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Reaction of Guanidinodiazonium Salt

Research Project

Project/Area Number 21750105
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Synthetic chemistry
Research InstitutionKyushu Institute of Technology

Principal Investigator

KITAMURA Mitsuru  Kyushu Institute of Technology, 大学院・工学研究院, 准教授 (10313199)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2009: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsジアゾ / アジド / ジアゾニウム塩 / アミノ化 / ジアゾナフトキノン / ジアゾ移動 / アジド移動 / ジアゾ化合物 / ジアゾ移動反応 / 酸アジド
Research Abstract

Guanidino diazonium salt having Cl^- as a counter anion was prepared by the reaction of 2-chloro-1,3-dimethylimidazolinium chloride (DMC) and sodium azide. The corresponding phosphate, was isolated as a crystal, and was found to be stable and safe reagent. Guanidino diazonium salts were found to have the abilities of diazo and azide transfer to various nucleophilic reagent.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (19 results)

All 2011 2010 2009 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (7 results) Remarks (1 results)

  • [Journal Article] Synthesis of alpha, alpha-diaryl-acetamides from benzyl aryl ketones using 2-azido-1,3-dimethylimidazolinium hexafluorophosphate2011

    • Author(s)
      Kitamura, M.; Miyagawa, S.; Okauchi, T.
    • Journal Title

      Tetrahedron Lett. 52

      Pages: 3158-3161

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Cross-Coupling Reactionsof 2-Diazonaphthoquinones with Arylboronic Acids2011

    • Author(s)
      Kitamura, M.; Sakata, R.; Okauchi, T.
    • Journal Title

      Tetrahedron Lett. 52

      Pages: 1931-1933

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] 2-Azido-1,3-dimethylimidazolinium Salts : Efficient Diazo-Transfer Reagents for 1,3-Dicarbonyl Compounds2011

    • Author(s)
      Kitamura, M.; Tashiro, N.; Miyagawa, S.Okauchi, T.
    • Journal Title

      Synthesis

      Pages: 1037-1044

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Direct Synthesis of Organic Azides from Primary Amines with 2-Azido-1,3-Dimethylimidazolinium Hexafluorophosphate2011

    • Author(s)
      Kitamura, M.; Yano, M.; Tashiro, N.; Miyagawa, S.; Sando, M.; Okauchi, T.
    • Journal Title

      Eur.J.Org.Chem.

      Pages: 458-462

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Direct Synthesis of Organic Azides from Primary Amines with 2-Azido-1,3-Dimethylimidazolinium Hexafluorophosphate2011

    • Author(s)
      Kitamura, M.; Yano, M.; Tashiro N.; Miyagawa, S.; Sando, M.; Okauchi, T.
    • Journal Title

      Eur.J.Org.Chem.

      Pages: 458-462

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Diazonaphthoquinones from Naphthols by Diazo-transfer Reaction with 2-Azido-1,3-dimethylimidazolinium Chloride2010

    • Author(s)
      Kitamura, M.; Tashiro, N.; Sakata, R.; Okauchi, T.
    • Journal Title

      Synlett

      Pages: 2503-2505

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Direct Synthesis of Acyl Azides from Carboxylic Acids Using 2-Azido-1,3-Dimethylimidazolinium Chloride2010

    • Author(s)
      Kitamura, M.; Tashiro, N.; Takamoto, Y.; Okauchi, T.
    • Journal Title

      Chem.Lett.

      Pages: 732-733

    • NAID

      10027182726

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Diazonaphthoquinones from Naphthols by Diazo-transfer Reaction with 2-Azido-1, 3-dimethylimidazolinium Chloride2010

    • Author(s)
      Kitamura, M.; Tashiro, N.; Sakata, R.; Okauchi, T.
    • Journal Title

      Synlett

      Pages: 2503-2505

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct Synthesis of Acyl Azides from Carboxylic Acids Using 2-Azido-1, 3-Dimethylimidazolinium Chloride2010

    • Author(s)
      Kitamura, M.; Tashiro, N.; Takamoto, Y.; Okauchi, T.
    • Journal Title

      Chem.Lett.

      Volume: 39 Pages: 732-733

    • NAID

      10027182726

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Azido-1,3-dimethylimidazolinium Chloride : An Efficient Diazo Transfer Reagent for 1,3-Dicarbonyl Compounds2009

    • Author(s)
      Kitamura, M.; Tashiro, N; Okauchi, T.
    • Journal Title

      Synlett

      Pages: 2943-2944

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] 2-Azido-1, 3-dimethylimidazolinium Chloride : An Efficient Diazo-Transfer Reagent for 1, 3-Dicarbonyl Compounds2009

    • Author(s)
      M.Kitamura, N.Tashiro, T.Okauchi
    • Journal Title

      Synlett

      Pages: 2943-2944

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] グアニジノジアゾニウム塩を用いるジアゾ化反応2010

    • Author(s)
      北村充・田代憲史・佐嘉田理恵・宮川智史・岡内辰夫
    • Organizer
      第40回複素環化学討論会
    • Place of Presentation
      仙台市民会館(仙台)
    • Year and Date
      2010-10-16
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] グアニジノジアゾニウム塩を用いるジアゾ化反応の開発2010

    • Author(s)
      北村充
    • Organizer
      第47回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場(北九州)
    • Year and Date
      2010-07-10
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] グアニジノジアゾニウム塩の合成と反応(1)-カルボニル化合物との反応2010

    • Author(s)
      宮川智史・田代憲史・佐嘉田理恵・岡内辰夫・北村充
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪)
    • Year and Date
      2010-03-27
    • Related Report
      2010 Final Research Report
  • [Presentation] グアニジノジアゾニウム塩の合成と反応(2)-第一級アミンとの反応2010

    • Author(s)
      矢野匡一・三道光喜・田代憲史・岡内辰夫・北村充
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪)
    • Year and Date
      2010-03-27
    • Related Report
      2010 Final Research Report
  • [Presentation] グアニジノジアゾニウム塩の合成と反応(1)-カルボニル化合物との反応2010

    • Author(s)
      宮川智史・田代憲史・佐嘉田理恵・岡内辰夫・北村充
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] グアニジノジアゾニウム塩の合成と反応(2)-第一級アミンとの反応2010

    • Author(s)
      矢野匡一・三道光喜・田代憲史・岡内辰夫・北村充
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] Pd触媒を用いるオキシム誘導体からのイソインドール類の合成2010

    • Author(s)
      森安洋平・岡内辰夫・北村充
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Remarks] ホームページ

    • URL

      http://www.che.kyutech.ac.jp/chem27/chem27.html

    • Related Report
      2010 Final Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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