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Local electronic structure and charge transport dynamics in organic films and interfaces by means of inner-shell excitation

Research Project

Project/Area Number 21750030
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Physical chemistry
Research InstitutionInstitute for Molecular Science

Principal Investigator

YAMANE Hiroyuki  Institute for Molecular Science, 光分子科学研究領域, 助教 (50402459)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords軟X線吸収分光法 / 軟X線発光分光法 / 角度分解光電子分光法 / 局所電子状態 / 電荷輸送 / 分子配向 / 有機半導体 / フタロシアニン / 電子状態 / 表面・界面 / 共鳴光電子分光法 / 放射光 / シンクロトロン放射光
Research Abstract

The electronic structure of organic thin films and interfaces plays a crucial role in the performance of organic devices such as light-emitting diodes, field-effect transistors, and photovoltaic cells. The functionality of these devices is dominated by the geometric film/interface structure, which varies depending on the molecular structure and the sample preparation. In this work, we succeeded to clarify the correlation between the geometric and electronic structure of organic thin films and interfaces by means of the combination of (i) the control of geometric film/interface structure and (ii) local electronic structure analyses based on soft X-ray spectroscopies.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (47 results)

All 2011 2010 2009 Other

All Journal Article (15 results) (of which Peer Reviewed: 15 results) Presentation (29 results) Remarks (3 results)

  • [Journal Article] Dielectric properties of polar-phthalocyanine monolayer systems with repulsive dipole interaction2011

    • Author(s)
      H.Fukagawa, S.Hosoumi, H.Yamane, S.Kera, N.Ueno
    • Journal Title

      Phys.Rev.B 83

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dielectric properties of polar-phthalocyanine monolayer systems with repulsive dipole interaction2011

    • Author(s)
      H.Fukagawa, S.Hosoumi, H.Yamane, S.Kera, N.Ueno
    • Journal Title

      Physical Review B

      Volume: 83

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Site-specific geometric and electronic relaxations at organic-metal interfaces2010

    • Author(s)
      H.Yamane, A.Gerlach, S.Duhm, Y.Tanaka, T.Hosokai, Y.Y.Mi, J.Zegenhagen, N.Koch, K.Seki, F.Schreiber
    • Journal Title

      Phys.Rev.Lett. 105

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] A systematic study of soft-X-ray spectra of poly(dG)-poly(dC) and poly(dA)-poly(dT) DNA duplexes2010

    • Author(s)
      W.Hua, H.Yamane, B.Gao, J.Jiang, S.Li, H.S.Kato, M.Kawai, T.Hatsui, Y.Luo, N.Kosugi, H.Agren
    • Journal Title

      J.Phys.Chem.B 114

      Pages: 7016-7021

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] 第14回日本放射光学会奨励賞受賞研究報告:高度構造制御による有機薄膜・界面電子状態の精密実験2010

    • Author(s)
      山根宏之
    • Journal Title

      放射光 23

      Pages: 132-134

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Site-specific geometric and electronic relaxations at organic-metal interfaces2010

    • Author(s)
      H.Yamane, A.Gerlach, S.Duhm, Y.Tanaka, T.Hosokai, Y.Y.Mi, J.Zegenhagen, N.Koch, K.Seki, F.Schreiber
    • Journal Title

      Physical Review Letters

      Volume: 105

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A systematic study of soft-X-ray spectra of poly(dG)-poly(dC) and poly(dA)-poly(dT) DNA duplexes2010

    • Author(s)
      W.Hua, H.Yamane, B.Gao, J.Jiang, S.Li, H.S.Kato, M.Kawai, T.Hatsui, Y.Luo, N.Kosugi, H.Agren
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 114 Pages: 7016-7021

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface structural study on ionic liquids using metastable atom electron spectroscopy2009

    • Author(s)
      T.Iwahashi, T.Nishi, H.Yamane, T.Miyamae, K.Kanai, K.Seki, D.Kim, Y.Ouchi
    • Journal Title

      J.Phys.Chem.C 113

      Pages: 19237-19243

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Impact of interface geometric structure on organic-metal interface energetics and subsequent films electronic structure2009

