| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
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| Research Abstract |
An aim of this project is creation of photofunctional uranium(III) complexes. In order to achieve the aim, the research was focused on "the evaluation and development of photofuncitonal ligands" and "the establishment of synthetic methods of uranium(III) complexes". The obtained results are as follows :
(1) Novel photofunctionalized triazacyclononane (TACN) ligands were successfully synthesized.
(2) The terbium(III) complexes, which are mock complexes of the aimed uranium(III), were photo-physically characterized and valuable guidelines on how to design the ligands were obtained.
(3) A convenient synthetic route of uranium(III) complexes was developed.
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