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Fabrication of novel nanotube-based hybrid materials and development of characterization of their structure and properties

Research Project

Project/Area Number 21750142
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionNagoya University

Principal Investigator

KITAURA Ryo  Nagoya University, 理学研究科, 准教授 (50394903)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2009: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsナノチューブ / 透過型電子顕微鏡 / デバイス特性 / カーボンナノチューブ / 電子線回折 / 電気二重層トランジスタ / 磁気物性 / ナノワイヤー / 電気伝導度
Research Abstract

Atomic nanowires have been synthesized using ultra-thin 1-dimensional nanospace of carbon nanotubes. One of the key to achieve the formation of atomic wire inside nanotube nanospace is to use high quality and high purity carbon nanotubes synthesized by laser vaporization and chemical vapor deposition method. Synthesized atomic wires have a diameter of one atom thick at thinnest, which is the world thinnest wires among ever synthesized. In the case of atomic wires whose diameter is two-atom thick, I have found that the reversible structural transformation from zigzag structure and helical structure occurs during TEM observations at room temperature. In addition to synthesis of novel nanocarbon materials, I have developed characterization technique using micro-gap electrodes with channel penetrating though the substrate to elucidate correlation between structure and properties of atomic wires in detail. Using this method, atomic structure characterization using electron microscopy and device characteristics measurement on individual and specific nanotubes have been successfully carried out.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (26 results)

All 2011 2010 2009 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (15 results) Remarks (2 results)

  • [Journal Article] Templating rare-earth hybridization via ultrahigh vacuum annealing of ErCl3 nanowires inside carbon nanotubes2011

    • Author(s)
      P.Ayala, R.Kitaura, R.Nakanishi, H.Shiozawa, D.Ogawa, P.Hoffmann, H.Shinohara, T.Pichler
    • Journal Title

      Physical Review B 83

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Irregular Modulation of Density-of-States of Nano-Peapods Encapsulating Gd@C-822011

    • Author(s)
      K.Ohashi, N.Imazu, R.Kitaura, H.Shinohara
    • Journal Title

      Metallofullerenes 115

      Pages: 3968-3972

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Templating rare-earth hybridization via ultrahigh vacuum annealing of ErCl3 nanowires inside carbon nanotubes2011

    • Author(s)
      Ayala, P.
    • Journal Title

      Physical Review B

      Volume: 8 Pages: 85407-85407

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Irregular Modulation of Density-of-States of Nano-Peapods Encapsulating Gd@C-82 Metallofullerenes2011

    • Author(s)
      Ohashi, K.
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 115 Pages: 3968-3972

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of single-wall carbon nanotubes within the channels of a mesoporous material by catalyst-supported chemical vapor deposition2009

    • Author(s)
      K.Kobayashi, R.Kitaura, et. al.
    • Journal Title

      Carbon 47

      Pages: 722-730

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-Yield Synthesis of Ultrathin Metal Nanowires in Carbon Nanotubes2009

    • Author(s)
      R.Kitaura, et. al.
    • Journal Title

      Angew. Chem. Int. Ed. 48

      Pages: 8298-8302

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Morphology and Melting Behavior of Ionic Liquids inside Single-Walled Carbon Nanotubes2009

    • Author(s)
      S.Chen, et. al.
    • Journal Title

      J.Am. Chem. Soc. 131

      Pages: 14850-14856

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chromatographic Length Separation and Photoluminescence Study on DNA-Wrapped Single-Wall and Double-Wall Carbon Nanotubes2009

    • Author(s)
      Y.Asada, et. al.
    • Journal Title

      J.NanoMat.

