Development of Novel Transformations via Cleavage of Inactive Bonds using Group 7 Transition Metal Catalysts
Project/Area Number |
21750103
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Single-year Grants |
Research Field |
Synthetic chemistry
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Research Institution | Okayama University |
Principal Investigator |
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Project Period (FY) |
2009 – 2011
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Project Status |
Completed (Fiscal Year 2011)
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Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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Keywords | レニウム / マンガン / C-H結合活性化 / C-C結合切断 / 挿入 / 付加 / 位置選択的 / 触媒反応 |
Research Abstract |
We focused on group 7 transition metal compounds, such as rhenium and manganese complexes, and carried out investigations to develop novel and efficient transformations using such complexes as catalysts. As a result, we have succeeded in the development of transformations via the cleavage of C-H or C-C bond, which forms skeletons of organic molecules and is difficult to be cleaved. In addition, we also developed regioselective cycloaddition reactions.
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Report
(4 results)
Research Products
(123 results)
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[Presentation] Indium-Catalyzed Retro-Claisen Rearrangement2010
Author(s)
Shun-ichi Yamamoto, Atsushi Kawata, Taihei Noborio, Takashi Matsuki, Kazumi Takata, Yoichiro Kuninobu, and Kazuhiko Takai
Organizer
The International Chemical Congress of Pacific Basin Societies(Pacifichem 2010)
Place of Presentation
Honolulu, Hawaii, USA
Related Report
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[Presentation] Indium-Catalyzed Retro-Claisen Rearrangement2010
Author(s)
Shun-ichi Yamamoto, Atsushi Kawata, Taihei Noborio, Takashi Matsuki, Kazumi Takata, Yoichiro Kuninobu, Kazuhiko
Organizer
The International Chemical Congress of Pacific Basin Societies (Pacifichem 2010)
Place of Presentation
Honolulu (USA)
Related Report
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