Establishment of a spin regulated catalyst using specific interactionbetween orbitals
| Project/Area Number |
21750175
|
|---|
| Research Category |
Grant-in-Aid for Young Scientists (B)
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Chemistry related to living body
|
|---|
| Research Institution | Toho University |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2009 – 2012
|
| Project Status |
Completed (Fiscal Year 2012)
|
| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2012: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
|
|---|
| Keywords | 生物無機化学 / スピン制御 / 高原子価 / ポルフィリン鉄錯体 / 軌道間相互作用 / 非平面 / 電子構造 / 電子状態 / スピン平衡 / 電子構構造 / スピン状態 |
|---|
| Research Abstract |
The high valent one-electron oxidized product from an iron(III) porphyrin complex is either the iron(III) porphyrin radical or iron(IV) porphyrin. In this study, we have revealed the existence of novel concept of spin equilibrium between the iron(III) porphyrin radical and iron(IV) porphyrin. We have also found the novel electronic structures of the six-coordinate high-spin iron(III) porphyrin radical without antiferromagnetic coupling and the pure intermediate-spin iron(III) porphyrin radical in the case of one-electron oxidized products.
|
Report
(5 results)
Research Products
(104 results)