      Pages: 257892-257892

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] STM TIP-CURRENT-INDUCED POLYMERIZATION OF C-60, Ce-2@C-80 AND Lu-2@C-762009

    • Author(s)
      K.Ohashi, et. al.
    • Journal Title

      NANO 4

      Pages: 281-287

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 新規カーボンナノチューブハイブリッド物質の創製2011

    • Organizer
      カーボンナノ材料研究会
    • Year and Date
      2011-03-04
    • Related Report
      2010 Final Research Report
  • [Presentation] 新規カーボンナノチューブハイブリッド物質の創製2011

    • Author(s)
      北浦良
    • Organizer
      カーボンナノ材料研究会
    • Place of Presentation
      大阪化学技術センター
    • Year and Date
      2011-03-04
    • Related Report
      2010 Annual Research Report
  • [Presentation] 新規ハイブリッドナノカーボン物質の創製と機能探索2010

    • Author(s)
      北浦良
    • Organizer
      分子アンサンブル2010
    • Year and Date
      2010-11-17
    • Related Report
      2010 Final Research Report
  • [Presentation] 新規ハイブリッドカーボン物質の創製と機能探索2010

    • Author(s)
      北浦良
    • Organizer
      分子アンサンブル2010
    • Place of Presentation
      理化学研究所
    • Year and Date
      2010-11-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of metal-nanowire@SWCNTs and their physical properties2010

    • Author(s)
      Dea Heon Choi
    • Organizer
      A3 symposium on emerging materials : Nanocarbons and nanowires for energy
    • Place of Presentation
      Chonju, South Korea
    • Year and Date
      2010-11-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] 放射光X線回折を用いたナノカーボン材料の構造研究2010

    • Organizer
      SPring-8コンファレンス
    • Year and Date
      2010-11-04
    • Related Report
      2010 Final Research Report
  • [Presentation] 放射光X線回折を用いたナノカーボン材料の構造研究2010

    • Author(s)
      北浦良
    • Organizer
      SPring-8コンファレンス
    • Place of Presentation
      東京ステーションコンファレンス
    • Year and Date
      2010-11-04
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of one-dimensional coordination nanowires in nano-space of carbon nanotubes2010

    • Author(s)
      R.Kitaura
    • Organizer
      第60回記念錯体化学OSAKA国際会議
    • Year and Date
      2010-09-28
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Fabrication and characterization of novel nanotube-based hybrid materials2010

    • Author(s)
      R.Kitaura
    • Organizer
      the 1^<st> china-japan young chemist forum
    • Year and Date
      2010-06-20
    • Related Report
      2010 Final Research Report
  • [Presentation] Fabrication and characterization of novel nanotube-based hybrid materials2010

    • Author(s)
      R.Kitaura
    • Organizer
      The 1^<st> China-Japan Young Chemist Forum
    • Place of Presentation
      厦門大学(中国)
    • Year and Date
      2010-06-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] Fabrication of novel low-dimensional nanomaterials using carbon nanotube nanoreactors2010

    • Author(s)
      R.Kitaura, H.Shinohara
    • Organizer
      XXIVth International WInterschool on Electronic Properties of Novel Materials
    • Place of Presentation
      Hotal Sonnalp(Kirchberg Tirol Austria)
    • Year and Date
      2010-03-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] 制限カーボンナノ空間を用いた物質創製と機能探索2010

    • Author(s)
      北浦良
    • Organizer
      分子研研究会
    • Place of Presentation
      分子科学研究所
    • Year and Date
      2010-02-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] カーボンナノチューブをベースとした新規ナノ物質の創製と評価2009

    • Author(s)
      北浦良
    • Organizer
      日本化学会東海支部 地区講演会
    • Place of Presentation
      三重大学
    • Year and Date
      2009-11-06
    • Related Report
      2009 Annual Research Report
  • [Presentation] Formation and characterization of low-dimensional nanomaterials using 1D-space of Carbon Nanotubes2009

    • Author(s)
      R.Kitaura, et. al.
    • Organizer
      International Symposium on Carbon Nanotube Nanoelectronics
    • Place of Presentation
      ホテル大観荘(宮城県)
    • Year and Date
      2009-06-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] カーボンナノ空間を用いた物質創製2009

    • Author(s)
      北浦良
    • Organizer
      日本化学会
    • Place of Presentation
      日本大学
    • Year and Date
      2009-03-27
    • Related Report
      2009 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://nano.chem.nagoya-u.ac.jp/japanese/

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://nano.chem.nagoya-u.ac.jp/japanese/

    • Related Report
      2010 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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