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Highly Selective Transformation by Gold Clusters by Using Oxygen and Hydrogen

Research Project

Project/Area Number 21750160
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Environmental chemistry
Research InstitutionTokyo Metropolitan University

Principal Investigator

ISHIDA Tamao  Tokyo Metropolitan University, 都市環境科学研究科, 助教 (90444942)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsグリーンケミストリー / 金ナノ粒子 / 金触媒 / 金クラスター / アンモ酸化 / アルカン酸化 / メソポーラス有機シリカ / ワンポット反応 / 二級アミン / N-アルキル化
Research Abstract

We investigated the catalytic properties of gold nanoparticles deposited on various kinds of supports for solvent-free aerobic oxidation of alkane, oxidation of amine, hydrogenation of imine, and the N-alkylation of primary amine to produce secondary amine. We found that supported gold catalysts exhibited high catalytic activity and product selectivity when gold nanoparticles and clusters were deposited on suitable supports for each reactions.
We also found that metal oxide without gold could catalyze the ammoxidation of alcohol to yield nitrile with high selectivity.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (56 results)

All 2011 2010 2009 Other

All Journal Article (12 results) (of which Peer Reviewed: 11 results) Presentation (37 results) Book (4 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Synergistic Catalysis of Au@Ag Core-Shell Nanoparticles on Metal-Organic Framework2011

    • Author(s)
      H.-L.Jiang, T.Akita, T.Ishida, M.Haruta, Q.Xu
    • Journal Title

      J.Am.Chem.Soc. 133

      Pages: 1304-1304

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synergistic Catalysis of Au@Ag Core-Shell Nanoparticles Stabilized on Metal-Organic Framework2011

    • Author(s)
      H.-L.Jiang, T.Akita, T.Ishida, M.Haruta, Q.Xu
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 133 Pages: 1304-1305

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Deposition of Gold Clusters onto Porous Coordination Polymers by Solid Grinding2010

    • Author(s)
      T.Ishida, N.Kawakita, T.Akita, M.Haruta
    • Journal Title

      Stud.Surf.Sci.Catal. 175

      Pages: 839-842

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Aerobic Oxidation of Glucose over Gold Nanoparticles Deposited on Cellulose2010

    • Author(s)
      T.Ishida, H.Watanabe, T.Bebeko, T.Akita, M.Haruta
    • Journal Title

      Appl.Catal.A : Gen. 377

      Pages: 42-46

    • Related Report
      2010 Final Research Report 2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Deposition of Gold Clusters onto Porous Coordination Polymers by Solid Grinding2010

    • Author(s)
      T.Ishida, N.Kawakita, T.Akita, M.Haruta
    • Journal Title

      Stud.Surf.Sci.Catal.

      Volume: 175 Pages: 839-842

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 担持金ナノ粒子の調製と応用2010

    • Author(s)
      武井孝, 石田玉青, 春田正毅
    • Journal Title

      粉体技術

      Volume: 2 Pages: 44-51

    • Related Report
      2010 Annual Research Report
  • [Journal Article] N-Formylation of Amines via the Aerobic Oxidation of Amines via the Aerobic Oxidation of Methanol over Supported Gold Nanoparticles2009

    • Author(s)
      T.Ishida, M.Haruta
    • Journal Title

      ChemSusChem 2

      Pages: 538-541

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] One-Pot N-Alkylation of Primary Amines to Secondary Amines by Gold Clusters Supported on Porous Coordination Polymers2009

    • Author(s)
      T.Ishida, N.Kawakita, T.Akita, M.Haruta
    • Journal Title

      Gold Bull. 42

      Pages: 267-274

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] One-Pot Synthesisi of Indoles and Aniine Derivatives from Nitroarenes under Hydrogenation Condition with Supported Gold Nanoparticles2009

    • Author(s)
      Y.Yamane, X.Liu, A.Hamasaki, T.Ishida, M.Haruta, T.Yokoyama, M.Tokunaga
    • Journal Title

