiscal Year 2010)
|
Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2009: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
|
Keywords | 5-デオキシストリゴール / 全合成 / 菌根共生 / 植物ホルモン / 還元的炭素-炭素結合形成反応 / 生物有機化学 / 有機化学 |
Research Abstract |
The total synthesis of 5-deoxystrigol was carried out via regioselective coupling reaction between the aluminum ate complex of an alkyne and an epoxide, and two reductive carbon-carbon bond formations in the presence of transition metals such as titanium and samarium as key steps. A lipase-mediated kinetic resolution was successfully proceeded to afford optically active 5-deoxystrigols.
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Report
(3 results)
Research Products
(8 results)
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[Presentation] 天然物合成と人2009
Author(s)
庄司満
Organizer
東北大学第1回GCOE有機系若手シンポジウム
Place of Presentation
宮城県仙台市
Year and Date
2009-08-01
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