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Study on strongly correlated ternary transition metal nitride synthesized by H2-N2 gas method.

Research Project

Project/Area Number 21760531
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Inorganic materials/Physical properties
Research InstitutionKyoto University

Principal Investigator

WAKI Takeshi  京都大学, 大学院・工学研究科, 助教 (50463906)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2009: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsη-カーバイド / 幾何学的フラストレーション / メタ磁性転移 / 強相関電子系 / 遷移金属窒化物 / 非フェルミ液体 / n-カーバイド / 遍歴電子メタ磁性転移 / Fe3Mo3N / HIP
Research Abstract

Physical properties of Fe3Mo3N and(Fe1-xCox)_3Mo_3N systems have been studied comprehensively. In this study, a non-Fermi-liquid behavior without any tuning such as physical pressure and/or chemical doping was found for the first time. NFL behavior suggests the existence of quantum critical point in the vicinity of pure Fe_3Mo_3N. Field and substitution induced ferromagnetic phases were found as was expected. The constructed phase diagram is not trivial, suggesting the effect of geometrical frustration inherent in theη-carbide-type compound. Related compound Fe_3W_3N(a ferromagnet TC=110 K) and Fe_6W_6N(an antiferromagnet TN=75 K) were synthesized by HIP method for the first time.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (44 results)

All 2012 2011 2010 2009

All Journal Article (17 results) (of which Peer Reviewed: 9 results) Presentation (27 results)

  • [Journal Article] Magnetic susceptibility ofη-carbide-type molybdnum and tungsten carbides and nitrides2012

    • Author(s)
      T. Waki, S. Terazawa, Y. Umemoto, Y. Tabata, Y. Murase, M. Kato, J. Hirota, H. Nakamura
    • Journal Title

      J. Phys.: Conf. Ser

      Volume: 344 Pages: 12017-12017

    • Related Report
      2011 Final Research Report
  • [Journal Article] Geometric frustration in the stella quadrangula lattice and metamagnesims in Fe3Mo3N2012

    • Author(s)
      H. Nakamura, S. Terazawa, T. Waki, Y. Tabata, M. Takigawa
    • Journal Title

      J. Phys.: Conf. Ser

      Volume: 344 Pages: 12011-12011

    • Related Report
      2011 Final Research Report
  • [Journal Article] Magnetic susceptibility of η-carbide-type molybdnum and tungsten carbides and nitrides2012

    • Author(s)
      T.Waki, S.Terazawa, Y.Umemoto, Y.Tabata, Y.Murase, M.Kato, I.Hirota, H.Nakamura
    • Journal Title

      J.Phys. : Conf.Ser.

      Volume: 344 Pages: 12017-12017

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] HIP synthesis ofη-carbide-type nitrides Fe3W3N and Fe6W6N and their magnetic properties2011

    • Author(s)
      T. Waki, S. Terazawa, Y. Tabata, Y. Murase, M. Kato, K. Hirota, S. Ikeda, H. Kobayashi, K. Sato, K. Kindo, H. Nakamura
    • Journal Title

      J. Alloys Compd

      Volume: 509 Pages: 9451-9451

    • Related Report
      2011 Final Research Report
  • [Journal Article] Interplay between quantum criticality and geometrical frustration in Fe3Mo3N with stella quadrangula lattice2011

    • Author(s)
      T. Waki, S. Terazawa, T. Yamazaki, Y. Tabata, K. Sato, A. Kondo, K. Kindo, M. Yokoyama, Y. Takahashi, H. Nakamura
    • Journal Title

      EPL

      Volume: 94 Pages: 37004-37004

    • Related Report
      2011 Final Research Report
  • [Journal Article] Metamagnetism ofη-carbide-type transition-metal carbides and nitrides2011

    • Author(s)
      T. Waki, S. Terazawa, Y. Umemoto, Y. Tabata, K. Sato, A. Kondo, K. Kindo, H. Nakamura
    • Journal Title

      J. Phys.: Conf. Ser

      Volume: 320 Pages: 12069-12069

    • Related Report
      2011 Final Research Report
  • [Journal Article] Geometric frustration in Itinerant Electron Magnets2011

