Development of new magnetic conductors with higher magnetic transition temperatures using Benzothiazole-TTF hybrid molecules
| Project/Area Number |
21750150
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Functional materials chemistry
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| Research Institution | Osaka Prefecture University |
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Principal Investigator |
FUJIWARA Hideki Osaka Prefecture University, 理学系研究科, 准教授 (70290898)
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| Project Period (FY) |
2009 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2009: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Keywords | 有機伝導体 / 磁性伝導体 / 磁気的性質 / 電気伝導性 / π-d相互作用 / 結晶構造 / 遷移金属錯体 |
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| Research Abstract |
We prepared new π-d magnetic conductors using the TTF-BTA hybrid molecules 1 and transition metal complexes M(hfac)_2 (M=Cu, Co, Ni, Mn) to realize magnetic interactions between the π-conduction electrons and the localized d-spins of the transition metals. We cleared the crystal structure and physical properties of the 1_2M(hfac)_2 (M=Cu, Co, Ni, Mn) complexes. Furthermore, we also prepared a cation radical salts based on new transition metal complex, 1_2Cu(ReO_4)_2 and cleared its crystal structure and magnetic/conducting properties.
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Report
(3 results)
Research Products
(74 results)