      Org.Lett. 11

      Pages: 5162-5165

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Poly(arylene-ethynylene)s Containing Dithia[3.3]metaphane2009

    • Author(s)
      Y.Morisaki, T.Ishida, Y.Chujo
    • Journal Title

      C.R.Chimie 12

      Pages: 332-340

    • NAID

      120002317424

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] N-Formylation of Amines via the Aerobic Oxidation of Methanol over Supported Gold Nanoparticles2009

    • Author(s)
      T.Ishida, M.Haruta
    • Journal Title

      ChemSusChem 2

      Pages: 538-541

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One-pot N-Alkylation of Primary Amines to Secondary Amines by Gold Clusters Supported on Porous Coordination Polymers2009

    • Author(s)
      T.Ishida, N.Kawakita, T.Akita, M.Haruta
    • Journal Title

      Gold Bull. 42

      Pages: 267-274

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 酸化物及び高分子担持金触媒を用いたN-アルキル化による2級アミンの合成2010

    • Author(s)
      石田玉青, 高村玲那, 河北典子, 秋田知樹, 武井孝, 春田正毅
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      山梨大学
    • Year and Date
      2010-09-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] 金触媒によるアルカリ無添加での1-オクタノールからオクタン酸への直接酸化2010

    • Author(s)
      荻原裕一郎, 石田玉青, 春田正毅
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      山梨大学
    • Year and Date
      2010-09-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] 金属酸化物触媒を用いたベンジルアルコールのアンモ酸化反応によるベンゾニトリル合成2010

    • Author(s)
      渡部寛人, 石田玉青, 春田正毅
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      山梨大学
    • Year and Date
      2010-09-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] One-pot N-Alkylation of Primary Amines to Secondary Amines by Gold Clusters Supported on Porous Coordination Polymers2010

    • Author(s)
      N.Kawakita, T.Ishida, T.Akita, M.Haruta
    • Organizer
      TOCAT6/APCAT5
    • Place of Presentation
      札幌国際会議場
    • Year and Date
      2010-07-12
    • Related Report
      2010 Annual Research Report
  • [Presentation] 金属酸化物触媒を用いたベンジルアルコールのアンモ酸化反応によるベンゾニトリル合成2010

    • Author(s)
      渡部寛人, 石田玉青, 春田正毅
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      山梨大学甲府キャンパス
    • Related Report
      2010 Final Research Report
  • [Presentation] 金触媒によるアルカリ無添加での1-オクタノールからオクタン酸への直接酸化2010

    • Author(s)
      荻原裕一郎, 石田玉青, 春田正毅
    • Organizer
      回触媒討論会
    • Place of Presentation
      山梨大学甲府キャンパス
    • Related Report
      2010 Final Research Report
  • [Presentation] 酸化物及び高分子担持金触媒を用いたN-アルキル化による2級アミンの合成2010

    • Author(s)
      石田玉青, 高村玲那, 河北典子, 秋田知樹, 武井孝, 春田正毅
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      山梨大学甲府キャンパス
    • Related Report
      2010 Final Research Report
  • [Presentation] 金属ナノ粒子を包含した多孔性共役系高分子の合成とイミン水素化触媒活性2010

    • Author(s)
      大沼雄太, 石田玉青, 秋田知樹, 春田正毅
    • Organizer
      日本化学会第4回関東支部大会
    • Place of Presentation
      筑波大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 金微粒子凝集レーザーアブレーションによる金クラスター負イオンの生成とイオンビーム蓄積2010

    • Author(s)
      座間優, 松本淳, 城丸春夫, 阿知波洋次, 間嶋拓也, 田沼肇, 東俊行, 石田玉青, 春田正毅
    • Organizer
      原子衝突研究協会第35回年会
    • Place of Presentation
      奈良女子大学
    • Related Report
      2010 Final Research Report
  • [Presentation] Direct Aerobic Oxidation of 1-Octanol to Octanoic Acid over Supported Gold Nanoparticles under Base-Free2010

