Synthesis and Polymerization Reactivity of Novel Rare-Earth Hydride Clusters.
| Project/Area Number |
21750068
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | The Institute of Physical and Chemical Research |
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Principal Investigator |
SHIMA Takanori 独立行政法人理化学研究所, 侯有機金属化学研究室, 専任研究員 (60391976)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2011: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
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| Keywords | 希土類金属 / ヒドリドクラスター / イットリウム / モリブデン / 多核錯体 / 異種多金属 / 水素吸蔵 / カチオン錯体 |
|---|
| Research Abstract |
A new series of structurally well-defined heterometallic hexanuclear polyhydride complexes have been successfully synthesized from the half-sandwich type yttrium polyhydride complexes,[{Cp^HYH_2}_4(THF)_4](Cp^H=C_5Me_4H) and[{Cp YH_2}_5(THF)_2](Cp=C_5Me_5), with d-transition metal hydrides such as[Cp M(PMe_3) H_5](M=Mo, W). Those new hydrides reversible take up and release H2, which can be tuned by changing the metal combination and the ligand environment.
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Report
(4 results)
Research Products
(36 results)