    • Author(s)
      H. Nakamura, S. Terazawa, T. Waki, Y. Tabata, T. Koyama, T. Kohara
    • Journal Title

      AIP Conf. Proc

      Volume: 1347 Pages: 238-238

    • Related Report
      2011 Final Research Report
  • [Journal Article] Interplay between quantum criticality and geometric frustration in Fe_3Mo_3N with stella quadrangula lattice2011

    • Author(s)
      T. Waki, H. Nakamura, 他8名
    • Journal Title

      EPL

      Volume: vol.94 (3) Issue: 3 Pages: 37004-37004

    • DOI

      10.1209/0295-5075/94/37004

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] HIP synthesis of η-carbide-type nitrides Fe_3W_3N and Fe_6W_6N and their magnetic properties2011

    • Author(s)
      T.Waki
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 500 Issue: 39 Pages: 9451-9455

    • DOI

      10.1016/j.jallcom.2011.07.025

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metamagnetism of of η-carbide-type transition-metal carbides and nitrides2011

    • Author(s)
      T.Waki
    • Journal Title

      Journal of Physics : Conference Series

      Volume: 320 Pages: 12069-12069

    • DOI

      10.1088/1742-6596/320/1/012069

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Geometric frustration in the stella quadrangula lattice and metamagnetism in Fe_3Mo_3N2011

    • Author(s)
      H.Nakamura
    • Journal Title

      Journal of Physics : Conference Series

      Volume: 344 Pages: 12011-12011

    • DOI

      10.1088/1742-6596/344/1/012011

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Itenarant Electon Metamagnetism inη-Carbide-Type Compound Co3Mo3C2010

    • Author(s)
      T. Waki, Y. Umemoto, S. Terazawa, Y. Tabata, A. Kondo, K. Sato, K. Kindo, S. Alconchel, F. Sapina, H. Nakamura
    • Journal Title

      J. Phys. Soc. Jpn

      Volume: 79 Pages: 93793-93793

    • Related Report
      2011 Final Research Report
  • [Journal Article] Non-Fermi-Liquid Behavior on Iron-Based Itinerant Electron Magnet Fe3Mo3N2010

    • Author(s)
      T. Waki, S. Terazawa, Y. Tabata, F. Oba, C. Michioka, K. Yoshimura, S. Ikeda, H. Kobayashi, K. Ohoyama, H. Nakamura
    • Journal Title

      J. Phys. Soc. Jpn

      Volume: 79 Pages: 43701-43701

    • NAID

      40017072087

    • Related Report
      2011 Final Research Report
  • [Journal Article] Itenarant Electon Metamagnetism in η-Carbide-Type Compound Co_3Mo_3C2010

    • Author(s)
      T.Waki, et al.
    • Journal Title

      J.Phys.Soc.Jpn.

      Volume: 79

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic susceptibility of η-carbide-type molybdnum and tungsten carbides and nitrides2010

    • Author(s)
      T.Waki, et al.
    • Journal Title

      Accepted for publication J.Phys.: Conf.Ser.

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metamagnetism of η-carbide-type transition-metal carbides and nitrides2010

    • Author(s)
      T.Waki, et al.
    • Journal Title

      Accepted for publication J.Phys.: Conf.Ser.

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Non-Fermi-Liquid Behavior on an Iron-Based Itinerant Electron Magnet Fe3Mo3N2010

    • Author(s)
      Takeshi Waki, et al.
    • Journal Title

      Journal of Physical Society of Japan 79

      Pages: 0437011-4

    • NAID

      40017072087

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] η-カーバイド型化合物の磁歪測定2012

    • Author(s)
      和氣剛, 山本将貴, 田畑吉計, 石田憲二, 中村裕之
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学
    • Year and Date
      2012-03-26
    • Related Report
      2011 Final Research Report
  • [Presentation] タングステン系η-12型カーバイドの置換効果2012

    • Author(s)
      古澤大介, 和氣剛, 田畑吉計, 近藤晃弘, 金道浩一, 中村裕之
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学
    • Year and Date
      2012-03-24
    • Related Report
      2011 Final Research Report
  • [Presentation] M3Al2TC(M=Nb, Ta, T=Cr, Mn, Fe, Co)の磁性2012

