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Analysis of charge-transfer mechanism of the dye-sensitized photovoltaic devices using iodine-free electrolyte

Research Project

Project/Area Number 21750196
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Functional materials/Devices
Research InstitutionToin University of Yokohama

Principal Investigator

IKEGAMI Masashi  桐蔭横浜大学, 大学院・工学研究科, 講師 (30375414)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords色素増感太陽電池 / エネルギー変換 / 酸化チタン / イオン液体 / 光電変換素子 / 固体電解質 / ゲル電解質 / 電荷移動機構 / 交流インピーダンス / 温度依存性
Research Abstract

This research is centered on the electrolyte compositions of low iodine concentrations for dye-sensitized solar cells(DSSCs). Iodine is an essential component of a DSSC electrolyte, but even at the low iodine concentrations used in this research, comparable energy conversion efficiencies can be obtained. When the low iodine concentration electrolyte is used, the DSSCs based on conductive plastic substrates have high durability, and the photovoltaic performance shows a very small dependence on temperature.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (51 results)

All 2012 2011 2010 2009 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (36 results) Book (5 results) Remarks (4 results)

  • [Journal Article] Highly Luminescent Lead Bromide Perovskite Nanoparticles Synthesized with Porous Alumina Media2012

    • Author(s)
      A. Kojima, M. Ikegami, K. Teshima, and T. Miyasaka
    • Journal Title

      Chem. Lett

      Volume: 41 Issue: 4 Pages: 397-399

    • DOI

      10.1246/cl.2012.397

    • NAID

      10030544698

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Co-sensitization promoted light harvesting for plastic dye-sensitized solar cells2011

    • Author(s)
      K.M.Lee, Y.C.Hsu, M.Ikegami, T.Miyasaka, K.R.Justin Thomas, J.T.Lin, K.C.Ho
    • Journal Title

      Journal of Power Sources

      Volume: 196 Pages: 2416-2421

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stereocontrolled Synthesis and Photoisomerization Behavior of All-Cis and All-Trans Poly(m-phenylenevinylene)s2010

    • Author(s)
      M.Wakioka, M.Ikegami, F.Ozawa
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 6980-6985

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polythiophene-based mesoporous counter electrodes for plastic dye-sensitized solar cells2010

    • Author(s)
      T.Muto, M.Ikegami, T.Miyasaka
    • Journal Title

      Journal of Electrochemical Society

      Volume: 157

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient and stable plastic dye-sensitized solar cells based on a high light-harvesting ruthenium sensitizer2009

    • Author(s)
      K.M.Lee, S.J.Wu, C.Y.Chen, C.G.Wu, M.Ikeeami, K.Miyoshi, T.Miyasaka, K.C.Ho
    • Journal Title

      J.Mater.Chem. 19

      Pages: 5009-5015

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly porous PProDOT-Et2 film as counter electrode for plastic dye-sensitized solar cells2009

    • Author(s)
      Kun-Mu Lee, Chih-Yu Hsu, Po-Yen Chen, Masashi Ikegami, Tsutomu Miyasaka, Kuo-Chuan Ho
    • Journal Title

      Phys.Chem.Chem.Phys. 11

      Pages: 3375-3379

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 有機色素の共吸着による色素増感太陽電池の薄膜高効率化2012

    • Author(s)
      森田紗織, 池上和志, 宮坂力
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      アクトシティ浜松、静岡県浜松市
    • Year and Date
      2012-03-31
    • Related Report
      2011 Annual Research Report
  • [Presentation] 酸化ニッケルを用いる色素増感太陽電池用カーボン対極の高性能化2012

    • Author(s)
      奥村拓郎, 杉生剛, 井上鉄也, 池上和志, 宮坂力
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      アクトシティ浜松、静岡県浜松市
    • Year and Date
      2012-03-31
    • Related Report
      2011 Annual Research Report
  • [Presentation] 金属メッシュ電極を用いた色素増感太陽電池の大面積化2012

    • Author(s)
      梶田直人, 池上和志, 宮坂力
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      アクトシティ浜松、静岡県浜松市
    • Year and Date
      2012-03-31
    • Related Report
      2011 Annual Research Report
  • [Presentation] スプレー法による低温成膜酸化チタン電極の高効率化2012

