Development of highly-active noble-metal-free metal complex catalysts in the water splitting reaction
Project/Area Number |
21750065
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Single-year Grants |
Research Field |
Inorganic chemistry
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Research Institution | Kyushu University |
Principal Investigator |
MASAOKA Shigeyuki Kyushu University, 大学院・理学研究院, 助教 (20404048)
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Project Period (FY) |
2009 – 2010
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Project Status |
Completed (Fiscal Year 2010)
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Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2009: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
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Keywords | 金属錯体触媒 / 水素発生 / 酸素発生 / 水素エネルギー / 非貴金属 / 金属錯体 / 水可視光分解 / 太陽光エネルギー変換 / 鉄錯体 / ルテニウム錯体 / 光誘起電子移動 / セリウム錯体 / 水素生成触媒 / 酸素生成触媒 |
Research Abstract |
Water splitting reactions catalyzed by metal complexes have been investigated. A novel dinuclear iron complex was found to serve as a hydrogen-evolving catalyst from water. On the other hand, we revealed that cerium ion play an important role in water oxidation reaction.
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Report
(3 results)
Research Products
(87 results)
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[Journal Article] Photoinduced Electron Transfer in Tris(2,2'-bipyridine)ruthenium(II)-Viologen Dyads with Peptide Backbones Leading to Long-Lived Charge Separation and Hydrogen Evolution2010
Author(s)
Makoto Ogawa, Bijitha Balan, Gopalakrishnan Ajayakumar, Shigeyuki Masaoka, Heinz-Bernhard Kraatz, Masayasu Muramatsu, Syoji Ito, Yutaka Nagasawa, Hiroshi Miyasaka, Ken Sakai
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Journal Title
Dalton Trans. 39
Pages: 4421-4434
Related Report
Peer Reviewed
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[Journal Article] Photoinduced Electron Transfer in Tris (2,2'-bipyridine) ruthenium (II)-Viologen Dyads with Peptide Backbones Leading to Long-Lived Charge Separation, Hydrogen Evolution2010
Author(s)
Makoto Ogawa, Bijitha Balan, Gopalakrishnan Ajayakumar, Shigeyuki Masaoka, Heinz-Bernhard Kraatz, Masayasu Muramatsu, Syoji Ito, Yutaka Nagasawa, Hiroshi Mivasaka, Ken Sakai
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Journal Title
Related Report
Peer Reviewed
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[Journal Article] Dibromido(2,3,9,10-tetramethyl-1,4,8,11-tetr aazacyclotetradeca-1,3,8,10-tetraene)cobalt(III) bromide2009
Author(s)
Hoda El-Ghamry, Raafat Issa, Kamal El-Baradie, Shigeyuki Masaoka, Ken Sakai
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Journal Title
Acta Cryst. E65
Pages: 1378-1379
Related Report
Peer Reviewed
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[Journal Article] Dibromido (2,3,9,10-tetramethyl-1,4,8,11-tetraazacyclotetradeca-1,3,8,10-tetraene) cobalt (III) bromide2009
Author(s)
Hoda El-Ghamry, Raafat Issa, Kamal El-Baradie, Shigeyuki Masaoka, Ken Sakai
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Journal Title
Related Report
Peer Reviewed
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