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Characterization of nano-scale interface in lithium batteries using epitaxial model electrodes

Research Project

Project/Area Number 21750205
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Inorganic industrial materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

HIRAYAMA Masaaki  Tokyo Institute of Technology, 大学院・総合理工学研究科, 助教 (30531165)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2009: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Keywordsエネルギー一般 / MBE・エピタキシャル / ナノ材料 / 無機工業化学 / ハイブリッド車 / エネルギー全般 / MBE,エピタキシャル
Research Abstract

Interfacial reactions of lithium batteries have been determined by in situ X-ray surface scattering measurements using epitaxial thin-films electrodes. The atomic arrangements of electrode surfaces change on being soaked in the electrolyte, and are subsequently reconstructed when a voltage is applied in the first charge process. Mechanical and technical development of surface structures is of considerable importance for improving the power characteristics and cyclability of new-generation batteries.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (45 results)

All 2011 2010 2009 Other

All Journal Article (10 results) (of which Peer Reviewed: 5 results) Presentation (32 results) Remarks (3 results)

  • [Journal Article] Dynamic Structural Changes at LiMn_2O_4/Electrolyte Interface during Lithium Battery Reaction2011

    • Author(s)
      Masaaki Hirayama, Hidekazu Ido, Kyungsu Kim, Woosuk Cho, Kazuhisa Tamura, Jun'ichiro Mizuki, Ryoji Kanno
    • Journal Title

      Journal of the American Chemical Society 132

      Pages: 15268-15276

    • Related Report
      2010 Final Research Report
  • [Journal Article] Epitaxial growth and electrochemical properties of Li_4Ti_5O_<12> thin-film lithium battery anodes2011

    • Author(s)
      Masaaki Hirayama, Kyungsu Kim, Takeshi Toujigamori, Woosuk Cho, Ryoji Kanno
    • Journal Title

      Dalton Transactions 40

      Pages: 2882-2887

    • Related Report
      2010 Final Research Report
  • [Journal Article] Epitaxial growth and electrochemical properties of Li_4Ti_5O_<12> thin-film lithium battery anodes2011

    • Author(s)
      Masaaki Hirayama, Kyungsu Kim, Takeshi Toujigamori, Woosuk Cho, Ryoji Kanno
    • Journal Title

      Dalton Transactions

      Volume: 40 Pages: 2882-2887

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface characterization of LiFePO_4 epitaxial thin films by X-ray/neutron reflectometry2010

    • Author(s)
      Masaki Hirayama, Masao Yonemura, Kouta Suzuki, Naoya Torikai, Hillary Smith, Erik Watkinsand, Jarek Majewski, Ryoji Kanno
    • Journal Title

      Electrochemistry 78

      Pages: 413-415

    • NAID

      10026165859

    • Related Report
      2010 Final Research Report
  • [Journal Article] Structural changes in surface and bulk LiNi_<0.5>Mn_<0.5>O_2 during electrochemical reaction on epitaxial thin-film electrodes characterized by in situ X-ray scattering2010

    • Author(s)
      Kazuyuki Sakamoto, Masaaki Hirayama, Hiroaki Konishi, Noriyuki Sonoyama, Nicolas Dupre, Dominique Guyomard, Kazuhisa Tamura, Jun'ichiro Mizuki, Ryoji Kanno
    • Journal Title

      Physical Chemistry Chemical Physics 12

      Pages: 3815-3823

    • Related Report
      2010 Final Research Report
  • [Journal Article] Dynamic Structural Changes at LiMn_2O_4/Electrolyte Interface during Lithium Battery Reaction2010

    • Author(s)
      Masaaki Hirayama, Hidekazu Ido, Kyungsu Kim, Woosuk Cho, Kazuhisa Tamura, Jun'ichiro Mizuki, Ryoji Kanno
    • Journal Title

      Journal of the American Chemical Society

      Volume: 132 Pages: 15268-15276

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface characterization of LiFePO_4 epitaxial thin films by X-ray/neutron reflectometry2010