    • Author(s)
      青山孝介, 池上和志, 宮坂力
    • Organizer
      電気化学会第79回大会
    • Place of Presentation
      アクトシティ浜松、静岡県浜松市
    • Year and Date
      2012-03-31
    • Related Report
      2011 Annual Research Report
  • [Presentation] 塗布型酸化チタンバッファ層を利用したフィルム型色素増感太陽電池の光発電性能改善2012

    • Author(s)
      小島陽広・木暮英雄・池上和志・宮坂力
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学、横浜市
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] 両面受光型プラスチック色素増感太陽電池モジュールの設計開発2012

    • Author(s)
      池上和志・手島健次郎・宮坂力
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学、横浜市
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] 光蓄電型太陽電池「光キャパシタ」の開発-イオン液体を用いる高性能化-2012

    • Author(s)
      宮坂力、伊奈隼人、池上和志
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学、横浜市
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] Photo-rechargeable Capacitor (Dye-sensitized Photocapacitor) with Ionic Liquid Electrolytes2011

    • Author(s)
      T.Miyasaka, M.Ikegami, A.Ishii, H.Ina
    • Organizer
      The 6th Aceanian Conference on Dye-sensitized and Organic Solar Cells
    • Place of Presentation
      B-conプラザ、大分市
    • Year and Date
      2011-10-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Towards Optimal Combination of Photovoltaic Devices for Facade and Architectural Applications2011

    • Author(s)
      K.Sato, T.Miyasaka, M.Ikegami
    • Organizer
      The 6th Aceanian Conference on Dye-sensitized and Organic Solar Cells
    • Place of Presentation
      B-conプラザ、大分市
    • Year and Date
      2011-10-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Electrolyte compositions for Dye-sensitized solar cells showing constant energy conversion efficiencies in wide temperature range2011

    • Author(s)
      T.Tamura, M.Ikegami, T.Miyasaka
    • Organizer
      The 6th Aceanian Conference on Dye-sensitized and Organic Solar Cells
    • Place of Presentation
      B-conプラザ、大分市
    • Year and Date
      2011-10-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] Metal oxide-coated Zinc oxide Photoelectrode for Dye-sensitized Solar Cell2011

    • Author(s)
      N.Sakai, H.J.Snaith, M.Ikegami, T.Miyasaka, T.N.Murakami
    • Organizer
      The 6th Aceanian Conference on Dye-sensitized and Organic Solar Cells
    • Place of Presentation
      B-conプラザ、大分市
    • Year and Date
      2011-10-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] TiO2-Coated ZnO Photoelectrodes for Dye-sensitized Solar Cells with Controlled Back Electron Transfer2011

    • Author(s)
      N.Sakai, M.Ikegami, T.Miyasaka, T.N.Murakami
    • Organizer
      62nd Annual Meeting of the International Society of Electrochemistry (ISE)
    • Place of Presentation
      朱鷺メッセ、新潟市
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] A quasi-solid dye-sensitized solar cell with polyvinyl alcohol-based electrolytes2011

    • Author(s)
      T.Tamura, M.Ikegami, T.Miyasaka
    • Organizer
      62nd Annual Meeting of the International Society of Electrochemistry (ISE)
    • Place of Presentation
      朱鷺メッセ、新潟市
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] イミダゾリウム系イオン液体を電解液に用いた色素増感光キャパシタの光充放電特性-22011

    • Author(s)
      伊奈隼人, 池上和志, 手島健次郎, 宮坂力
    • Organizer
      電気化学会2011年秋季大会
    • Place of Presentation
      朱鷺メッセ、新潟市
    • Year and Date
      2011-09-10
    • Related Report
      2011 Annual Research Report
  • [Presentation] 低温成膜酸化チタンの薄膜を用いる色素増感太陽電池の高効率化2011

    • Author(s)
      青山孝介, 池上和志, 宮坂力
    • Organizer
      電気化学会2011年秋季大会
    • Place of Presentation
      朱鷺メッセ、新潟市
    • Year and Date
      2011-09-10
    • Related Report
      2011 Annual Research Report
  • [Presentation] Printed photovoltaic devices based on molecular and solid-state light-harvesting sensitizers2011