    • Author(s)
      T.Ishida, Y.Ogihara, T.Akita, M.Haruta
    • Organizer
      9th France-Japan Workshop on Nanomaterial
    • Place of Presentation
      France
    • Related Report
      2010 Final Research Report
  • [Presentation] Deposition of Gold Nanoparticles on Carbon Nanohorn and Their Catalytic Activity for Glucose Oxidation2010

    • Author(s)
      J.Yamada, T.Ishida, T.Takei, R.Yuge, T.Yoshitake, M.Yudasaka, S.Iijima, M.Haruta
    • Organizer
      International Conference on Nanoscopic Colloid and Surface Science 35th Anniversary of Division of Colloid and Surface Chemistry
    • Place of Presentation
      Chiba
    • Related Report
      2010 Final Research Report
  • [Presentation] One-pot N-Alkylation of Primary Amines to Secondary Amines by Gold Clusters Supported on Porous Coordination Polymers2010

    • Author(s)
      N.Kawakita, T.Ishida, T.Akita, M.Haruta
    • Organizer
      TOCAT6/APCAT5
    • Place of Presentation
      Sapporo.
    • Related Report
      2010 Final Research Report
  • [Presentation] Gold Nanoparticles Deposited on Periodic Mesoporous Organosilicaas for the Solventless Aerobic Oxidation of Teralin2010

    • Author(s)
      M.Tamakake, T.Ishida, Y.Goto, T.Tani, S, Inagaki, M.Haruta
    • Organizer
      TOCAT6/APCAT5
    • Place of Presentation
      Sapporo
    • Related Report
      2010 Final Research Report
  • [Presentation] Ammoxidation of Benzylalcohol to Benzonitrile in Liquid Phase over Transition Metal Oxides2010

    • Author(s)
      H.Watanabe, T.Ishida, M. Haruta
    • Organizer
      Inaugural International Conferences on Molecular & Functional Catalysis(ICMF-1)
    • Place of Presentation
      Singapore
    • Related Report
      2010 Final Research Report
  • [Presentation] Selective Oxidation of 1-Octanol to 1-Octanoic Acid over Gold Catalysts in the Absence of Bases2010

    • Author(s)
      Y.Ogihara, T.Akita, T.Ishida, M.Haruta
    • Organizer
      Inaugural International Conferences on Molecular & Functional Catalysis(ICMF-1)
    • Place of Presentation
      Singapore
    • Related Report
      2010 Final Research Report
  • [Presentation] Deposition of Gold Clusters onto Porous Coordination Polymers by Solid Grinding2010

    • Author(s)
      T.Ishida, N.Kawakita, T.Akita, M.Haruta
    • Organizer
      PREPA10
    • Place of Presentation
      Belgium
    • Related Report
      2010 Final Research Report
  • [Presentation] 金ナノ粒子触媒を用いた1級アミンのN-アルキル化による2級アミンの選択的合成2010

    • Author(s)
      高村玲那, 石田玉青, 秋田知樹, 春田正毅
    • Organizer
      第105回触媒討論会
    • Place of Presentation
      京都テルサ
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] 酸化タングステン担持金触媒によるニトロベンゼンのアニリンへの水素化2010

    • Author(s)
      大橋弘範, 石田玉青, 武井孝, 春田正毅
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 多孔性配位高分子担持金クラスター触媒を用いた1級アミンから2級アミンのone-pot合成2009

    • Author(s)
      石田玉青, 河北典子, 秋田知樹, 春田正毅
    • Organizer
      第104回触媒討論会
    • Place of Presentation
      宮崎大学
    • Year and Date
      2009-09-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] Aerobic Oxidation of Glucose to Gluconic Acid over Supported Gold Clusters2009

