Regioselective Arrangement and Bond Activation of the Metallacycles Composed of the Heavier Group 14 Elements
| Project/Area Number |
21750057
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
TANABE Makoto Tokyo Institute of Technology, 資源化学研究所, 助教 (80376962)
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| Project Period (FY) |
2009 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2009: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
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| Keywords | ケイ素 / メタラサイクル / 不飽和有機分子 / 水素 / 10族遷移金属 / ポリシラン / 高分子合成 / ゲルマニウム / 脱水素カップリング反応 / スズ / 白金 / オリゴゲルマン / 環拡大反応 / アルキン / パラジウム |
|---|
| Research Abstract |
This study demonstrates new preparation of metallacycles composed of silicon, germanium, and tin and their chemical properties. A new and convenient synthetic method for oligogermanes was developed via these germametallacycles precursors. Nickel-catalyzed dehydrocoupling precise polymerizations of hydrosilanes produced cyclic oligosilanes with narrow molecular weight distribution.
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Report
(3 results)
Research Products
(38 results)
