Development of Efficient Synthetic Methodologies Based on Direct Functionalization
| Project/Area Number |
21750099
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | The University of Tokyo (2010)
Kyoto University (2009) |
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Principal Investigator |
TAKITA Ryo The University of Tokyo, 大学院・薬学系研究科, 助教 (50452321)
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| Project Period (FY) |
2009 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 触媒反応 / 直接的アリール化反応 / パラジウム / チオフェン / 直接的重合反応 / パラジウム触媒 / ポリチオフェン / ホスフィン配位 |
|---|
| Research Abstract |
The efficient methodologies based on direct arylation to provide π-conjugate materials has been investigated. A simple catalyst system using Pd(OAc)_2 and 1,10-phenanthroline enables the efficient direct arylation of heteroarenes. Furthermore, the practical dehydrogenative polycondensation of 2-bromothiophenes based on direct arylation method has been developed for the first time to afford polythiophenes with high molecular weight and regioregularity.
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Report
(3 results)
Research Products
(21 results)