    • Author(s)
      M.Hirayama, M.Yonemura, K.Suzuki, N.Torikai, H.Smith, E.Watkinsand, J.Majewski, R.Kanno
    • Journal Title

      Electrochemistry (In press)

    • NAID

      10026165859

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural changes in surface and bulk LiNi_<0.5>Mn_<0.5>O_2 during electrochemical reaction on epitaxial thin-film electrodes characterized by in situ X-ray scattering2010

    • Author(s)
      K.Sakamoto, M.Hirayama, H.Konishi, N.Sonoyama, N.Dupre, D.Guyomard, K.Tamura, J.Mizuki, R.Kanno
    • Journal Title

      Phys.Chem.Chem.Phys 12

      Pages: 3815-3823

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface Structure of LiNi_<0.8>Co_<0.2>O_2 : a New Experimental Technique Using in Situ X-ray Diffraction and Two-Dimensional Epitaxial Film Electrodes2009

    • Author(s)
      Kazuyuki Sakamoto, Masaaki Hirayama, Noriyuki Sonoyama, Daisuke Mori, Atsuo Yamada, Kazuhisa Tamura, Jun'ichiro Mizuki, Ryoji Kanno
    • Journal Title

      Chemistry Materials. 21

      Pages: 730-735

    • Related Report
      2010 Final Research Report
  • [Journal Article] Surface Structure of LiNi_<0.8>Co_<0.2>O_2 : a New Experimental Technique Using in Situ X-ray Diffraction and Two-Dimensional Epitaxial Film Electrodes2009

    • Author(s)
      K.Sakamoto, M.Hirayama, N.Sonoyama, D.Mori, A.Yamada, K.Tamura, J.Mizuki, R.Kanno
    • Journal Title

      Chem.Mater. 21(3)

      Pages: 730-735

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Characterization of Nano-Scale Interface in Lithium Batteries2011

    • Author(s)
      Masaaki Hirayama
    • Organizer
      International Scientific Spring 2011
    • Place of Presentation
      Islamabad, Pakistan.
    • Year and Date
      2011-03-01
    • Related Report
      2010 Final Research Report
  • [Presentation] Characterization of Nano-Scale Interface in Lithium Batteries2011

    • Author(s)
      Masaaki Hirayama
    • Organizer
      International Scientific Spring-2011
    • Place of Presentation
      National Centre for Physics, Islamabad, Pakistan
    • Year and Date
      2011-03-01
    • Related Report
      2010 Annual Research Report
  • [Presentation] In situ中性子反射率法によるリチウムインターカレーション界面構造解析2010

    • Author(s)
      平山雅章, 金敬洙, 鈴木耕太, 田港聡, 粉生守, 菅野了次, 米村雅雄, 山田悟史
    • Organizer
      第36回固体イオニクス討論会
    • Place of Presentation
      仙台市情報・産業プラザ
    • Year and Date
      2010-11-26
    • Related Report
      2010 Final Research Report
  • [Presentation] Li_2RuO_3電極・電解質界面構造とリチウムインターカレーション特性2010

    • Author(s)
      田港聡, 平山雅章, 鈴木耕太, 金敬洙, 粉生守, 南嶋宏映, 菅野了次, 田村和久, 水木純一郎
    • Organizer
      第36回固体イオニクス討論会
    • Place of Presentation
      仙台市情報・産業プラザ
    • Year and Date
      2010-11-26
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] in situ中性子反射率法によるリチウムインターカレーション界面構造解析2010

    • Author(s)
      平山雅章, 金敬洙, 鈴木耕太, 田港聡, 粉生守, 菅野了次, 米村雅雄, 山田悟史
    • Organizer
      第36回固体イオニクス討論会
    • Place of Presentation
      仙台市情報・産業プラザ
    • Year and Date
      2010-11-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] TEM-EELS法によるLiMn_2O_4電極表面の劣化機構解析2010

    • Author(s)
      平山雅章, 井戸秀和, 金敬洙, Cho Woosuk, 菅野了次
    • Organizer
      第51回電池討論会
    • Place of Presentation
      愛知県産業労働センター
    • Year and Date
      2010-11-11
    • Related Report
      2010 Final Research Report
  • [Presentation] TEM-EELS法によるLIMn2_O4電極表面の劣化機構解析2010