    • Author(s)
      T.Miyasaka, M.Ikegami
    • Organizer
      3rd international Conference on Hybrid and Organic Photovoltaics(HOPV2011)
    • Place of Presentation
      Valencia, Spain
    • Year and Date
      2011-05-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] バッファ層による色素増感太陽電池の電子移動制御と高性能化2011

    • Author(s)
      森田紗織、池上和志、宮坂力
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      横浜国立大学(横浜市)
    • Year and Date
      2011-03-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] 色素増感電極を用いる活性酸素発生と環境浄化システム2011

    • Author(s)
      副田知宏、池上和志、宮坂力
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      横浜国立大学(横浜市)
    • Year and Date
      2011-03-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] ポリビニルアルコールを電解質に用いる擬固体色素増感太陽電池の熱依存特性2011

    • Author(s)
      田村壮礼、池上和志、宮坂力
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      横浜国立大学(横浜市)
    • Year and Date
      2011-03-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] 有機色素を用いる両面発電型色素増感太陽電池2010

    • Author(s)
      池上和志
    • Organizer
      光電気化学研究懇談会
    • Place of Presentation
      桐蔭横浜大学(横浜市)
    • Year and Date
      2010-11-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] 色素増感太陽電池用電解液の封止技術2010

    • Author(s)
      池上和志
    • Organizer
      サイエンス&テクノロジー主催 色素増感太陽電池における課題改善セミナー【封止・固体化】
    • Place of Presentation
      きゅりあん(東京都品川区)
    • Year and Date
      2010-10-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] Low Temperature Preparation of Counter Electrodes for Full Plastic Film Type Dye-sensitized Solar Cells2010

    • Author(s)
      M. Ikegami, T. Miyasaka
    • Organizer
      The 7^<th> Korea-Japan Symposium on Frontier Photoscience-2010
    • Place of Presentation
      Inter Bulgo hotel韓国大邱市
    • Year and Date
      2010-10-25
    • Related Report
      2011 Final Research Report
  • [Presentation] Low Temperature Preparation of Counter Electrodes for Full Plastic Film Type Dye-sensitized Solar Cells2010

    • Author(s)
      M.Ikegami, T.Miyasaka
    • Organizer
      The 7th Korea-Japan Symposium on Frontier Photoscience-2010
    • Place of Presentation
      Inter Bulgo hotel(韓国大邱市)
    • Year and Date
      2010-10-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] 白金/導電性高分子複合膜を用いる色素増感太陽電池プラスチック対極の電気化学特性2010

    • Author(s)
      塚本直、池上和志、宮坂力
    • Organizer
      電気化学会2010年秋季大会
    • Place of Presentation
      神奈川工科大学(神奈川県厚木市)
    • Year and Date
      2010-09-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] イオン液体ハロゲン化物を電解液に用いた電気二重層キャパシタの初期特性2010

    • Author(s)
      伊奈隼人、池上和志、手島健二郎、宮坂力
    • Organizer
      日本化学会2010年関東支部大会
    • Place of Presentation
      筑波大学(茨城県つくば市)
    • Year and Date
      2010-08-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] 白金触媒と導電性高分子対極を用いた色素増感太陽電池の電気化学特性2010

    • Author(s)
      塚本直、池上和志、宮坂力
    • Organizer
      日本化学会2010年関東支部大会
    • Place of Presentation
      筑波大学(茨城県つくば市)
    • Year and Date
      2010-08-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] 新規吸着基を持つカルバゾール系有機色素を用いた色素増感太陽電池2、プラスチック電極への応用と高効率化2010

    • Author(s)
      森田紗織、河野正教、池上和志、手島健二郎、宮坂力、甲村長利、原浩二郎、張雪華
    • Organizer
      日本化学会2010年関東支部大会
    • Place of Presentation
      筑波大学(茨城県つくば市)
    • Year and Date
      2010-08-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] 新規吸着基を持つカルバゾール系有機色素を用いた色素増感太陽電池1、増感色素の合成とデバイス評価2010

