| Project/Area Number |
21750191
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Functional materials/Devices
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| Research Institution | Nagoya Institute of Technology |
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Principal Investigator |
INOMATA Tomohiko Nagoya Institute of Technology, 大学院・工学研究科, 助教 (40397493)
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| Project Period (FY) |
2009 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
|
| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
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| Keywords | イオン液体 / 鉄複各錯体 / ナノ反応場 / 燃料電池 / 修飾電極 / 鉄複核錯体 / 酸素活性化 |
|---|
| Research Abstract |
A phosphonium-type ionic liquid-modified Au electrode was prepared by a self-assembled monolayer technique. A diiron complex was introduced into the ionic liquid-modified electrode. The immobilization of the diiron complex was confirmed by IR-RAS and electrochemical measurement. From the change of its redox behavior under O_2 condition, the diiron complex on the ionic liquid-modified electrode was able to reduce O_2 electrocatalytically. From rotating ring-disk electrode measurements, two processes (2e^- and 4e^- reduction of O_2) have occurred on the ionic liquid electrode containing diiron complexes.
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