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Analysis of the electron transfer at lipid membrane/water interface by a slab optical waveguide spectroscopy

Research Project

Project/Area Number 21750071
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Analytical chemistry
Research InstitutionNara University of Education (2010)
Gunma University (2009)

Principal Investigator

HOTTA Hiroki  Nara University of Education, 教育学部, 准教授 (80397603)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2009: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords化学センサー / 脂質膜 / 水相界面 / 電子移動 / 脂質二分子膜 / ベシクルフュージョン / 環境応答性色素 / 脂溶性抗酸化剤 / プロトン移動 / 脂質膜/水溶液界面 / 水溶液界面
Research Abstract

An electron transfer at lipid membrane/water interface was observed by a slab optical waveguide spectroscopy. A lipid membrane was formed on a thin glass plate, into which an excitation light was introduced. Thus, an absorption spectrum of the inside of lipid membrane was selectively observed by an evanescent wave of the guiding light. Curcumin, on of the lipophilic antioxidants, was distributed into the lipid membrane, and the oxidation, i.e. electron transfer reaction through the lipid membrane/water interface between H_2O_2 dissolved in water was observed.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (14 results)

All 2011 2010 2009

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (12 results)

  • [Journal Article] Suppression Mechanism of the Photodegradation of J-Aggregate Thin Films of Cyanine Dyes by Coating with Polysilanes.2011

    • Author(s)
      Hiroaki Horiuchi, Syohei Ishida, Ken-ichi Matsuzaki, Katsuhiko Tani, Takuya Hashimoto, Hiroki Hotta, Kin-ichi Tsunoda, Takuo Koraida, Tetsuo Okutsu, Hiroshi, Hiratsuka.
    • Journal Title

      J.Phys.Chem.C 115

      Pages: 6902-6909

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Suppression Mechanism of the Photodegradation of J-Aggregate Thin Films of Cyanine Dyes by Coating with Polysilanes2011

    • Author(s)
      Hiroaki Horiuchi, Hiroki Hotta, ら
    • Journal Title

      J.Phys.Chem.C

      Volume: 115 Pages: 6902-6909

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Application ofpolymer coated slab optical waveguide to the electrode surface analysis.2010

    • Author(s)
      堀田弘樹
    • Organizer
      The 2010 International Chemical Congress of PacificBasin Societies (PACIFICHEM 2010).
    • Place of Presentation
      ホノルル(ハワイ)(依頼講演)
    • Year and Date
      2010-12-19
    • Related Report
      2010 Final Research Report
  • [Presentation] Application of polymer coated slab optical waveguide to the electrode surface analysis.2010

    • Author(s)
      堀田弘樹、角田欣一, ら
    • Organizer
      The 2010 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2010)
    • Place of Presentation
      ホノルル(ハワイ)(招待講演)
    • Year and Date
      2010-12-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] Construction of a lipid bilayer membrane on the slab optical waveguide surface and the observation of chemical reactions at the hpid bilayer/solution interface.2010

    • Author(s)
      櫻井貴裕、堀田弘樹、角田欣一, ら
    • Organizer
      The 2010 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2010)
    • Place of Presentation
      ホノルル(ハワイ)
    • Year and Date
      2010-12-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] 光導波路蛍光顕微鏡システムの構築とその脂質分子膜観察への応用2010

    • Author(s)
      堀田弘樹
    • Organizer
      分析化学討論会(日本分析化学会)
    • Place of Presentation
      島根大学
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] 電極型スラブ光導波路を用いた脂質二分子膜を介した電子移動反応の観察2010

    • Author(s)
      櫻井貴裕、堀田弘樹、角田欣一, ら
    • Organizer
      分析化学討論会(日本分析化学会)
    • Place of Presentation
      島根大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] 光導波路蛍光顕微鏡を用いた平面上に作製したDMPC (Dimyristoyl phosphat idylcholine)二分子膜への蛍光色素の染み込み深さの測定2010

    • Author(s)
      齋藤裕紀、堀田弘樹、角田欣一, ら
    • Organizer
      平成22年分析化学会関東若手交流会(日本分析化学会関東支部)
    • Place of Presentation
      群馬県みどり市
    • Related Report
      2010 Annual Research Report
  • [Presentation] スラブ光導波路分光法を用いたTiO_2表面への色素の吸着状態解析2009

    • Author(s)
      堀田弘樹
    • Organizer
      電気化学秋季大会(電気化学会)
    • Place of Presentation
      東京農工大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 電極型スラブ光導波路を用いた電極表面のpHセンシング2009

    • Author(s)
      堀田弘樹
    • Organizer
      分析化学会年会(日本分析化学会)
    • Place of Presentation
      北海道大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 直線二色性測定用スラブ光導波路分光装置の開発とそれを用いた固液界面への色素の吸着状態解析2009

    • Author(s)
      堀田弘樹
    • Organizer
      ポーラログラフィーおよび電気分析化学討論会(日本ポーラログラフ学会)
    • Place of Presentation
      徳島大学
    • Related Report
      2010 Final Research Report
  • [Presentation] スラブ光導波路分光法を用いたTiO_2表面への色素の吸着状態解析2009

    • Author(s)
      堀田弘樹
    • Organizer
      電気化学秋季大会
    • Place of Presentation
      東京農工大学
    • Related Report
      2009 Annual Research Report
  • [Presentation] 電極型スラブ光導波路を用いた電極表面のpHセンシング2009

    • Author(s)
      堀田弘樹
    • Organizer
      分析化学会年会
    • Place of Presentation
      北海道大学
    • Related Report
      2009 Annual Research Report
  • [Presentation] 直線二色性測定用スラブ光導波路分光装置の開発とそれを用いた固液界面への色素の吸着状態解析2009

    • Author(s)
      堀田弘樹
    • Organizer
      ポーラログラフィーおよび電気分析化学討論会
    • Place of Presentation
      徳島大学
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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