    • Author(s)
      H.Yamane, K.Kanai, Y.Ouchi, N.Ueno, K.Seki
    • Journal Title

      J.Electron Spectrosc.Relat.Phenom. 174

      Pages: 28-34

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] First principles measurements of charge mobility in organic semiconductors : Valence hole-vibration coupling in organic ultrathin films2009

    • Author(s)
      S.Kera, H.Yamane, N.Ueno
    • Journal Title

      Prog.Surf.Sci. 84

      Pages: 135-154

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] 解説論文:有機半導体における電子物性の解明と制御2009

    • Author(s)
      山根宏之, 上野信雄, 関一彦
    • Journal Title

      放射光 22

      Pages: 192-201

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Impact of interface geometric structure on organic-metal interface energetics and subsequent films electronic structure2009

    • Author(s)
      H.Yamane, K.Kanai, Y.Ouchi, N.Ueno, K.Seki
    • Journal Title

      Journal of Electron Spectroscopy and Related Phenomena 174

      Pages: 28-34

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] First principles measurements of charge mobility in organic semiconductors : Valence hole-vibration coupling in organic ultrathin films2009

    • Author(s)
      S.Kera, H.Yamane, N.Ueno
    • Journal Title

      Progress in Surface Science 84

      Pages: 135-154

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface structural study on ionic liquids using metastable atom electron spectroscopy2009

    • Author(s)
      T.Iwahashi, T.Nishi, H.Yamane, T.Miyamae, K.Kanai, K.Seki, D.Kim, Y.Ouchi
    • Journal Title

      Journal of Physical Chemistry(c) 113

      Pages: 19237-19243

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 解説;有機半導体における電子物性の解明と制御2009

    • Author(s)
      山根宏之、上野信雄、関一彦
    • Journal Title

      放射光 22

      Pages: 192-201

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] フタロシアニン結晶膜における狭い分子間エネルギーバンド分散の観測2011

    • Author(s)
      山根宏之, 池滝何以, 嘉治寿彦, 平本昌宏, 小杉信博
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟大学(新潟)
    • Year and Date
      2011-03-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] Highly efficient soft X-ray emission spectrometer using a transmission grating2010

    • Author(s)
      H.Yamane, T.Hatsui, N.Kosugi
    • Organizer
      The International Chemical Congress of Pacific Basin Societies Sponsors : Pacifichem2010
    • Place of Presentation
      ホノルル(米国)
    • Year and Date
      2010-12-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] 透過型軟X線発光分光器の高度化と分子性固体の局所電子構造解析2010

    • Author(s)
      山根宏之, 初井宇記, 小杉信博
    • Organizer
      第4回分子科学討論会
    • Place of Presentation
      大阪大学(大阪)
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] フタロシアニン結晶膜における狭い分子間エネルギーバンド分散の観測2010

    • Author(s)
      山根宏之, 池滝何以, 嘉治寿彦, 平本昌宏, 小杉信博
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟大
    • Related Report
      2010 Final Research Report
  • [Presentation] Highly efficient soft X-ray emission spectrometer using a transmission grating2010

    • Author(s)
      H.Yamane, T.Hatsui, N.Kosugi
    • Organizer
      The International Chemical Congress of Pacific Basin Societies Sponsors : Pacifichem2010
    • Place of Presentation
      Honolulu
    • Related Report
      2010 Final Research Report
  • [Presentation] 透過型軟X線発光分光器の高度化と分子性固体の局所電子構造解析2010

    • Author(s)
      山根宏之, 初井宇記, 小杉信博
    • Organizer
      第4回分子科学討論会
    • Place of Presentation
      大阪大
    • Related Report
      2010 Final Research Report
  • [Presentation] 分子間相互作用に依存した有機固体の局所電子状態と透過型軟X線発光分光器の現状2010

    • Author(s)
      山根宏之, 初井宇記, 小杉信博
    • Organizer
      日本物理学会第65回年次大会
    • Place of Presentation
      岡山大
    • Related Report
      2010 Final Research Report
  • [Presentation] Site-specific geometric and electronic relaxation at organic/metal interfaces2010

