Research on Photofunctional Uranium(III) Complexes
| Project/Area Number |
21750059
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kyushu University (2010)
Kanazawa University (2009) |
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Principal Investigator |
NAKAI Hidetaka Kyushu University, 工学研究院, 准教授 (70377399)
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| Project Period (FY) |
2009 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
|
| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
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| Keywords | 有機金属化学 / 金属錯体化学 / 光物性 |
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| Research Abstract |
An aim of this project is creation of photofunctional uranium(III) complexes. In order to achieve the aim, the research was focused on "the evaluation and development of photofuncitonal ligands" and "the establishment of synthetic methods of uranium(III) complexes". The obtained results are as follows :
(1) Novel photofunctionalized triazacyclononane (TACN) ligands were successfully synthesized.
(2) The terbium(III) complexes, which are mock complexes of the aimed uranium(III), were photo-physically characterized and valuable guidelines on how to design the ligands were obtained.
(3) A convenient synthetic route of uranium(III) complexes was developed.
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Report
(3 results)
Research Products
(28 results)
