Synthesis, structure and aromatic properties of σ-bonded gallatabenzene complexes
| Project/Area Number |
21750056
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Gunma University |
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Principal Investigator |
MURAOKA Takako Gunma University, 大学院・工学研究科, 助教 (40400775)
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| Project Period (FY) |
2009 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2009: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
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| Keywords | ガラタベンゼン錯体 / シグマ結合型 / ガラシクロペンタジエニル錯体 / ガラタベンゼン / ガラシクロペンタジエニル配位子 / σ結合型 / 遷移金属ガリル錯体 / 合成 / ルイス塩基 / 不均化 |
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| Research Abstract |
Attempts to the synthesis of σ-bonded gallacyclohexadienyliron and -tungsten complexes by the reactions of dichlorogallyliron or -tungsten complexes with dilithiodialkenyl derivatives or cyclic tin compounds were not successful. On the other hand, gallacyclopentadienyliron complexes were obtained by the transmetallation between dichlorogallyliron complex and cyclopentadienylzirconium compound.
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Report
(3 results)
Research Products
(19 results)