    • Author(s)
      平松良朗, 和氣剛, 田畑吉計, 中村裕之
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学
    • Year and Date
      2012-03-24
    • Related Report
      2011 Final Research Report
  • [Presentation] イータカーバイド型化合物Fe6W6Cの基底状態2011

    • Author(s)
      中村裕之, 和氣剛, 田畑吉計, 山本将貴, 道岡千城, 吉村一良
    • Organizer
      粉体粉末冶金協会平成23年度秋季大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2011-10-28
    • Related Report
      2011 Final Research Report
  • [Presentation] タングステン系η-カーバイドの磁性2011

    • Author(s)
      古澤大介, 和氣剛, 田畑吉計, 近藤晃弘, 金道浩一, 中村裕之
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学
    • Year and Date
      2011-09-21
    • Related Report
      2011 Final Research Report
  • [Presentation] M3Al2TC(M=Nb, Ta, T=Cr, Mn, Fe, Co)の磁性2011

    • Author(s)
      平松良朗, 和氣剛, 田畑吉計, 中村裕之
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学
    • Year and Date
      2011-09-21
    • Related Report
      2011 Final Research Report
  • [Presentation] 遍歴電子メタ磁性体Fe3Mo3Nの高磁場物性2011

    • Author(s)
      山本将貴, 田畑吉計, 和氣剛, 中村裕之, 鳴海康雄, 野尻浩之, 石田憲二, 中井祐介
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学
    • Year and Date
      2011-09-21
    • Related Report
      2011 Final Research Report
  • [Presentation] η-12型炭化物の磁性2011

    • Author(s)
      和氣剛, 山崎照夫, 田畑吉計, 近藤晃弘, 金道浩一, 中村裕之
    • Organizer
      日本物理学会2011年秋季大会
    • Place of Presentation
      富山大学
    • Year and Date
      2011-09-21
    • Related Report
      2011 Final Research Report
  • [Presentation] イータカーバイド型遷移金属炭化物の磁性2011

    • Author(s)
      中村裕之, 和氣剛, 田畑吉計
    • Organizer
      粉体粉末冶金協会平成23年度春期大会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2011-06-01
    • Related Report
      2011 Final Research Report
  • [Presentation] HIP法によるイータカーバイド型遷移金属化物の合成2010

    • Author(s)
      和氣剛, 寺澤慎祐, 田畑吉計, 中村裕之, 村瀬康, 加藤将樹, 廣田健
    • Organizer
      粉体粉末冶金協会平成22年度秋季大会
    • Place of Presentation
      京都大学
    • Year and Date
      2010-11-10
    • Related Report
      2011 Final Research Report
  • [Presentation] HIP法によるイータカーバイド型遷移金属窒化物の合成2010

    • Author(s)
      和氣剛, ら
    • Organizer
      粉体粉末冶金協会
    • Place of Presentation
      京都大学百周年時計台記念館(招待講演)
    • Year and Date
      2010-11-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] Co3Mo3Cの遍歴電子メタ磁性転移2010

    • Author(s)
      梅本康記, 寺澤慎祐, 和氣剛, 田畑吉計, 近藤晃弘, 佐藤桂輔, 金道浩一, Silvia Alconchel, Fernando Sapina, 中村裕之
    • Organizer
      日本物理学会2010年秋季大会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2010-09-25
    • Related Report
      2011 Final Research Report
  • [Presentation] イータカーバイド型遷移金属炭化物窒化物の合成と物性2010

    • Author(s)
      和氣剛, 寺澤慎祐, 梅本康記, 田畑吉計, 村瀬康, 加藤将樹, 廣田健, 中村裕之
    • Organizer
      日本物理学会2010年秋季大会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2010-09-25
    • Related Report
      2011 Final Research Report
  • [Presentation] Fe3Mo3Nの微視的研究2010

    • Author(s)
      寺澤慎祐, 和氣剛, 田畑吉計, 山崎照夫, 中村裕之, 瀧川仁, 横山淳
    • Organizer
      日本物理学会2010年秋季大会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2010-09-25
    • Related Report
      2011 Final Research Report
  • [Presentation] Co置換系(FexCo1-x) 3Mo3Nの57Fe核メスバウアー測定2010

