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New approach for boron analysis using metal complex detector and its application to redox-controlled boron sensing

Research Project

Project/Area Number 21750082
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Analytical chemistry
Research InstitutionKonan University

Principal Investigator

IWATSUKI Satoshi  甲南大学, 理工学部, 講師 (80373033)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2009: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywords化学センサー / 定量分析 / 金属錯体 / ホウ素 / 比色定量試薬 / 酸化還元
Research Abstract

The colorimetric analysis of boron using organic reagents has some thermodynamic and/or kinetic problems. In this study, a new colorimetric analytical reaction of boron using metal complex detectors was examined. The metal complexes having a diol moiety, which is a reactive site toward boron, react with boric acid with change in the absorption and/or emission spectra, indicating that the proposed analytical reaction of boron using metal complex detector would be applied as an alternative useful colorimetric analysis of boron. This study also provides the further strategy of molecular design of metal complex detectors for a conventional colorimetric analysis of boron in aqueous samples.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (14 results)

All 2012 2011 2010 2009

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (11 results)

  • [Journal Article] Higher Reactivity of 3-Pyridinium Boronic Acid Compared to 3-Pyridinium Boronate Ion toward 4-Isopropyltropolone in Acidic Aqueous Solution : Fundamental Reaction Analyses for an Effective Organoboron-Based Chemosensor2012

    • Author(s)
      S. Iwatsuki, Y. Kanamitsu, H. Ohara, E. Watanabe, K. Ishihara
    • Journal Title

      J. Phys. Org. Chem.

      Volume: 25 Issue: 9 Pages: 760-768

    • DOI

      10.1002/poc.2915

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Crystal Structure of Methanesulfonate Salt of 3-(N-Methyl)pyridinium Boronic Acid2011

    • Author(s)
      S. Iwatsuki, Y. Kanamitsu, H. Danjo, K. Ishihara
    • Journal Title

      X-ray Structure Analysis Online

      Volume: 27 Pages: 61-62

    • DOI

      10.2116/xraystruct.27.61

    • NAID

      130004544285

    • ISSN
      1883-3578
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Concentration-Dependent Palladium(II)-Indole Bond Formation in Complexes with a 2N-Donor Ligand Containing an Indole Moiety2011

    • Author(s)
      S. Iwatsuki, T. Suzuki, T. Yajima, T. Shiraiwa, O. Yamauchi, Y. Shimazaki
    • Journal Title

      Synthesis, Characterization, and Reaction Analysis, Inorg. Chim. Acta

      Volume: 377 Issue: 1 Pages: 111-119

    • DOI

      10.1016/j.ica.2011.07.045

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Presentation] ピリジルボロン酸誘導体とヒノキチオールとの錯形成反応の速度論的研究2011

    • Author(s)
      岩月聡史, 大原秀隆, 金光優希, 渡邉永祐, 檀上博史, 石原浩二
    • Organizer
      第34回溶液化学シンポジウム
    • Place of Presentation
      名古屋大学(愛知)
    • Year and Date
      2011-11-16
    • Related Report
      2011 Final Research Report
  • [Presentation] 3-トリフルオロメチルフェニルボロン酸とD-フルクトースの反応性に関する速度論的研究2011

    • Author(s)
      田中亜純, 岩月聡史, 稲毛正彦, 高木秀夫, 石原浩二
    • Place of Presentation
      名古屋大学(愛知)
    • Year and Date
      2011-11-16
    • Related Report
      2011 Final Research Report
  • [Presentation] ピリジルボロン酸誘導体とヒノキチオールとの錯形成反応の速度論的研究2011

    • Author(s)
      岩月聡史、大原秀隆、金光優希、渡邉永祐、檀上博史、石原浩二
    • Organizer
      第34回溶液化学シンポジウム
    • Place of Presentation
      名古屋大学(愛知県)
    • Year and Date
      2011-11-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] 3-トリフルオロメチルフェニルボロン酸とD-フルクトースの反応性に関する速度論的研究2011

    • Author(s)
      田中亜純、岩月聡史、稲毛正彦、高木秀夫、石原浩二
    • Organizer
      第34回溶液化学シンポジウム
    • Place of Presentation
      名古屋大学(愛知県)
    • Year and Date
      2011-11-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] ピリジン窒素上に置換基を導入したピリジニウムボロン酸の酸解離特性と糖類との錯形成反応2011

    • Author(s)
      大原秀隆, 金光優希, 檀上博史, 茶山健二, 石原浩二, 岩月聡史
    • Organizer
      日本分析化学会第60年
    • Place of Presentation
      名古屋大学(愛知)
    • Year and Date
      2011-09-14
    • Related Report
      2011 Final Research Report
  • [Presentation] フェニルボロン酸とD-フルクトースの反応に関する速度論的研究2011

    • Author(s)
      田中亜純, 佐藤祐太郎, 岩月聡史, 稲毛正彦, 高木秀夫, 石原浩二
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学(愛知)
    • Year and Date
      2011-09-14
    • Related Report
      2011 Final Research Report
  • [Presentation] ピリジン窒素上に置換基を導入したピリジニウムボロン酸の酸解離特性と糖類との錯形成反応2011

    • Author(s)
      大原秀隆、金光優希、檀上博史、茶山健二、石原浩二、岩月聡史
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Year and Date
      2011-09-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] フェニルボロン酸とD-フルクトースの反応に関する速度論的研究2011

    • Author(s)
      田中亜純、佐藤祐太郎、岩月聡史、稲毛正彦、高木秀夫、石原浩二
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学(愛知県)
    • Year and Date
      2011-09-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] Optical sensing of boron using metal complexes with 3, 3'-dihydroxy-2, 2'-bipyridine and 5, 6-dihydroxy-1, 10-phenanthroline2010

    • Author(s)
      S. Iwatsuki, K. Chayama, M. Inamo, H. D. Takagi, K. Ishihara
    • Organizer
      2010環太平洋国際化学会議(PACIFICHEM2010)
    • Place of Presentation
      Honolulu(USA)
    • Year and Date
      2010-12-16
    • Related Report
      2011 Final Research Report
  • [Presentation] Optical sensing of boron using metal complexes with 3,3'-dihydroxy-2,2'-bipyridine and 5,6-dihydmxy-1,10-phenanthroline2010

    • Author(s)
      S.Iwatsuki, K.Chayama, M.Inamo, H.D.Takagi, K.Ishihara
    • Organizer
      2010環太平洋国際化学会議(PACIFICHEM2010)
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2010-12-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] 特異なボロン酸の反応性と分析化学への展開2009

    • Author(s)
      金光優希, 茶山健二, 岩月聡史
    • Organizer
      東京コンファレンス2009
    • Place of Presentation
      幕張メッセ(千葉)
    • Year and Date
      2009-09-04
    • Related Report
      2011 Final Research Report 2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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