Development of stereoselective hydrogenation method for alkylphenols

• Project/Area Number: 21750161
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Environmental chemistry
• Research Institution: National Institute of Advanced Industrial Science and Technology
• Principal Investigator: HIYOSHI Norihito 独立行政法人産業技術総合研究所, コンパクト化学システム研究センター, 主任研究員 (50415733)
• Project Period (FY): 2009 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000); Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000); Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000); Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000); Fiscal Year 2009: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
• Keywords: 超臨界二酸化炭素 / 水素化反応 / 金属触媒 / 超臨界二酸化炭

Research Abstract

The hydrogenation of alkylphenols was studied using supported metal catalysts and supercritical carbon dioxide solvent with low environmental impact. The yields of the cis-alkylcyclohexanols, important compounds for the production of perfumes, were i

Research Products

• [Journal Article] Chandrashekhar V. Rode、白井誠之、 Effect of Carbon Dioxide Pressure on 4-t-Butylphenol Hydrogenation Activity of Supported Rhodium Catalyst (2013)
  • Author(s): 日吉範人、佐藤修、山口有朋
  • Journal Title: Journal of the Japan Petroleum Institute Volume: 56巻 Pages: 165-170
  • URL: https://www.jstage.jst.go.jp/browse/jpi/-char/ja/
  • Peer Reviewed
• [Journal Article] Effect of Carbon Dioxide Pressure on 4-t-Butylphenol Hydrogenation Activity of Supported Rhodium Catalyst (2013)
  • Author(s): Norihito Hiyoshi
  • Journal Title: Journal of the Japan Petroleum Institute Volume: 56 Pages: 165-170
  • NAID: 10031193397
  • Peer Reviewed
• [Journal Article] Kinetic analysis of 4-isopropylphenol hydrogenation over activated carbon-supported rhodium catalysts in supercritical carbon dioxide solvent (2012)
  • Author(s): 日吉範人、佐藤修、山口有朋、Chandrashekhar V. Rode、白井誠之
  • Journal Title: Green Chemistry Volume: 14巻 Issue: 3 Pages: 633-638
  • DOI: 10.1039/c1gc16038a
  • Peer Reviewed
• [Journal Article] Acetophenone hydrogenation over a Pd catalyst in the presence of H_2O and CO_2 (2011)
  • Author(s): 日吉範人、佐藤修、山口有朋、白井誠之
  • Journal Title: Chemical Communications Volume: 47巻 Issue: 41 Pages: 11546-11548
  • DOI: 10.1039/c1cc13130c
  • Peer Reviewed
• [Presentation] Stereoselective hydrogenation with supported metal catalysts and supercritical carbon dioxide solvent (2010)
  • Author(s): 白井誠之
  • Organizer: PACIFICHEM 2010
  • Place of Presentation: Hawaii Convention Center(ハワイ)
  • Year and Date: 2010-12-18
• [Presentation] Hydrogenation process of 2-tert-butylphenol using supported metal catalysts and supercritical carbon dioxide solvent (2010)
  • Author(s): 日吉範人
  • Organizer: International Workshop on Process Intensification 2010
  • Place of Presentation: 九州大学 (福岡)
  • Year and Date: 2010-12-03
• [Presentation] Hydrogenation process of 2-tert-butylphenol using supported metal catalysts and supercritical carbon dioxide solvent (2010)
  • Author(s): 日吉範人
  • Organizer: International Workshop on Process Intensification 2010
  • Place of Presentation: 九州大学(福岡)
  • Year and Date: 2010-12-03
• [Presentation] 超臨界二酸化炭素溶媒を利用した tert-ブチルフェノールの立体選択的水素化反応 (2009)
  • Author(s): 日吉範人
  • Organizer: 第104回触媒討論会
  • Place of Presentation: 宮崎大学(宮崎)
  • Year and Date: 2009-09-29
• [Presentation] 超臨界二酸化炭素溶媒を利用したtert-ブチルフェノールの立体選択的水素化反応 (2009)
  • Author(s): 日吉範人
  • Organizer: 第104回触媒討論会
  • Place of Presentation: 宮崎大学
  • Year and Date: 2009-09-29