    • Author(s)
      池田修悟, 和氣剛, 寺澤慎祐, 中村裕之, 小林寿夫
    • Organizer
      日本物理学会2010年秋季大会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2010-09-25
    • Related Report
      2011 Final Research Report
  • [Presentation] 遍歴電子メタ磁性体Fe3Mo3Nの高磁場比熱2010

    • Author(s)
      田畑吉計, 寺澤慎祐, 和氣剛, 中村裕之, 鳴海康雄, 野尻浩之
    • Organizer
      日本物理学会2010年秋季大会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2010-09-25
    • Related Report
      2011 Final Research Report
  • [Presentation] Co3Mo3Cの遍歴電子メタ磁性転移2010

    • Author(s)
      梅本康記、和氣剛, ら
    • Organizer
      日本物理学会2010年秋季大会
    • Place of Presentation
      大阪府立大学(招待講演)
    • Year and Date
      2010-09-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] イータカーバイド型遷移金属炭化物窒化物の合成と物性2010

    • Author(s)
      和氣剛, ら
    • Organizer
      日本物理学会2010年秋季大会
    • Place of Presentation
      大阪府立大学(招待講演)
    • Year and Date
      2010-09-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] 星型四面体格子のフラストレーションとFe3Mo3Nのスピン液体状態2010

    • Author(s)
      中村裕之, 寺澤慎祐, 和氣剛, 田畑吉計, 高橋慶紀
    • Organizer
      日本物理学会2010年秋季大会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2010-09-23
    • Related Report
      2011 Final Research Report
  • [Presentation] Fe3Mo3NのCo置換効果2010

    • Author(s)
      寺澤慎祐, 和氣剛, 田畑吉計, 中村裕之
    • Organizer
      日本物理学会第65回年次大会
    • Place of Presentation
      岡山大学
    • Year and Date
      2010-03-22
    • Related Report
      2011 Final Research Report
  • [Presentation] Fe3Mo3NのCo置換効果2010

    • Author(s)
      寺澤慎祐、和氣剛, ら
    • Organizer
      日本物理学会
    • Place of Presentation
      岡山大学(岡山市)
    • Year and Date
      2010-03-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] Fe3Mo3Nの非フェルミ液体的挙動2010

    • Author(s)
      寺澤慎祐, 和氣剛, 田畑吉計, 中村裕之, 道岡千城, 吉村一良, 佐藤桂輔, 金道浩一, 高橋慶紀
    • Organizer
      日本物理学会第65回年次大会
    • Place of Presentation
      岡山大学
    • Year and Date
      2010-03-20
    • Related Report
      2011 Final Research Report
  • [Presentation] Fe3Mo3Nの非フェルミ液体的挙動2010

    • Author(s)
      寺澤慎祐、和氣剛, ら
    • Organizer
      日本物理学会
    • Place of Presentation
      岡山大学(岡山市)
    • Year and Date
      2010-03-20
    • Related Report
      2009 Annual Research Report
  • [Presentation] ηカーバイド型鉄化合物の構造と磁性2009

    • Author(s)
      中村裕之, 寺澤慎祐, 和氣剛, 田畑吉計
    • Organizer
      粉体粉末冶金協会平成21年度春季大会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2009-10-27
    • Related Report
      2011 Final Research Report
  • [Presentation] Fe3Mo3Nの基底状態2009

    • Author(s)
      寺澤慎祐, 和氣剛, 田畑吉計, 中村裕之, 池田修悟, 小林寿夫
    • Organizer
      日本物理学会2009年秋季大会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-27
    • Related Report
      2011 Final Research Report
  • [Presentation] Fe3Mo3Nの基底状態2009

    • Author(s)
      寺澤慎祐、和氣剛, ら
    • Organizer
      日本物理学会
    • Place of Presentation
      熊本大学(熊本市)
    • Year and Date
      2009-09-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] 遷移金属窒化物Fe3Mo3Nにおける幾何学的フラストレーション2009

    • Author(s)
      寺澤慎祐, 和氣剛, 田畑吉計, 中村裕之
    • Organizer
      粉体粉末冶金協会平成21年度春季大会
    • Place of Presentation
      京都工芸繊維大学
    • Year and Date
      2009-06-02
    • Related Report
      2011 Final Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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