| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2009: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Research Abstract |
We have developed a variety of novel and atom economical asymmetric carbon-carbon forming reactions catalyzed by cationic chiral palladium complex as a Lewis acid. We demonstrated that the chiral Pd-complexes are 1) air- and moisture-stable, 2) easily synthesized, and 3) catalytically very active (up to 0.01mol%) with high yield and enantioselectivity.
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