    • Author(s)
      H.Yamane, A.Gerlach, S.Duhm, Y.Tanaka, T.Hosokai, N.Koch, F.Schreiber, K.Seki
    • Organizer
      5th International workshop on Electronic Structure and Processes of Molecular-Based Interfaces : In Relation to Organic and Molecular Devices : ESPMI-V
    • Place of Presentation
      Chiba
    • Related Report
      2010 Final Research Report
  • [Presentation] 高度構造制御による有機薄膜・界面電子状態の精密実験2010

    • Author(s)
      山根宏之
    • Organizer
      第23回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      イーグレ姫路(受賞記念講演)
    • Related Report
      2010 Final Research Report
  • [Presentation] Impact of interface geometric structure on organic-metal interface energetics and subsequent films electronic structure : The case of pentacene2010

    • Author(s)
      H.Yamane, K.Kanai, N.Ueno, K.Seki
    • Organizer
      5th International workshop on Electronic Structure and Processes of Molecular-Based Interfaces : In Relation to Organic and Molecular Devices : ESPMI-V
    • Place of Presentation
      Chiba
    • Related Report
      2010 Final Research Report
  • [Presentation] 分子間相互作用に依存した有機固体の局所電子状態と透過型軟X線発光分光器の現状2010

    • Author(s)
      山根宏之, 初井宇記, 小杉信博
    • Organizer
      日本物理学会第65回年次大会
    • Place of Presentation
      岡山大学(岡山県)
    • Related Report
      2009 Annual Research Report
  • [Presentation] Site-specific geometric and electronic relaxation at organic/metal interfaces2010

    • Author(s)
      H.Yamane, A.Gerlach, S.Duhm, Y.Tanaka, T.Hosokai, N.Koch, F.Schreiber, K.Seki
    • Organizer
      5th International workshop on Electronic Structure and Processes of Molecular-Based Interfaces : In Relation to Organic and Molecular Devices : ESPMI-V
    • Place of Presentation
      千葉大学(千葉県)
    • Related Report
      2009 Annual Research Report
  • [Presentation] 高度構造制御による有機薄膜・界面電子状態の精密実験2010

    • Author(s)
      山根宏之
    • Organizer
      第23回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      イーグレ姫路(兵庫県)
    • Related Report
      2009 Annual Research Report
  • [Presentation] Elucidation and control of electronic properties related to organic nanoelectronics2009

    • Author(s)
      H.Yamane
    • Organizer
      Multi-Dimension Seminar : Frontiers in Nanoscience and Technology
    • Place of Presentation
      JAIST(招待講演)
    • Year and Date
      2009-09-18
    • Related Report
      2010 Final Research Report
  • [Presentation] Elucidation and control of electronic properties related to organic Nanoelectronics2009

    • Author(s)
      山根宏之
    • Organizer
      Multi-Dimension Seminar : Frontiers in Nanoscience and Technology
    • Place of Presentation
      北陸先端大学院大学(石川県)
    • Year and Date
      2009-09-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] Recent progress and future prospects of transmission-grating-based X-ray emission spectroscopy of functional materials2009

    • Author(s)
      H.Yamane, T.Hatsui, N.Kosugi
    • Organizer
      Workshop on soft X-ray scattering
    • Place of Presentation
      Hsinchu(招待講演)
    • Related Report
      2010 Final Research Report
  • [Presentation] Bulk electronic structure of organic solids probed by soft X-ray emission spectroscopy using transmission-grating spectrometer2009

    • Author(s)
      H.Yamane, T.Hatsui, N.Kosugi
    • Organizer
      11th International Conference on Electronic Spectroscopy and Structure : ICESS-11
    • Place of Presentation
      Nara
    • Related Report
      2010 Final Research Report
  • [Presentation] XSW and ARUPS study on Znphthalocyanine/Cu(111) interface : correlating interfacial geometric and electronic structure2009

    • Author(s)
      H.Yamane, A.Gerlach, S.Duhm, T.Hosokai, Y.Tanaka, F.Schreiber, K.Seki
    • Organizer
      11th International Conference on Electronic Spectroscopy and Structure : ICESS-11
    • Place of Presentation
      Nara
    • Related Report
      2010 Final Research Report
  • [Presentation] Soft X-ray emission spectroscopy of organic solids2009

