Practical Synthesis and Properties of Seleno- and Tellurocarbonyl Complexes
| Project/Area Number |
21750066
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Chuo University |
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Principal Investigator |
MUTOH Yuichiro Chuo University, 理工学部, 助教 (50453676)
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| Project Period (FY) |
2009 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
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| Keywords | セレノカルボニル / テルロカルボニル / カーバイド錯体 / アトムトランスファー / チオカルボニル / ルテニウム / カルボニル |
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| Research Abstract |
The first five-coordinate selenocarbonyl complex, [RuCl_2(CSe)(H_2IMes)(PCy_3)] (H_2IMes=1,3-dimesitylimidazolin-2-ylidene), and the tellurocarbonyl complex [RuCl_2(CTe)(H_2IMes)(dmap)_2] (3-CTe ; dmap=4-(dimethylamino)pyridine) was obtained by selenium and tellurium atom transfer reaction to the carbido complex [RuCl_2(C)(H_2IMes)(PCy_3)]. Systematic elucidation of the complete series of chalcogenocarbonyl complexes revealed that tellurocarbonyl complex 3-CTe is a potential tellurium atom transfer reagent.
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Report
(3 results)
Research Products
(20 results)