    • Author(s)
      平山雅章, 井戸秀和, 金敬洙, Cho Woosuk, 菅野了次
    • Organizer
      第51回電池討論会
    • Place of Presentation
      愛知県産業労働センター
    • Year and Date
      2010-11-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] Surface Structure Changes in Lithium Battery Electrodes Studied by In Situ X-ray and Neutron Scattering Methods2010

    • Author(s)
      Ryoji Kanno, Masaaki Hirayama, Kazuhisa Tamura, Hidekazu Ido
    • Organizer
      218th ECS Meeting
    • Place of Presentation
      Riviera Hotel, Las Vegas, USA.
    • Year and Date
      2010-10-12
    • Related Report
      2010 Final Research Report
  • [Presentation] Surface Structure Changes in Lithium Battery Electrodes Studied by In Situ X-ray and Neutron Scattering Methods2010

    • Author(s)
      Ryoji Kanno, Masaaki Hirayama, Kazuhisa Tamura, Hidekazu Ido
    • Organizer
      218th ECS Meeting
    • Place of Presentation
      Riviera Hotel, Las Vegas, USA
    • Year and Date
      2010-10-12
    • Related Report
      2010 Annual Research Report
  • [Presentation] Nano-effects in epitaxial LiFePO_4 thin film electrode2010

    • Author(s)
      Kouta Suzuki, Masaaki Hirayama, Kyungsu Kim,Mamoru Komo,Ryoji Kanno, Machiko Abe,Kazuhisa Tamura, Jun'ichiro Mizuki
    • Organizer
      The 5th Asian Conference on Electrochemical Power Sources (ACEPS)
    • Place of Presentation
      National university of Singapore, Singapore.
    • Year and Date
      2010-09-18
    • Related Report
      2010 Final Research Report
  • [Presentation] Interfacial phenomena and electrochemical properties of lithium battery electrodes2010

    • Author(s)
      Masaaki Hirayama, Kouta Suzuki, Kyungsu Kim, Kazuhisa Tamura, Jun'ichiro Mizuki, Ryoji Kanno
    • Organizer
      The 5th Asian Conference on Electrochemical Power Sources (ACEPS)
    • Place of Presentation
      National university of Singapore, Singapore.
    • Year and Date
      2010-09-18
    • Related Report
      2010 Final Research Report
  • [Presentation] Nano-effects in epitaxial LiFePO_4 thin film electrode2010

    • Author(s)
      Kouta Suzuki, Masaaki Hirayama, Kyungsu Kim, Mamoru Komo, Ryoji Kanno, Machiko Abe, Kazuhisa Tamura, Jun'ichiro Mizuki
    • Organizer
      The 5th Asian Conference on Electrochemical Power Sources (ACEPS)
    • Place of Presentation
      National university of Singapore, Singapore
    • Year and Date
      2010-09-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Interfacial phenomena and electrochemical properties of lithium battery electrodes2010

    • Author(s)
      Masaaki Hirayama, Kouta Suzuki, Kyungsu Kim, Kazuhisa Tamura, Jun'ichiro Mizuki, Ryoji Kanno
    • Organizer
      The 5th Asian Conference on Electrochemical Power Sources (ACEPS)
    • Place of Presentation
      National university of Singapore, Singapore
    • Year and Date
      2010-09-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Surface structural changes of Li_4Ti_5O_<12> electrode2010

    • Author(s)
      Kyungsu Kim, Kouta Suzuki, Woosuk Cho, Hidekazu Ido, Kazuhisa Tamura, Jun'ichiro Mizuki, Masaaki Hirayama, Ryoji Kanno
    • Organizer
      3rd International Conference on Advanced Lithium Batteries for Automobile Applications (ABAA)
    • Place of Presentation
      Hanyang Institute of Technology, Korea.
    • Year and Date
      2010-09-09
    • Related Report
      2010 Final Research Report
  • [Presentation] Surface structural changes of Li_4Ti_5O_<12>, electrode2010

