| Project/Area Number |
21750150
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Functional materials chemistry
|
|---|
| Research Institution | Osaka Prefecture University |
|---|
Principal Investigator |
FUJIWARA Hideki Osaka Prefecture University, 理学系研究科, 准教授 (70290898)
|
|---|
| Project Period (FY) |
2009 – 2010
|
| Project Status |
Completed (Fiscal Year 2010)
|
| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2009: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
|
|---|
| Keywords | 有機伝導体 / 磁性伝導体 / 磁気的性質 / 電気伝導性 / π-d相互作用 / 結晶構造 / 遷移金属錯体 |
|---|
| Research Abstract |
We prepared new π-d magnetic conductors using the TTF-BTA hybrid molecules 1 and transition metal complexes M(hfac)_2 (M=Cu, Co, Ni, Mn) to realize magnetic interactions between the π-conduction electrons and the localized d-spins of the transition metals. We cleared the crystal structure and physical properties of the 1_2M(hfac)_2 (M=Cu, Co, Ni, Mn) complexes. Furthermore, we also prepared a cation radical salts based on new transition metal complex, 1_2Cu(ReO_4)_2 and cleared its crystal structure and magnetic/conducting properties.
|