    • Author(s)
      石田玉青, 木下直人, 大勝裕子, 秋田知樹, 春田正毅
    • Organizer
      The 4th International Conference on Green and Sustainable Chemistry (GSC-4) & the 2nd Asian-Oceanian Conference on Green and Sustainable Chemistry (AOC-2)
    • Place of Presentation
      中国・北京Jinhua Resort & Convention Center
    • Year and Date
      2009-08-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] Deposition of Au Clusters on Porous Coordination Polymers for the Oxidation of Alcohols and Amines2009

    • Author(s)
      石田玉青, 河北典子, 秋田知樹, 春田正毅
    • Organizer
      5th International Conference on Gold Science, Technology, and its Applicatons (GOLD2009)
    • Place of Presentation
      ドイツ・ハイデルベルグ大学
    • Year and Date
      2009-07-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] 配位高分子担持金クラスターの触媒活性2009

    • Author(s)
      石田玉青, 河北典子, 秋田知樹, 春田正毅
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2009-05-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] 多孔性配位高分子に担持した金クラスターによるアミンの酸化及びイミンの水素化2009

    • Author(s)
      河北典子, 石田玉青, 秋田知樹, 春田正毅
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2009-05-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] メソポーラス有機シリカハイブリッドへの金ナノ粒子の担持とアルコール酸化活性2009

    • Author(s)
      玉懸未久歩, 石田玉青, 後藤康友, 谷孝夫, 稲垣伸二, 春田正毅
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2009-05-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 金ナノ粒子を用いた触媒反応-環境負荷の低減に向けて-2009

    • Author(s)
      石田玉青, 春田正毅
    • Organizer
      東京都立産業技術研究センター平成21年度研究発表会
    • Place of Presentation
      東京都立産業技術研究センター城南支所
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] 配位高分子担持金クラスターの触媒活性2009

    • Author(s)
      石田玉青, 河北典子, 秋田知樹, 春田正毅
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸
    • Related Report
      2010 Final Research Report
  • [Presentation] Deposition of Au Clusters on Porous Coordination Polymers for the Oxidation of Alcohols and Amines2009

    • Author(s)
      T.Ishida, N.Kawakita, T.Akita, M.Haruta
    • Organizer
      GOLD2009, Heidelberg
    • Place of Presentation
      Germany
    • Related Report
      2010 Final Research Report
  • [Presentation] Production of Propylene Glycol from Glycerol over Au Catalysts under Mild Conditions2009

    • Author(s)
      H.Okatsu, M.Horikawa, T.Ishida, T.Takei, M.Haruta
    • Organizer
      The 238th ACS National Meeting
    • Place of Presentation
      Washington D.C., USA
    • Related Report
      2010 Final Research Report
  • [Presentation] 多孔性配位高分子に担持した金クラスター触媒による2級アミンのone-pot合成2009

    • Author(s)
      河北典子, 石田玉青, 秋田知樹, 春田正毅
    • Organizer
      日本化学会第3回関東支部大会
    • Place of Presentation
      早稲田大学
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] メソポーラス有機シリカハイブリッドへの金ナノ粒子の担持と酸化触媒活性2009

    • Author(s)
      玉懸未久歩, 石田玉青, 後藤康友, 谷孝夫, 稲垣伸二, 春田正毅
    • Organizer
      日本化学会第3回関東支部大会
    • Place of Presentation
      早稲田大学
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] 酸性担体に金を担持する有効な3つの調製法2009

    • Author(s)
      大橋弘範, 陰地宏, 本間徹生, 石田玉青, 武井孝, 春田正毅
    • Organizer
      第104回触媒討論会A
    • Place of Presentation
      宮崎大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 多孔性配位高分子担持金クラスター触媒を用いた1級アミンから2級アミンのone-pot合成2009

    • Author(s)
      石田玉青, 河北典子, 秋口知樹, 春田正毅
    • Organizer
      第104回触媒討論会A
    • Place of Presentation
      宮崎大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 金ナノ粒子触媒調製時の燃焼条件と熱還元挙動2009

