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A Study on the Formation of PAHs in the Internal Combustion Engine

Research Project

Project/Area Number 21760151
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Thermal engineering
Research InstitutionUniversity of Fukui

Principal Investigator

SAKAI Yasuyuki  University of Fukui, 大学院・工学研究科, 助教 (70511088)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2009: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Keywords燃焼 / 内燃機関 / ナノPM / 化学反応 / 多環芳香族 / 炭化水素燃料 / 燃焼反応モデル / 量子化学計算 / 反応速度論 / PAH / モデル構築
Research Abstract

On the growth of nano-particles in the internal combustion engines starting from the ignition and combustion of fuels, following points were little known; the ignition mechanism of real fuels, and the reaction mechanism of unsaturated species which strongly related to the production of poly aromatic hydrocarbons, the precursor of the nano-particle. The ternary mixture of n-heptane, iso-octane, and toluene is assumed to be a minimum surrogate fuel, which is a model fuel for the combustion simulation of gasoline. The goal of this study is the development of the detailed chemical kinetic model for the oxidation of gasoline surrogate fuels under the engine environment.
The model was constructed based on the literature data and the quantum chemical calculations. The proposed gasoline surrogate fuel model includes low temperature oxidation kinetics, which is important under the engine environment. And, to obtain the measurement data such as ignition delay times for the validation of the model, high-pressure shock tube and constant volume chamber were designed and developed.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (9 results)

All 2011 2010 2009

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (7 results)

  • [Journal Article] アルカン簡略化燃焼反応モデルの中間生成物反応パッケージ2011

    • Author(s)
      酒井康行, 安東弘光, 桑原一成
    • Journal Title

      自動車技術会論文集 Vol.42, No.1

      Pages: 213-218

    • NAID

      130004515654

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] アルカン簡略化燃焼反応モデルの中間生成物反応パッケージ2011

    • Author(s)
      酒井康行, 安東弘光, 桑原一成
    • Journal Title

      自動車技術会論文集

      Volume: Vol.42,No.1 Pages: 213-218

    • NAID

      130004515654

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] トルエン詳細反応モデルの改良と着火過程の反応論的考察2010

    • Author(s)
      酒井康行, 前田博貴, 中村昭裕, 安東弘光
    • Organizer
      第48回燃焼シンポジウム
    • Place of Presentation
      福岡
    • Year and Date
      2010-12-01
    • Related Report
      2010 Final Research Report
  • [Presentation] トルエン詳細反応モデルの改良と着火過程の反応論的考察2010

    • Author(s)
      酒井康行, 前田博貴, 中村昭裕, 安東弘光
    • Organizer
      第48回燃焼シンポジウム
    • Place of Presentation
      福岡ガーデンパレス&都久志会館(福岡)
    • Year and Date
      2010-12-01
    • Related Report
      2010 Annual Research Report
  • [Presentation] アルカン簡略化燃焼反応モデルの中間生成物反応パッケージ2010

    • Author(s)
      酒井康行, 安東弘光, 桑原一成
    • Organizer
      自動車技術会2010年秋季大会
    • Place of Presentation
      北九州
    • Year and Date
      2010-10-01
    • Related Report
      2010 Final Research Report
  • [Presentation] アルカン簡略化燃焼反応モデルの中間生成物反応パッケージ2010

    • Author(s)
      酒井康行, 安東弘光, 桑原一成
    • Organizer
      自動車技術会2010年秋季大会
    • Place of Presentation
      西日本総合展示場(北九州)
    • Year and Date
      2010-10-01
    • Related Report
      2010 Annual Research Report
  • [Presentation] THEORETICAL INVESTIGATIONS ON THE REACTIONS OF CYCLOHEKYL AND DECALYL PEROXY RADICALS2010

    • Author(s)
      Y.Sakai, T.Watanabe, H.Ando, A.Miyoshi
    • Organizer
      33rd International Symposium on Combustion
    • Place of Presentation
      Beijing, China
    • Year and Date
      2010-08-03
    • Related Report
      2010 Final Research Report
  • [Presentation] THEORETICAL INVESTIGATIONS ON THE REACTIONS OF CYCLOHEKYL AND DECALYL PEROXY RADICALS2010

    • Author(s)
      Y.Sakai, T.Watanabe, H.Ando, A.Miyoshi
    • Organizer
      33rd International Symposium on Combustion
    • Place of Presentation
      中国・北京
    • Year and Date
      2010-08-03
    • Related Report
      2010 Annual Research Report
  • [Presentation] 量子化学計算によるデカリンの低温酸化反応機構の検討2009

    • Author(s)
      渡邉貴文, 酒井康行, 安東弘光
    • Organizer
      第47回燃焼シンポジウム
    • Place of Presentation
      札幌
    • Year and Date
      2009-12-04
    • Related Report
      2010 Final Research Report 2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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