    • Author(s)
      Kyungsu Kim, Kouta Suzuki, Woosuk Cho, Hidekazu Ido, Kazuhisa Tamura Jun'ichiro Mizuki, Masaaki Hirayama, Ryoji Kanno
    • Organizer
      3rd International Conference on Advanced Lithium Batteries for Automobile Applications (ABAA)
    • Place of Presentation
      Hanyang Institute of Technology, Korea
    • Year and Date
      2010-09-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] Characterization of the Electrode/Electrolyte Interface Using Model Epitaxial Electrodes2010

    • Author(s)
      Ryoji Kanno, Masaaki Hirayama, Kazuhisa Tamura, Hidekazu Ido
    • Organizer
      The 15th International Meeting on Lithium Batteries
    • Place of Presentation
      Fairmont The Queen Elizabeth, Montreal, Canada.
    • Year and Date
      2010-06-30
    • Related Report
      2010 Final Research Report
  • [Presentation] Phase Transition at Li_4Ti_5O_<12> Surface, In Situ Surface Characterization Using Epitaxial Thin-film Electrode and Surface Diffraction Technique2010

    • Author(s)
      Kyungsu Kim, Kouta Suzuki, Woosuk Cho, Hidekazu Ido, Kazuhisa Tamura,Jun'ichiro Mizuki, Masaaki Hirayama, Ryoji Kanno
    • Organizer
      The 15th International Meeting on Lithium Batteries
    • Place of Presentation
      Fairmont The Queen Elizabeth, Montreal, Canada.
    • Year and Date
      2010-06-30
    • Related Report
      2010 Final Research Report
  • [Presentation] Characterization of the Electrode/Electrolyte Interface Using Model Epitaxial Electrodes2010

    • Author(s)
      Ryoji Kanno, Masaaki Hirayama, Kazuhisa Tamura, Hidekazu Ido
    • Organizer
      The 15th International Meeting on Lithium Batteries
    • Place of Presentation
      Fairmont The Queen Elizabeth, Montreal, Canada
    • Year and Date
      2010-06-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] Phase Transition at Li_4Ti_5O_<12>, Surface : In Situ Surface Characterization Using Epitaxial Thin-film Electrode and Surface Diffraction Technique2010

    • Author(s)
      Kyungsu Kim, Kouta Suzuki, Woosuk Cho, Hidekazu Ido, Kazuhisa Tamura Jun'ichiro Mizuki, Masaaki Hirayama, Ryoji Kanno
    • Organizer
      The 15th International Meeting on Lithium Batteries
    • Place of Presentation
      Fairmont The Queen Elizabeth, Montreal, Canada
    • Year and Date
      2010-06-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] 放射光X線によるリチウム電池電極界面のその場観察2010

    • Author(s)
      粉生守, 平山雅章, 鈴木耕太, 金敬洙, 田村和久, 内本喜晴, 谷田肇, 宇留賀朋哉, 菅野了次
    • Organizer
      化学電池材料研究会ミーティング
    • Place of Presentation
      日本化学会館,東京
    • Year and Date
      2010-06-08
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] エピタキシャル薄膜を用いたリチウム電極界面反応のその場観察2010

    • Author(s)
      粉生守, 平山雅章, 鈴木耕太, 金敬洙, 田村和久, 菅野了次
    • Organizer
      粉体粉末冶金協会平成22年度春季大会
    • Place of Presentation
      早稲田大学,東京
    • Year and Date
      2010-05-26
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] 中性子反射率法によるリチウム電池界面挙動観測2010

    • Author(s)
      平山雅章, 鈴木耕太, 菅野了次, 米村雅雄, 鳥飼直也, Hillary Smith, Erik Watkinsand, Jarek Majewski
    • Organizer
      電気化学会
    • Place of Presentation
      富山
    • Year and Date
      2010-03-30
    • Related Report
      2010 Final Research Report
  • [Presentation] 中性子反射率法によるリチウム電池界面挙動観測2010

