Construction of novel metal-containing nanotubes viaself-assembling of cylindrical multidentate ligands
| Project/Area Number |
21750054
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Inorganic chemistry
|
|---|
| Research Institution | University of Tsukuba |
|---|
Principal Investigator |
AKINE Shigehisa University of Tsukuba, 大学院・数理物質科学研究科, 准教授 (30323265)
|
|---|
| Project Period (FY) |
2009 – 2010
|
| Project Status |
Completed (Fiscal Year 2010)
|
| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2009: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
|
|---|
| Keywords | チューブ構造 / 超分子化学 / 自己集合 / 分子認識 / ナノチューブ / 金属錯体 / 大環状分子 |
|---|
| Research Abstract |
This research project aims to develop novel metal-containing nanotubes by metal-assisted self-assembly of macrocyclic ligands with a defined diameter. As a building block, cylindrical and disc-shaped ligands were designed and the construction of tubular structures by metal-assisted self-assembly was investigated.
A calix[6]arene-based ligand bearing pyridyl groups at the upper rim was synthesized. The complexation of the ligand with palladium(II) afforded coordination polymer that presumably has a tubular structure. When a macrocyclic hexaoxime ligand was reacted with zinc(II) acetate, a dimeric hexanuclear complex with a unique structure was formed. The structure of the complex was determined by X-ray crystallography. Metal-assisted self-aggregation of a dinickel(II) metallohost obtained from a disc-shaped bis(saloph) ligand was also studied.
|
Report
(3 results)
Research Products
(95 results)
-
-
-
-
[Journal Article] Wheel-Shaped Er^<III>Zn^<II> 3 Single-Molecule Magnet : A Macrocyclic Approach to Designing Magnetic Anisotropy2011
Author(s)
Yamashita, A., Watanabe, A., Akine, S., Nabeshima, T., Nakano, M., Yamamura, T., Kajiwara, T.
-
Journal Title
Angew.Chem., Int.Ed. 50
Pages: 4016-4019
Related Report
Peer Reviewed
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
[Presentation] Magnetic anisotropy designed SMM including Er (III) ion2010
Author(s)
Aika Yamashita, Akiko Watanabe, Takashi Kajiwara, Shigehisa Akine, Tatsuya Nabeshima, Motohiro Nakano, Tomoo Yamamura
Organizer
The International Chemical Congress of Pacific Basin Societies (Pacifichem 2010)
Place of Presentation
Honolulu, Hawaii, USA
Year and Date
2010-12-19
Related Report
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
