| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Research Abstract |
Synthesis of functional hetero-π-conjugated molecules by taking advantage of electron-withdrawing property and Lewis acidity of boron was investigated for the development of electron-transporting material and anion sensors. Fluorescence molecular sensors for biologically active anions, such as fluoride and cyanide ions, were developed using a dibenzoazaborine framework. The synthesis of electron-accepting conjugated molecules based on oligoacene-like frameworks substituted with boron atoms was investigated. The electron-accepting and anion-complexation abilities of a 9,10-dihydro-9,10-diboraanthracene were elucidated.
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