    • Author(s)
      平山雅章, 鈴木耕太, 菅野了次, 米村雅雄, 鳥飼直也, Hillary Smith, Erik Watkinsand, Jarek Majewski
    • Organizer
      第50回電池討論会
    • Place of Presentation
      富山
    • Year and Date
      2010-03-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] Interfacial phenomena of lithium battery electrodes studied by in-situ X-ray scattering methods2009

    • Author(s)
      Ryoji Kanno, Masaaki Hirayama
    • Organizer
      The 50th battery symposium
    • Place of Presentation
      Kyoto, Japan.
    • Year and Date
      2009-12-02
    • Related Report
      2010 Final Research Report
  • [Presentation] Interfacial phenomena of lithium battery electrodes studied by in-situ X-ray scattering methods2009

    • Author(s)
      菅野了次, 平山雅章
    • Organizer
      he 50th battery symposium
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2009-12-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] In situ XAFS法によるリチウム電池電極界面の検出2009

    • Author(s)
      平山雅章、Woosuk Cho、鈴木耕太、Kim Kyungsu、田村和久、中尾孝之、折笠有基、内本喜晴、谷田肇、宇留賀朋哉、菅野了次
    • Organizer
      第50回電池討論会
    • Place of Presentation
      京都
    • Year and Date
      2009-12-01
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] Structure and Electrochemical Properties of Epitaxial LiFePO_4 Thin Film Electrode2009

    • Author(s)
      Masaaki Hirayama, Kouta Suzuki, Kazuhisa Tamura, Jun'ichiro Mizuki, Ryoji Kanno
    • Organizer
      2nd International Conference on Advanced Lithium Batteries for Automobile Applications
    • Place of Presentation
      Tokyo, Japan.
    • Year and Date
      2009-11-28
    • Related Report
      2010 Final Research Report
  • [Presentation] Structure and Electrochemical Properties of Epitaxial LiFePO_4 Thin Film Electrode2009

    • Author(s)
      M.Hirayama, K.Suzuki, K.Tamura, J.Mizuki, R.Kanno
    • Organizer
      2nd International Conference on Advanced Lithium Batteries for Automobile Applications
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2009-11-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] Interfacial structure changes of intercalation materials during electrochemical process2009

    • Author(s)
      Ryoji Kanno, Masaaki Hirayama, Takeshi Toujigamori, Kouta Suzuki, Woosuk Cho, Kazuhisa Tamura, Juniciro Mizuki
    • Organizer
      The 3rd International Conference on Physics of Solid State Ionics
    • Place of Presentation
      Kumamoto, Japan.
    • Year and Date
      2009-10-27
    • Related Report
      2010 Final Research Report
  • [Presentation] Interfacial structure changes of intercalation materials during electro chemical process2009

    • Author(s)
      R.Kanno, M.Hirayama, T.Toujigamori, K.Suzuki, W.Cho, K.Tamura, J.Mizuki
    • Organizer
      The 3rd International Conference on Physics of Solid State Ionics
    • Place of Presentation
      Kumamoto, Japan
    • Year and Date
      2009-10-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] Structure and electrochemical properties of epitaxial thin film electrodes for lithium batteries2009

    • Author(s)
      Masaaki Hirayama, Takeshi Toujigamori, Kouta Suzuki, Woosuk Cho, Atsuo Yamada, Kazuhisa Tamura, Jun'ichiro Mizuki, Ryoji Kanno
    • Organizer
      216th Meeting of The Electrochemical Society
    • Place of Presentation
      Vienna, Austria.
    • Year and Date
      2009-10-07
    • Related Report
      2010 Final Research Report
  • [Presentation] Structure and electrochemical properties of epitaxial thin film electrodes for lithium batteries2009

    • Author(s)
      M.Hirayama, T.Toujigamon, K.Suzuki, W.Cho, A.Yamada, K.Tamura, J.Mizuki, R.Kanno
    • Organizer
      216th Meeting of The Electrochemical Society
    • Place of Presentation
      Vienna, Austria
    • Year and Date
      2009-10-07
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.echem.titech.ac.jp/~kanno/index.html

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://www.echem.titech.ac.jp/~kanno/index.html

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.echem.titech.ac.jp/~kanno/index.html

    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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