    • Author(s)
      甲村長利、原浩二郎、X.H.Zhang、池上和志、手島健二郎、宮坂力
    • Organizer
      日本化学会2010年関東支部大会
    • Place of Presentation
      筑波大学(茨城県つくば市)
    • Year and Date
      2010-08-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] 色素増感太陽電池の直列及び並列接続における電気化学特性の検討2010

    • Author(s)
      山本慶太、手島健次郎、池上和志、宮坂力
    • Organizer
      日本化学会2010年関東支部大会
    • Place of Presentation
      筑波大学(茨城県つくば市)
    • Year and Date
      2010-08-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] Plastic dye-sensitized photovoltaic cells with metal-free organic sensitizers2010

    • Author(s)
      T.Miyasaka, S.Morita, M.Ikegami
    • Organizer
      The 18th International Conference on Photochemical Conversion and Storage of Solar Energy(IPS-18)
    • Place of Presentation
      コリア大学(ソウル)
    • Year and Date
      2010-07-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] 色素増感太陽電池 徹底解説2010

    • Author(s)
      池上和志
    • Organizer
      Electronic Journal第534回Technical Seminar
    • Place of Presentation
      総評会館(東京都)
    • Year and Date
      2010-07-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] Photoelectrochemical study on the characteristic of photocapacitors2010

    • Author(s)
      K.Yamamoto, K.Teshima, M.Ikegami, T.Miyasaka
    • Organizer
      Renewable Energy 2010
    • Place of Presentation
      パシフィコ横浜(横浜市)
    • Year and Date
      2010-06-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] Plastic dye sensitized solar cells with organic dyes : Efficiency improvement with TiOX buffer layers2010

    • Author(s)
      S.Morita, M.Ikegami, T.Miyasaka
    • Organizer
      Renewable Energy 2010
    • Place of Presentation
      パシフィコ横浜(横浜市)
    • Year and Date
      2010-06-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] High viscosity electrolyte containing polyvinyl alcohol and imidazolium iodide for dye-sensitized solar cells2010

    • Author(s)
      T.Tamura, M.Ikegami, T.Miyasaka
    • Organizer
      Renewable Energy 2010
    • Place of Presentation
      パシフィコ横浜(横浜市)
    • Year and Date
      2010-06-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] 色素増感太陽電池の作製・測定技術2010

    • Author(s)
      池上和志
    • Organizer
      技術情報協会 セミナーNo.005208
    • Place of Presentation
      ゆうぽうと(東京都)
    • Year and Date
      2010-05-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] Development of Plastic Film type dye-sensitized solar cells2009

    • Author(s)
      池上和志
    • Organizer
      Plastic Electronics Conference Asia 2009
    • Place of Presentation
      シャングリ・ラファーイースタンプラザホテル台北
    • Year and Date
      2009-06-08
    • Related Report
      2009 Annual Research Report
  • [Book] Electronic Journal Archives 色素増感太陽電池の全貌★徹底解説2011

    • Author(s)
      池上和志
    • Total Pages
      140
    • Publisher
      電子ジャーナル
    • Related Report
      2011 Final Research Report
  • [Book] 色素増感太陽電池の全貌★徹底解説~開発動向・最新成果・実用化など全てを詳解~2011

    • Author(s)
      池上和志
    • Total Pages
      140
    • Publisher
      株式会社電子ジャーナル
    • Related Report
      2011 Annual Research Report
  • [Book] Electronic Journal PV Archives色素増感太陽電池徹底解説2010

    • Author(s)
      池上和志
    • Total Pages
      124
    • Publisher
      電子ジャーナル
    • Related Report
      2011 Final Research Report
  • [Book] 色素増感太陽電池★徹底解説2010

    • Author(s)
      池上和志
    • Total Pages
      124
    • Publisher
      電子ジャーナル
    • Related Report
      2010 Annual Research Report
  • [Book] 高機能デバイス封止材料と最先端材料 第4章-4 色素増感太陽電池用の封止材料2009

    • Author(s)
      池上和志(監修 高橋昭雄)
    • Publisher
      シーエムシー出版
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.cc.toin.ac.jp/sc/miyasaka

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://www.cc.toin.ac.jp/sc/miyasaka/

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.cc.toin.ac.jp/sc/miyasaka/

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.cc.toin.ac.jp/sc/miyasaka/

    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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