New approach for boron analysis using metal complex detector and its application to redox-controlled boron sensing
| Project/Area Number |
21750082
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Analytical chemistry
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| Research Institution | Konan University |
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Principal Investigator |
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2009: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
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| Keywords | 化学センサー / 定量分析 / 金属錯体 / ホウ素 / 比色定量試薬 / 酸化還元 |
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| Research Abstract |
The colorimetric analysis of boron using organic reagents has some thermodynamic and/or kinetic problems. In this study, a new colorimetric analytical reaction of boron using metal complex detectors was examined. The metal complexes having a diol moiety, which is a reactive site toward boron, react with boric acid with change in the absorption and/or emission spectra, indicating that the proposed analytical reaction of boron using metal complex detector would be applied as an alternative useful colorimetric analysis of boron. This study also provides the further strategy of molecular design of metal complex detectors for a conventional colorimetric analysis of boron in aqueous samples.
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Report
(4 results)
Research Products
(14 results)