    • Author(s)
      武井孝, 河北典子, 堀川雅功, 陰地宏, 本間徹生, 大橋弘範, 石田玉青, 春田正毅
    • Organizer
      第45回熱測定討論会
    • Place of Presentation
      首都大学東京
    • Related Report
      2010 Final Research Report
  • [Presentation] 金ナノ粒子触媒を用いたニトロ基の水素化による有機合成反応の開発2009

    • Author(s)
      山根義弘, 濱崎昭行, 劉小浩, 石田玉青, 春田正毅, 徳永信
    • Organizer
      第56回有機金属化学討論会
    • Place of Presentation
      京都
    • Related Report
      2010 Final Research Report
  • [Presentation] 多孔性配位高分子に担持した金クラスターによるアミンの酸化及びイミンの水素化2009

    • Author(s)
      河北典子, 石田玉青, 秋田知樹, 春田正毅
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸
    • Related Report
      2010 Final Research Report
  • [Presentation] メソポーラス有機シリカハイブリッドへの金ナノ粒子の担持とアルコール酸化活性2009

    • Author(s)
      玉懸未久歩, 石田玉青, 後藤康友, 谷孝夫, 稲垣伸二, 春田正毅
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸
    • Related Report
      2010 Final Research Report
  • [Presentation] The 4th International Conference on Green and Sustainable Chernisrtry (GSC-4)2009

    • Author(s)
      T.Ishida, N.Kinoshita, H.Okatsu, T.Akita, M.HarutaAerobic Oxidation of Glucose to Gluconic Acid over Supported Gold Clusters
    • Organizer
      the 2nd Asian-Oceanian Conference on Green and Sustainable Chemisrtry (AOC-2)
    • Place of Presentation
      Beijing, China
    • Related Report
      2010 Final Research Report
  • [Book] 常温で空気をきれいにする金ナノ粒子触媒",新・醐危学の最藤-未来を渤る「化学のカ」-「第1章2,pp.26-35,首都大学東京都市環境学部分子応用化学研究会編2010

    • Publisher
      講談社
    • Related Report
      2010 Final Research Report
  • [Book] 金ナノ粒子触媒",配位空間の化学-最新技術と応用-(北川進監修),第5章「反応」2009

    • Author(s)
      石田玉安青
    • Publisher
      シーエムシー出版
    • Related Report
      2010 Final Research Report
  • [Book] 配位空間の化学-最新技術と応用-(北川進監修),第5章1「金ナノ粒子触媒」2009

    • Author(s)
      石田玉青
    • Total Pages
      345
    • Publisher
      シーエムシー出版
    • Related Report
      2009 Annual Research Report
  • [Book] Prepartion of Nanosized Gold Catalysts and Oxidation at Room Temperature, Novel Concepts in Catalysis and Chemical Reactors(A.Cybulski, A.J.Moulijn, A.Stankiewicz, Eds.)(Wiley-VCH, Weinheim, Chapter 3)

    • Author(s)
      T.Takei, T.Ishida, M.Haruta
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 選択酸化反応用高活性卑金属酸化物触媒2010

    • Inventor(s)
      石田玉青, 春田正毅, 渡部寛人
    • Industrial Property Rights Holder
      首都大学東京
    • Filing Date
      2010-09-04
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 金属被覆粒子の製造方法2010

    • Inventor(s)
      佐々木令晋, 浅子佳延, 石田玉青, 春田正毅
    • Industrial Property Rights Holder
      (株式会社)日本触媒,首都大学東京
    • Filing Date
      2010-09-04
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 選択酸化反応用高活性卑金属酸化物触媒2010

    • Inventor(s)
      石田玉青, 春田正毅, 渡部寛人
    • Industrial Property Rights Holder
      首都大学東京
    • Industrial Property Number
      2010-206129
    • Filing Date
      2010-09-04
    • Related Report
      2010 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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