Highly Selective Transformation by Gold Clusters by Using Oxygen and Hydrogen
| Project/Area Number |
21750160
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Environmental chemistry
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| Research Institution | Tokyo Metropolitan University |
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Principal Investigator |
ISHIDA Tamao Tokyo Metropolitan University, 都市環境科学研究科, 助教 (90444942)
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| Project Period (FY) |
2009 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
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| Keywords | グリーンケミストリー / 金ナノ粒子 / 金触媒 / 金クラスター / アンモ酸化 / アルカン酸化 / メソポーラス有機シリカ / ワンポット反応 / 二級アミン / N-アルキル化 |
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| Research Abstract |
We investigated the catalytic properties of gold nanoparticles deposited on various kinds of supports for solvent-free aerobic oxidation of alkane, oxidation of amine, hydrogenation of imine, and the N-alkylation of primary amine to produce secondary amine. We found that supported gold catalysts exhibited high catalytic activity and product selectivity when gold nanoparticles and clusters were deposited on suitable supports for each reactions.
We also found that metal oxide without gold could catalyze the ammoxidation of alcohol to yield nitrile with high selectivity.
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Report
(3 results)
Research Products
(56 results)