    • Author(s)
      H.Yamane, T.Hatsui, N.Kosugi
    • Organizer
      5th Workshop on Advanced Spectroscopy of Organic Materials for Electronic Applications : ASOMEA-V
    • Place of Presentation
      Krusenberg(招待講演)
    • Related Report
      2010 Final Research Report
  • [Presentation] Adsorption-induced modification of geometric and electronic structure at organic/metal interface2009

    • Author(s)
      H.Yamane, A.Gerlach, S.Duhm, T.Hosokai, Y.Tanaka, F.Schreiber, K.Seki
    • Organizer
      5th Workshop on Advanced Spectroscopy of Organic Materials for Electronic Applications : ASOMEA-V
    • Place of Presentation
      Krusenberg
    • Related Report
      2010 Final Research Report
  • [Presentation] 放射光を用いて有機/金属界面の構造と電子状態の相関を探る2009

    • Author(s)
      山根宏之
    • Organizer
      日本物理学会2009年度秋期大会
    • Place of Presentation
      熊本大(招待講演)
    • Related Report
      2010 Final Research Report
  • [Presentation] 軟X線発光分光法による有機固体のエネルギーギャップ近傍電子状態2009

    • Author(s)
      山根宏之, 初井宇記, 小杉信博
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名大
    • Related Report
      2010 Final Research Report
  • [Presentation] 高度構造制御による有機半導体薄膜・界面の電子物性2009

    • Author(s)
      山根宏之
    • Organizer
      物性研短期研究会「高輝度VSX光源が切り拓く先端分光と物性研究への展開」
    • Place of Presentation
      東大物性研(招待講演)
    • Related Report
      2010 Final Research Report
  • [Presentation] Recent progress and future prospects of transmission-grating-based X-ray emission spectroscopy of functional materials2009

    • Author(s)
      山根宏之, 初井宇記, 小杉信博
    • Organizer
      International workshop on soft X-ray scattering
    • Place of Presentation
      National Synchrotron Radiation Research Center:NSRRC(台湾)
    • Related Report
      2009 Annual Research Report
  • [Presentation] Bulk electronic structure of organic solids probed by soft X-ray emission spectroscopy using transmission-grating spectrometer2009

    • Author(s)
      山根宏之, 初井宇記, 小杉信博
    • Organizer
      11th International Conference on Electronic Spectroscopy and Structure : ICESS-11
    • Place of Presentation
      奈良県新公会堂(奈良県)
    • Related Report
      2009 Annual Research Report
  • [Presentation] Soft X-ray emission spectroscopy of organic solids2009

    • Author(s)
      山根宏之, 初井宇記, 小杉信博
    • Organizer
      5th Workshop on Advanced Spectroscopy of Organic Materials for Electronic Applications : ASOMEA-V
    • Place of Presentation
      Krusenberg Herrgard(Sweden)
    • Related Report
      2009 Annual Research Report
  • [Presentation] 放射光を用いて有機/金属界面の構造と電子状態の相関を探る2009

    • Author(s)
      山根宏之
    • Organizer
      日本物理学会2009年度秋期大会
    • Place of Presentation
      熊本大学(熊本県)
    • Related Report
      2009 Annual Research Report
  • [Presentation] 軟X線発光分光法による有機固体のエネルギーギャップ近傍電子状態2009

    • Author(s)
      山根宏之, 初井宇記, 小杉信博
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名古屋大学(愛知県)
    • Related Report
      2009 Annual Research Report
  • [Presentation] 高度構造制御による有機半導体薄膜・界面の電子物性2009

    • Author(s)
      山根宏之
    • Organizer
      物性研短期研究会「高輝度VSX光源が切り拓く先端分光と物性研究への展開」
    • Place of Presentation
      東京大学物性研究所(東京都)
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • Related Report
      2010 Final Research Report
  • [Remarks] 第14回日本放射光学会奨励賞受賞(2010年1月)

    • URL

      http://www.ims.ac.jp/topics/2009/091209.html

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.ims.ac.jp/publications/letters61/601.pdf

    • Related Report
      2009 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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