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Molecular manipulator driven by spatial variation of molecular order

Research Project

Project/Area Number 21740312
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Biophysics/Chemical physics
Research InstitutionNational Institute for Materials Science

Principal Investigator

SAMITSU Sadaki  National Institute for Materials Science, ナノ有機センター, 研究員 (80432350)

Research Collaborator TAKANISHI Yoichi  京都大学, 大学院・理学研究科物理学, 宇宙物理学専攻准教授 (80251619)
YAMAMOTO Jun  京都大学, 大学院・理学研究科物理学, 宇宙物理学専攻教授 (10200809)
Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2009: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywordsソフトマター物理学 / 液晶 / アゾベンゼン / オーダーパラメータ / 分子マニピュレーション / マニピュレーター / 形状効果 / ナノ秩序構造 / 光異性化 / 液晶・高分子複合系 / パターン形成 / ソフトマター / ナノ構造 / 光ピンセット
Research Abstract

Previous studies on liquid crystal systems containing impurities such as colloidal particles have focused on the collective long-range interactions among micron-scale impurities, resulting from elastic distortion of the liquid crystalline order. Here, we propose a novel mechanism in which the spatial variation of S generates a 'force' that transports nano-scale solutes mediated by the coupling between S and solute concentration. We have successfully designed a prototype of a molecular manipulator that transports a molecular solute along spatial variations of the scalar order parameter, modulated in a controlled manner by spot illumination of an azobenzene-doped nematic phase by UV light. The manipulator can control the spatial variation of the polymer concentration; therefore it shows promise for use in the design of novel hybrid soft materials.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (17 results)

All 2011 2010 2009 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (9 results) Remarks (2 results)

  • [Journal Article] Molecular Manipulator Driven by Spatial Variation of Liquid Crystalline Order2010

    • Author(s)
      S.Samitsu, Y.Takanishi, J.Yamamoto
    • Journal Title

      Nature Materials 9

      Pages: 816-820

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Field-effect carrier transport in poly (3-alkylthiophene) nanofiber networks and isolated nanofibers2010

    • Author(s)
      S.Samitsu, T.Shimomura, S.Heike, T.Hashizume, K.Ito
    • Journal Title

      Macromolecules 43

      Pages: 7891-7894

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molecular Manipulator Driven by Spatial Variation of Liquid Crystalline Order2010

    • Author(s)
      S.Samitsu, Y.Takanishi, J.Yamamoto
    • Journal Title

      Nature Materials

      Volume: 9 Pages: 816-820

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Field-effect carrier transport in poly(3-alkylthiophene) nanofiber networks and isolated nanofibers2010

    • Author(s)
      S.Samitsu, T.Shimomura, S.Heike, T.Hashizume, K.Ito
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 7891-7894

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-Assembly and One-Dimensional Alignment of a Conducting Polymer Nanofiber in a Nematic Liquid Crystal2009

    • Author(s)
      S.Samitsu, Y.Takanishi, J.Yamamoto
    • Journal Title

      Macromolecules 42

      Pages: 4366-4368

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Self-Assembly and One-Dimensional Alignment of a Conducting Polymer Nanofiber in a Nematic Liquid Crystal2009

    • Author(s)
      S.Samitsu, Y.Takanishi, J.Yamamoto
    • Journal Title

      Macromolecules

      Volume: 42 Pages: 4366-4368

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] 導電性高分子のナノファイバー構造化と電荷輸送特性2011

    • Author(s)
      佐光貞樹
    • Organizer
      10-2高分子基礎物性研究会
    • Place of Presentation
      東京大学本郷キャンパス山上会館
    • Year and Date
      2011-03-04
    • Related Report
      2010 Final Research Report
  • [Presentation] 導電性高分子のナノファイバー構造化と電荷輸送特性2011

    • Author(s)
      佐光貞樹
    • Organizer
      10-2高分子基礎物性研究会
    • Place of Presentation
      東京大学山上会館
    • Year and Date
      2011-03-04
    • Related Report
      2010 Annual Research Report
  • [Presentation] 液晶秩序の変調に基づく高分子マニピュレーターの開発2010

    • Author(s)
      佐光貞樹・高西陽一・山本潤
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学高等教育機能開発総合センター
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 導電性高分子ナノファイバーの形成と電界効果トランジスタ特性2010

    • Author(s)
      佐光貞樹
    • Organizer
      第25回茨城地区「若手の会」交流会
    • Place of Presentation
      つくばセミナーハウス
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] 液晶秩序の変調に基づく高分子マニピュレーターの開発2010

    • Author(s)
      佐光貞樹、高西陽一、山本潤
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 液晶秩序の空間制御を用いた分子マニピュレーターとその応用2010

    • Author(s)
      佐光貞樹
    • Organizer
      つくばソフトマター研究会2010
    • Place of Presentation
      独立行政法人産業技術総合研究所
    • Related Report
      2010 Final Research Report
  • [Presentation] アゾベンゼンの光異性化による液晶秩序の制御と分子マニピュレーションへの応用2009

    • Author(s)
      佐光貞樹
    • Organizer
      液晶学会合同フォーラム講演会
    • Place of Presentation
      立命館大学琵琶湖草津キャンパスエポック立命21
    • Year and Date
      2009-11-25
    • Related Report
      2010 Final Research Report
  • [Presentation] アゾベンゼンの光異性化による液晶秩序の制御と分子マニピュレーションへの応用2009

    • Author(s)
      佐光貞樹
    • Organizer
      日本液晶学会 4フォーラム合同講演会
    • Place of Presentation
      立教大学びわこ・くさつキャンパス(滋賀県草津市)
    • Year and Date
      2009-11-25
    • Related Report
      2009 Annual Research Report
  • [Presentation] 液晶配向秩序の制御に基づく分子マニピュレータ2009

    • Author(s)
      佐光貞樹
    • Organizer
      第24回茨城地区「若手の会」交流会
    • Place of Presentation
      つくばセミナーハウス
    • Year and Date
      2009-10-29
    • Related Report
      2010 Final Research Report
  • [Remarks] ホームページ等

    • URL

      http://www.nims.go.jp/mfo/

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://softmatter.scphys.kyoto-u.ac.jp/

    • Related Report
      2010 Final Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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